Depleted arc volcanism in the Alboran Sea and shoshonitic volcanism in Morocco: geochemical and isotopic constraints on Neogene tectonic processes

Samples of volcanic rocks from Alborán Island, the Alboran Sea floor and from the Gourougou volcanic centre in northern Morocco have been analyzed for major and trace elements and Sr–Nd isotopes to test current theories on the tectonic geodynamic evolution of the Alboran Sea. The Alborán Island samples are low-K tholeiitic basaltic andesites whose depleted contents of HFS elements (0.5×N-MORB), especially Nb (0.2×N-MORB), show marked geochemical parallels with volcanics from immature intra-oceanic arcs and back-arc basins. Several of the submarine samples have similar compositions, one showing low-Ca boninite affinity. ¹⁴³Nd/¹⁴⁴Nd ratios fall in the same range as many island-arc and back-arc basin samples, whereas ⁸⁷Sr/⁸⁶Sr ratios (on leached samples) are somewhat more radiogenic. Our data point to active subduction taking place beneath the Alboran region in Miocene times, and imply the presence of an associated back-arc spreading centre. Our sea floor suite includes a few more evolved dacite and rhyolite samples with (⁸⁷Sr/⁸⁶Sr)₀ up to 0.717 that probably represent varying degrees of crustal melting. The shoshonite and high-K basaltic andesite lavas from Gourougou have comparable normalized incompatible-element enrichment diagrams and Ce/Y ratios to shoshonitic volcanics from oceanic island arcs, though they have less pronounced Nb deficits. They are much less LIL- and LREE-enriched than continental arc analogues and post-collisional shoshonites from Tibet. The magmas probably originated by melting in subcontinental lithospheric mantle that had experienced negligible subduction input. Sr–Nd isotope compositions point to significant crustal contamination which appears to account for the small Nb anomalies.

The unmistakable supra-subduction zone (SSZ) signature shown by our Alboran basalts and basaltic andesite samples refutes geodynamic models that attribute all Neogene volcanism in the Alboran domain to decompression melting of upwelling asthenosphere arising from convective thinning of over-thickened lithosphere. Our data support recent models in which subsidence is caused by westward rollback of an eastward-dipping subduction zone beneath the westernmost Mediterranean. Moreover, severance of the lithosphere at the edges of the rolling-back slab provides opportunities for locally melting lithospheric mantle, providing a possible explanation for the shoshonitic volcanism seen in northern Morocco and more sporadically in SE Spain.     

Petrology of lower-middle Miocene Zoumi Flysch Fm. (Mesorif sub-domain,Rif belt,Morocco): first evidence of mixed mode provenance and geodynamic setting

The Zoumi Basin was generated in a collisional tectonic setting during the Lower-Middle Miocene. The syn-orogenic flysch deposits of the basin have been well investigated by petrographic and geochemical studies to characterize the composition, source to sink routing system, and tectonic setting of the Zoumi flysch. Forty-three sandstone samples and 45 mudstone samples have been gathered from six measured stratigraphic sections. These samples have been analyzed using XRD, XRF, inductively coupled plasma-mass spectrometry (ICP-MS) for mudrocks and petrographic investigation for sandstones. The Lower-Middle Miocene Zoumi flysch is defined as sublitharenites and quartzarenites according to mineralogical content. Detrital grains are commonly subangular to subrounded, poorly sorted, and rich in quartz grains. Point counting modal analysis leads to craton interior and recycled orogen provenance with significant first-cycle sediment supply and low sedimentary recycling. Several chemical ratios (Al₂O₃/TiO₂, La/Th, Cr/Th, Th/Sc, Zr/Sc) as well as chondrite-normalized REE patterns with flat HREE, LREE enrichment, and negative Eu anomaly suggest a dominant felsic rock sources. However, V-Ni-La*4, V-Ni-Th*10, and Th/Sc vs. Cr/Th plots do not exclude a mafic supply source nature which is evidenced by numerous ophiolitic outcrops scattered throughout the Mesorifan Subdomain (Mesorifan Ophiolitic Suture Zone).     

Structure et caractérisation des matériaux utilisés dans la construction d'une mosaı̈que romaine de la cité de Volubilis (Maroc)

In Volubilis, Roman mosaics are very beautiful and reveal, from the bottom to the surface, three layers: (i) ‘hedgehog’ layer, (ii) coarse grain mortar layer (rudus + nucleus) and (iii) tesselatum. Mineralogical analysis of coarse grain mortar sampled in Flavius Germanus mosaic shows that it consisted of quartz and calcite, with some feldspar and probably mica and dolomite. Fine-grained mortar in tesselatum is made from a mixture of calcite and quartz only. Limestone tesserae (white, pink and brown) show petrographic facies that change from micritic to oolithic limestone. Conversely, black and brick red tesserae are respectively made of marble, red sandstone and from fire clay. Other colours as yellow, blue, green and grey are obtained from artificial glass with different chemical compositions. To cite this article: A. Dekayir et al., C. R. Geoscience 336 (2004).     

Perogenesis of granites, Sharm El-Sheikh area, South Sinai, Egypt: petrological constrains and tectonic evolution

Precambrian granites of the Sharm El-Sheikh area in south Sinai, Egypt belong to collisional and post-collisional Magmatism (610–580 Ma). The granites are widely distributed in the northern part of the Neoproterozoic Arabian-Nubian Shield. South Sinai includes important components of successive multiple stages of upper crust granitic rocks. The earliest stages include monzogranite and syenogranites while the later stages produced alkali feldspar granites and riebeckite-bearing granites. Numerous felsic, mafic dikes and quartz veins traverse the study granites. Petrographically, the granitic rocks consist mainly of perthite, plagioclase, quartz, biotite and riebeckite. Analysis results portray monzogranites displaying calc-alkaline characteristics and emplaced in island-arc tectonic settings, whereas the syenogranites, alkali-feldspar granites and the riebeckite bearing-granites exhibit an alkaline nature and are enriched in HFSEs similar to granites within an extensional regime. Multi-element variation diagrams and geochemical characteristics reinforce a post-collision tectonic setting. REEs geochemical modeling reveals that the rocks were generated as a result of partial melting and fractionation of lower crust basaltic magma giving rise to A₁ and A₂ subtype granites. They were subsequently emplaced within an intraplate environment at the end of the Pan-African Orogeny.     

Modeling and simulation of hybrid anaerobic/aerobic wastewater treatment system

Modeling and simulation using GPS-X software for a packed bed up-flow anaerobic sludge blanket followed by a biological aerated filter were studied. Both treatment units were packed with a non-woven polyester fabric as a bio-bed. The system was operated at a hydraulic and organic loading rate of 9.65 m³/m²/d and 2.64 kg BOD₅/m³/day. Verification of the experimental results and calibration of the model were carried out prior simulation and modeling. Variables under consideration were HLR, OLR, and surface area of the packing material. HLR and OLR are increased incrementally until the break through point has been achieved. The results obtained from modeling indicated that the treatment system has great potential to be used as an ideal and efficient option for high hydraulic and organic loading rates up to 19.29 m³/m²/d and 4.48 kg BOD₅/m³/day. The model indicated that increasing the input HLR and OLR loads to the treatment system up to 50 % of the original values achieved removal efficiencies 98 % for TSS, 88 % for BOD₅, and 85 % for COD. Moreover, increasing the HLR to four times the original value (38.59 m³/m²/d) reduced the efficiency of the treatment system to 50 % for COD and BOD₅. However, the removal rates of TSS, TKN, and TP were not affected. Also, the modeling results indicated that increasing the surface area of the packing material increased the overall efficiency of the treatment system.     

Hydrothermal alteration of plagioclase in granitic rocks from Proterozoic basement of SE Sweden

Petrographic examinations and electron microprobe analyses of Proterozoic granitic rocks, SE Sweden aimed to characterize and unravel the mechanisms and conditions of plagioclase alterations. These alterations include saussuritization, albitization and replacement of plagioclase by K‐feldspar. The hydrothermal alterations, which are inferred to have occurred at ca. 250–400°C, resulted in concomitant formation of Al‐rich titanite, epidote, calcite, pumpellyite, prehnite and iron oxides. Replacement of plagioclase by K‐feldspar occurs in red‐stained zones, which have developed close to thin fractures owing to the precipitation of tiny Fe‐oxide pigment particles within the altered plagioclase, whereas saussuritized plagioclase has less systematic spatial relationships to these fractures. Albitization of plagioclase occurred in rocks that are poor in biotite compared to rocks that suffered extensive saussuritization. The chemical and textural characterization of various types of plagioclase alterations allows elucidation of the granitic hydrothermal systems. Features of feldspar alteration in the granitic rocks are similar to those encountered in feldspathic sandstones and should hence be considered in studies on diagenetic changes of siliciclastic successions during basin evolution. Copyright © 2009 John Wiley & Sons, Ltd.     

Analytical solution for distributed torsional low strain integrity test for pipe pile

Low strain integrity tests (LSITs) are the most popular non-destructive methods for pile testing. However, traditional LSITs have encountered unprecedented challenges as the need for long pile and existing pile testing keeps multiplying. Compared to traditional longitudinal excitations, the torsional wave is less influenced by the velocity attenuation effect and can be subjected at the pile shaft for existing piles. Distributed torsional LSIT is proposed in this article with the presentation of the corresponding analytical solutions that exhibiting the velocity responses along the pile shaft. The solution is verified with previous simplified theoretical and rigorous finite element method (FEM) answers. At the end, the application of this method is exhibited through the identification of necking and concrete segregation defects on pipe piles, which shows the advantage of this method on long pile testing.