Study of the effect of water-soluble fractions of heavy-oil on coastal marine organisms using enclosed ecosystems,mesocosms

Mesocosm facilities composed of 4 experimental and 2 reservoir tanks (1.5 m in diameter, 3.0 m in depth and 5 tons in capacity) made of FRP plastics, were constructed in the concrete fish rearing pond in the Fisheries Laboratory, The University of Tokyo. The water-soluble fraction of Rank A heavy residual oil was formed by mixing 500 g of the oil with 10 l of seawater, which was introduced to the 5000 l-capacity tanks. Experimental Run 4 was conducted from May 31 to June 7, 2000. Oil concentrations in the tanks were 4.5 microg/l called LOW, and 13.5 microg/l, called HIGH tank. Bacterial growth rates very quickly accelerated in the HIGH tank just after the loading of oil which corresponded with a high increase of bacterial cells in the same tank after 2 days. Later, bacterial numbers in HIGH tank rapidly decreased, corresponding with the rapid increase of heterotrophic nano-flagellates and virus numbers on the same day. Sediment traps were deployed at the bottom of the experimental tanks, and were periodically retrieved. These samples were observed both under light microscope and epi-fluorescent microscope with UV-excitation. It was observed that the main components of the vertical flux were amorphous suspended matter, mostly originating from dead phytoplankton and living diatoms. It was further observed from the pictures that vertical transport of oil emulsions were probably conducted after adsorption to amorphous suspended matter and living diatoms, and were settling in the sediment traps at the bottom of the tanks. This means that the main force which drives the soluble fraction of oil into bottom sediment would be vertical flux of such amorphous suspended particles and phytoplankton. Further incubation of the samples revealed that the oil emulsions were degraded by the activity of autochtonous bacteria in the sediment in aerobic condition.     

Effects of deposit feeder Stichopus japonicus on algal bloom and organic matter contents of bottom sediments of the enclosed sea

Algae growing in an enclosed sea may inhibit eutrophication because they absorb nutrients in the water. However, dead algae often cause anaerobic conditions in the water just above and on sediment after they are deposited on the bottom. We found that Stichopus japonicus inhibited the anaerobic processes coupling water sulfite production in sediment. The present study investigates whether S. japonicus inhibits algal flourish and influences sediment properties such as organic matter contents. Aquarium experiments were carried out at Komatsushima port in Tokushima Prefecture, western Japan. The aquaria used in the experiments were supplied with water directly from the adjacent sea (6 L/min), laid with sand of 10 cm depths, and lighted at 12 h intervals. Six aquaria each containing a sea cucumber from Komatsushima port and six aquaria without any were used in the experiments. Water temperature ranged between 9 and 15 degrees C during December 2000 and April 2001. Salinity ranged between 32 per thousand and 34 per thousand. Algae began to cover the bottom of the aquaria without S. japonicus after 2 weeks, whereas no growth was evident in the aquaria containing sea cucumbers. Chlorophyll a concentration in the surface sediment of the aquaria with S. japonicus (6.1+/-3.6 microg/g, mean S.D.+/-standard deviation) was significantly lower than that without it (60+/-17 microg/g, U-test, p<0.05). Phaeophytin concentration in the surface sediment of the aquaria with S. japonicus (0.9+/-0.09 microg/g) was also significantly lower than that without it (4.5+/-1.0 microg/g, U-test, p<0.05). TOC concentration in the surface sediment of the aquaria with S. japonicus (2.6+/-1.3 microg/g) was slightly lower than that without it (4.0+/-1.2 microg/g). These results showed that algal biomass and organic matter concentration of the bottom were decreased in the presence of S. japonicus. Therefore, S. japonicus inhibits algal bloom and decrease the contents of organic matter deposited on the bottom of enclosed sea areas.     

Landslides in Sado Island of Japan: Part I. Case studies, monitoring techniques and environmental considerations

A sufficient knowledge on the kinematics and development of landslides helps to adopt proper measures that can be used to protect slopes and the environment in general. This can be achieved by adequate monitoring programs. This paper presents the findings of intensive monitoring activities carried out on Shiidomari and Katanoo landslides found in Sado Island of Japan. More than one year of observation of the two landslides allowed defining some peculiar futures of their kinematics and style of development. The problem of slope instability in the two areas is generally accredited to various factors. But, both landslides were triggered by heavy rainfalls and snowmelt. Because of the outline of the area and the presence of relict topographic features, the Shiidomari landslide is considered to be a large-scale reactivation of old slope failures. The Katanoo landslide is, however, a first-time case. Geophysical investigations and drilling activities in Shiidomari indicated the presence of two slip planes. The deepest (80–100 m) of these is controlled by existing lineaments. Monitoring data suggests that the body of the landslide has subsided as much as 1.16 m just below the main scarp, but a centimeter in the central region. The toe sector also experienced a significant amount of subsidence, but this was counter-balanced by an uplift on the opposite side of the landslide. Hence, the landslide seems not any more active along the deepest slip surface, although it may extend upward and define a series of shallow shear planes around the crown. In the case of Katanoo, the landform characteristics, differential weathering, the road cut and groundwater fluctuations appeared to contribute much to determine the exact location of the landslide. Extensional cracks that preceded the landslide can be related to heavy rainfalls and the cold and warm cycles thereafter. Subsurface investigations and monitoring works indicated that the landslide has two slide blocks with different slip planes. During the observation period, the upper part of the landslide responded more effectively to rainfall and snowmelt than the middle and lower sections. The corresponding movements, however, appeared to settle about three months after failure. There were also little strain transmissions in boreholes and no significant change in the characteristics of the landslide. The kinematics of deformation of many of the slopes in Sado Island resembles that of Shiidomari landslide. But mass movements along highways and mountain roads are usually similar to Katanoo. Landslides of the type like Shiidomari may not show sudden and drastic failures, but are usually long lasting and can reactivate repeatedly along new, shallow shear planes. Monitoring works and long-term supervisions in these types of landslides are useful to identify impending failures and take the right measures before they brought about large-scale destruction to the environment.     

A model current system for the magnetospheric substorm

We propose a model three-dimensional current system for the magnetospheric substorm, which can account for the new findings of the field-aligned and ionospheric currents obtained during the last few years by using new techniques. They include (1) the ionospheric currents at the auroral latitude deduced from the Chatanika incoherent scatter radar data, (2) the field-aligned currents inferred from the vector magnetic field observations by the TRIAD satellite and (3) the global distribution of auroras with respect to the auroral electrojets appearing in DMSP satellite photographs. The model current system is also tested by a computer model calculation of the ionospheric current pattern. It is shown that the auroral electrojets have a strong asymmetry with respect to the midnight meridian. The westward electrojet flows along the discrete aurora in the evening sector, as well as along the diffuse aurora in the morning sector. The eastward electrojet flows equatorward of the westward electrojet in the evening sector. It has a northward component and joins the westward electrojet by turning westward across the Harang discontinuity. Thus, the latitudinal width of the westward electrojet in the morning sector is much larger than that in the evening sector. The field-aligned currents, consisting of two pairs of upward and inward currents (one is located in the morning sector and the other in the evening sector), are closed neither simply by the east-west ionospheric currents nor by the north-south currents, but by a complicated combination of the north-south and east-west paths in the ionosphere. The magnetospheric extension of the current system is also briefly discussed.     

Mechanical and transport constitutive models for fractures subject to dissolution and precipitation

Transient changes in the permeability of fractures in systems driven far‐from‐equilibrium are described in terms of proxy roles of stress, temperature and chemistry. The combined effects of stress and temperature are accommodated in the response of asperity bridges where mineral mass is mobilized from the bridge to the surrounding fluid. Mass balance within the fluid accommodates mineral mass either removed from the flow system by precipitation or advection, or augmented by either dissolution or advection. Where the system is hydraulically closed and initially at equilibrium, reduction in aperture driven by the effects of applied stresses and temperatures will be augmented by precipitation on the fracture walls. Where the system is open, the initial drop in aperture may continue, and accelerate, where the influent fluid is oversaturated with respect to the equilibrium mineral concentration within the fluid, or may reverse, if undersaturated. This simple zero‐dimensional model is capable of representing the intricate behavior observed in experiments where the feasibility of fracture sealing concurrent with net dissolution is observed. This zero‐order model is developed as a constitutive model capable of representing key aspects of changes in the transport parameters of the continuum response of fractured media to changes in stress, temperature and chemistry. Copyright © 2009 John Wiley & Sons, Ltd.     

Temporal alteration of fracture permeability in granite under hydrothermal conditions and its interpretation by coupled chemo-mechanical model

Examining the evolution of fracture permeability under stressed and temperature-elevated conditions, a series of flow-through experiments on a single rock fracture in granite has been conducted under confining pressures of 5 and 10 MPa, under differential water pressures ranging from 0.04 to 0.5 MPa, and at temperatures of 20–90 °C, for several hundred hours in each experiment. Measurements of fluid and dissolved mass fluxes, and post-experimental microscopy, were conducted to constrain the progress of mineral dissolution and/or precipitation and to examine its effect on transport properties. Generally, the fracture aperture monotonically decreased with time at room temperature, and reached a steady state in relatively short periods (i.e., <400 h). However, once the temperature was elevated to 90 °C, the aperture resumed decreasing and kept decreasing throughout the rest of the experimental periods. This reduction may result from the removal of the mineral mass from the bridging asperities within the fracture. Post-experimental observations by scanning electron microscopy, coupled with energy dispersive X-ray spectroscopy (SEM-EDX), revealed the formation of several kinds of secondary minerals such as silica and calcite. However, the precipitated minerals seemed to have had little influence on the flow characteristics within the fracture, because the precipitation was limited to quite local and small areas. The evolving rates and ultimate magnitudes of the fracture aperture are likely to be controlled by the stress exerted over the contacting asperities and temperatures, and by the prescribed flow conditions. Thus, this complex behavior should be attributed to the coupled chemically- and mechanically-induced effect. A coupled chemo–mechano conceptual model, accounting for pressure and free-face dissolutions, is presented in this paper to follow the evolution of the fracture permeability observed in the flow-through experiments. This model addresses the two dissolution processes at the contacting asperities and the free walls within the fractures, and is also capable of describing multi-mineral dissolution behavior. The model shows that the evolution of a fracture aperture (or related permeability) and of element concentrations may be followed with time under arbitrary temperature and pressure conditions. The model predictions for the evolving fracture aperture and elements concentrations show a relatively good agreement with the experimental measurements, although it is not possible to replicate the abrupt reduction observed in the early periods of the experiments, which is likely to be due to an unaccounted mechanism of more stress-mediated fracture compaction driven by the fracturing of the propping asperities.     

Terrestrial – Ocean environmental change in the northwestern Pacific from the glacial times to Holocene

The Mixed Water Region (MWR) between the Oyashio Current and the Kuroshio Extension and surrounding terrestrial region have been affected by the global climatic change. The sedimentary core KR02-15 PC6 collected at 40°23.8871′N, 143°29.8663′E in the MWR provides detailed records of pollen and spores and alkenone sea surface temperature (SST) during the last 15 kyr, showing that both ocean and terrestrial environments have been appreciably linked. Abundance of Picea, a proxy for terrestrial cool climate, fluctuated, coinciding with the alkenone-SST change during the interstadial period (15.0–7.7 cal kyr B.P.). Alkenone-SST increased to the modern level at 8.0 cal kyr B.P. and remained almost constant until 2.0 kyr B.P. while the terrestrial warming still continued until 4.0 cal kyr B.P. The rainfall under terrestrial warm condition increased gradually from 7.9 cal kyr B.P. and rapidly from 2.0 cal kyr B.P. Both terrestrial and marine environments cooled down during the last 2 kyr possibly due to the intensified cold Oyashio Current.     

A numerical model simulating reactive transport and evolution of fracture permeability

A numerical model is presented to describe the evolution of fracture aperture (and related permeability) mediated by the competing chemical processes of pressure solution and free‐face dissolution/precipitation; pressure (dis)solution and precipitation effect net‐reduction in aperture and free‐face dissolution effects net‐increase. These processes are incorporated to examine coupled thermo‐hydro‐mechano‐chemo responses during a flow‐through experiment, and applied to reckon the effect of forced fluid injection within rock fractures at geothermal and petroleum sites. The model accommodates advection‐dominant transport systems by employing the Lagrangian–Eulerian method. This enables changes in aperture and solute concentration within a fracture to be followed with time for arbitrary driving effective stresses, fluid and rock temperatures, and fluid flow rates. This allows a systematic evaluation of evolving linked mechanical and chemical processes. Changes in fracture aperture and solute concentration tracked within a well‐constrained flow‐through test completed on a natural fracture in novaculite (Earth Planet. Sci. Lett. 2006, in press) are compared with the distributed parameter model. These results show relatively good agreement, excepting an enigmatic abrupt reduction in fracture aperture in the early experimental period, suggesting that other mechanisms such as mechanical creep and clogging induced by unanticipated local precipitation need to be quantified and incorporated. The model is applied to examine the evolution in fracture permeability for different inlet conditions, including localized (rather than distributed) injection. Predictions show the evolution of preferential flow paths driven by dissolution, and also define the sense of permeability evolution at field scale. Copyright © 2006 John Wiley & Sons, Ltd.