Degradation of 2, 4, 6-trinitotoluene in aqueous solution by ozonation and multi-stage ozonation biological treatment

The objective of this study was to explore the extent of 2,4,6-trinitrotoluene synthetic solution and red water mineralization by comparing conventional direct ozonation and multi-stage ozonation-biological treatment process. The alkaline hydrolysis was used for remediation 2, 4, 6-trinitrotoluene and red water at pH = 10.9. Nevertheless, the hydroxyl radicals would be generated by ozone decomposition with ozone dose of 0.177 g/L. The samples were subjected to chemical oxygen demand and total organic carbon analysis to monitor pollutants removal. The rate of 2, 4, 6-trinitrotoluene and red water pollutants degradation were quantified using high performance liquid chromatography. 2, 4, 6-trinitrotoluene synthetic solution resulted 55.5 % chemical oxygen demand removal by 3 h direct ozonation. Following direct ozonation the biological treatment twenty four hours chemical oxygen demand reached 98.9 % and 98.7 % removal using humic acid and river water 1 % ( v/v) inoculation singly and respectively. Conventional direct ozonation showed non significant change in total organic carbon degradation. While on using multi-stage ozone-biological treatment process where humic acid and/or river water were used as inoculums singly and respectively, total organic carbon fulfilled 73 % and 98.3 % removal. The process was one hour direct ozonation and followed by three days multi-stage ozone-biological treatment. In multi-stage ozone-biological treatment process, ozonation was effective to decompose total organic carbon and to produce biodegradable dissolved organic carbon easily removed by ozone oxidation up to 98.3 % in 2,4,6-trinitrotoluene synthetic solution. Pollutants removal achieved 99 % in authentic red water effluent using river inoculation 1 % (v/v) in 5 days. Nuclear Magnetic Resonance and Fourier Transformation Infra Red methods were performed to confirm types of pollutants content in red water.     

Pan-African high-grade metamorphism of southern Sinai,Egypt, fluid inclusion evidence

Fluid inclusions in the leucosomes of Wadi Feiran migmatites showed that CO ₂ , H₂O and (H₂O-CO₂) fluids were likely to have been present when partial melting began in these rocks. Low salinity, aqueous fluid, to a lesser extent, CO₂-rich fluids are the most abundant fluids. The present study suggests that high-density CO₂ inclusions were formed at the earliest stage, while H₂O inclusions were formed at the late stage. In an intermediate stage, low-density CO₂ and H₂O, CO₂ inclusions were formed. At the early stage of uplift and during melt crystallization, the CO₂-bearing vapour was trapped at grain boundaries. At the late stage of uplift, H₂O released at the time of crystallization of the melt was trapped as inclusions.     

Application of data assimilation for improving forecast of water levels and residual currents in Singapore regional waters

Hydrodynamic models are commonly used for predicting water levels and currents in the deep ocean, ocean margins and shelf seas. Their accuracy is typically limited by factors, such as the complexity of the coastal geometry and bathymetry, plus the uncertainty in the flow forcing (deep ocean tide, winds and pressure). In Southeast Asian waters with its strongly hydrodynamic characteristics, the lack of detailed marine observations (bathymetry and tides) for model validation is an additional factor limiting flow representation. This paper deals with the application of ensemble Kalman filter (EnKF)-based data assimilation with the purpose of improving the deterministic model forecast. The efficacy of the EnKF is analysed via a twin experiment conducted with the 2D barotropic Singapore regional model. The results show that the applied data assimilation can improve the forecasts significantly in this complex flow regime.     

Polybrominated diphenyl ethers and their methoxylated analogs in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) from Bizerte Lagoon, Tunisia

Concentrations of ten polybrominated diphenyl ethers (PBDEs) and eight methoxylated polybrominated diphenyl ethers (MeO-PBDEs) in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) collected from the Bizerte Lagoon and the Mediterranean Sea were investigated. To the best of our knowledge, this is the first report of these compounds in marine fishes from Tunisia. The PBDE mean concentrations in fish from Bizerte Lagoon were 45.3 and 96.2 ng g(-1) lw respectively in mullet and sea bass, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea were 7.80 and 27.9 ng g(-1) lw respectively. MeO-PBDE concentrations in mullet and sea bass from Bizerte Lagoon ranged from 6.46 to 286 ng g(-1) lw and from 49.4 to 798 ng g(-1) lw respectively, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea ranged from 190 to 401 ng g(-1) lw and from 353 to 578 ng g(-1) lw respectively. The total PBDEs and total MeO-PBDEs concentration in fish from Bizerte Lagoon were similar or slightly lower than those reported for other species from other locations around the world.     

Multivariate statistical analyses of the groundwater system in Darb El-Arbaein, Southwestern Desert, Egypt

In Darb El-Arbaein, the groundwater is the only water resource. The aquifer system starts from Paleozoic–Mesozoic to Upper Cretaceous sandstone rocks. They overlay the basement rocks and the aquifer is confined. In the present research, the performance of the statistical analyses to classify groundwater samples depending on their chemical characters has been tested. The hydrogeological and hydrogeochemical data of 92 groundwater samples were obtained from the General Authority for Rehabilitation Projects and Agricultural Development authority in northern, central, and southern Darb El-Arbaein. A robust classification scheme for partitioning groundwater chemistry into homogeneous groups was an important tool for the characterization of Nubian sandstone aquifer. We test the performance of the many available graphical and statistical methodologies used to classify water samples. R-mode, Q-mode, correlation analysis, and principal component analysis were investigated. All the methods were discussed and compared as to their ability to cluster, ease of use, and ease of interpretation. The correlation investigation clarifies the relationship among the lithologic, hydrogeologic, and anthropogenic factors. Factor investigation revealed three factors, namely, the evaporation process–agricultural impact–lithogenic dissolution, the hydrogeological characteristics of the aquifer system, and the surface meteoric water that recharge the aquifer system. Two main clusters that subdivided into four subclusters were identified in the groundwater system based on hydrogeological and hydrogeochemical data. They reflect the impact of geomedia, hydrogeology, geographic position, and agricultural wastewater. The groundwater is undersaturated with respect to most selected minerals. The groundwater was supersaturated with respect to iron minerals in northern and southern Darb El-Arbaein. The partial pressure of the groundwater versus saturation index of calcite shows the gradual change in PCO₂ from atmospheric to the present aquifer pressures.     

Wrench structural deformation in Ras Al Hilal-Al Athrun area, NE Libya: a new contribution in Northern Al Jabal Al Akhdar Belt

Al Jabal Al Akhdar is a NE/SW- to ENE/WSW-trending mobile part in Northern Cyrenaica province and is considered a large sedimentary belt in northeast Libya. Ras Al Hilal-Al Athrun area is situated in the northern part of this belt and is covered by Upper Cretaceous–Tertiary sedimentary successions with small outcrops of Quaternary deposits. Unmappable and very restricted thin layers of Palaeocene rocks are also encountered, but still under debate whether they are formed in situ or represent allochthonous remnants of Palaeocene age. The Upper Cretaceous rocks form low-lying to unmappable exposures and occupy the core of a major WSW-plunging anticline. To the west, south, and southeast, they are flanked by high-relief Eocene, Oligocene, and Lower Miocene rocks. Detailed structural analyses indicated structural inversion during Late Cretaceous–Miocene times in response to a right lateral compressional shear. The structural pattern is themed by the development of an E–W major shear zone that confines inside a system of wrench tectonics proceeded elsewhere by transpression. The deformation within this system revealed three phases of consistent ductile and brittle structures (D₁, D₂, and D₃) conformable with three main tectonic stages during Late Cretaceous, Eocene, and Oligocene–Early Miocene times. Quaternary deposits, however, showed at a local scale some of brittle structures accommodated with such deformation and thus reflect the continuity of wrenching post-the Miocene. D₁ deformation is manifested, in Late Cretaceous, via pure wrenching to convergent wrenching and formation of common E- to ENE-plunging folds. These folds are minor, tight, overturned, upright, and recumbent. They are accompanied with WNW–ESE to E–W dextral and N–S sinistral strike-slip faults, reverse to thrust faults and pop-up or flower structures. D₂ deformation initiated at the end of Lutetian (Middle Eocene) by wrenching and elsewhere transpression then enhanced by the development of minor ENE–WSW to E–W asymmetric, close, and, rarely, recumbent folds as well as rejuvenation of the Late Cretaceous strike-slip faults and formation of minor NNW–SSE normal faults. At the end of Eocene, D₂ led to localization of the movement within E–W major shear zone, formation of the early stage of the WSW-plunging Ras Al Hilal major anticline, preservation of the contemporaneity (at a major scale) between the synthetic WNW–ESE to E–W and ENE–WSW strike-slip faults and antithetic N–S strike-slip faults, and continuity of the NW–SE normal faults. D₃ deformation is continued, during the Oligocene-Early Miocene, with the appearance of a spectacular feature of the major anticline and reactivation along the E–W shear zone and the preexisting faults. Estimating stress directions assumed an acted principal horizontal stress from the NNW (N33°W) direction.     

Source parameters of some recent earthquakes in the Gulf of Aqaba, Egypt

Gulf of Aqaba is recognized as an active seismic zone where many destructive earthquakes have occurred. The estimation of source parameters and coda Q attenuation are the main target of this work. Fifty digital seismic events in eight short-period seismic stations with magnitude 2.5–5.2 are used. Most of these events occurred at hypocentral depths in the range of 7–20 km, indicating that the activity was restricted in the upper crust. Seismic moment, M _o, source radius, r, and stress drop, Δσ, are estimated from P- and S-wave spectra using the Brune’s seismic source model. The average seismic moment generated by the whole sequence of events was estimated to be 4.6E?+?22 dyne/cm. The earthquakes with higher stress drop occur at 10-km depth. The scaling relation between the seismic moment and the stress drop indicates a tendency of increasing seismic moment with stress drop. The seismic moment increases with increasing the source radius. Coda waves are sensitive to changes in the subsurface due to the wide scattering effects generating these waves. Single scattering model of local earthquakes is used to the coda Q calculation. The coda with lapse times 10, 20, and 30 s at six central frequencies 1.5, 3, 6, 12, 18, 24 Hz are calculated. The Q _c values are frequency dependent in the range 1–25 Hz, and are approximated by a least squares fit to the power law [ $ {Q_c}(f) = {Q_o}{(f/{f_o})^\eta } $ ]. The average of Q _c values increases from 53?±?10 at 1.5 Hz to 700?±?120 at 24 Hz. The average of Q _o values ranges from 13?±?1 at 1.5 Hz to 39?±?4 at 24 Hz. The frequency exponent parameter η ranges between 1.3?±?0.008 and 0.9?±?0.001.     

Hydrogeophysical investigation of groundwater potential in the El Bawiti, Northern Bahariya Oasis, Western Desert, Egypt

The future development of agriculture, industry, and civil activity planned to be in the Western Desert. This strategy need to the groundwater resource. Vertical electrical soundings (VES) and electromagnetic (TEM) measurements conducted in the El Bawiti, northern Bahariya Oasis. The measurements give detailed information about the geometry of the different hydrogeological layers in the aquifer system and depth to them. A total of 22 VES and TEM were carried out within El Bawiti area. Thirty-one sub soil samples were collected from eight sites to determine the chemical characteristics and address the effects of lithogenic source and anthropogenic activity on them. The geoelectrical measurements and borehole information indicate the presence of five geoelectrical units, from top to base; the surface cover, sand and shale, upper aquifer (Nubian sandstone), sand and shale, and lower aquifer (Nubian sandstone). Surface cover was equally distributed in thickness and composed of dry sand, gravel, and clay deposits. The regional resistivity of the upper aquifer increased in the southwestern part and decline in the northern, eastern, southern, and western parts. The decline in the resistivity reflects the high water yields and potentiality, as well as low salinity. The resistivity of the lower aquifer increased due the northwestern part and the southwestern part. The information collected during this research provides valuable data for estimating the fresh- to brackish-water resources and for development of a groundwater management plan. The integrated analyses carried out represent a significant and cost-effective method for delineating the main aquifer in this area. In turn, future well locations can be placed with more confidence than before, in accordance with the evaluation of the potentiality of the groundwater aquifers in the area. The electrical conductivity of the soil ranges from 302 to 8,490 μS/cm, increases in the western and central-northern parts. It is attributed to the location from the salt-affected soils (playa), the relatively lower elevation units (depressions) and the position in landscape in the Oasis. Sodium adsorption ratio ranges from 0.44 to 11 and the exchangeable sodium ratio ranges from 0.11 to 5. The estimated magnesium hazard fluctuated below 50%. The statistical analyses were accomplished in soil chemistry and discussed.     

Modeling hydrologic responses of the Zwalm catchment using the REW approach: propagation of uncertainty in soil properties to model output

The research presented in this paper focuses on the application of a newly developed physically based watershed modeling approach, which is called representative elementary watershed approach. The study stressed the effects of uncertainty of input parameters on the watershed responses (i.e., simulated discharges). The approach was applied to the Zwalm catchment, which is an agriculture-dominated watershed with a drainage area of 114 km² located in East Flanders, Belgium. Uncertainty analysis of the model parameters is limited to the saturated hydraulic conductivity because of its high influence on the watershed hydrologic behavior and availability of the data. The assessment of output uncertainty is performed using the Monte Carlo method. The ensemble statistical watershed responses and their uncertainties are calculated and compared with measurements. The results show that the measured discharges fall within the 95% confidence interval of the modeled discharge. This provides the uncertainty bounds of the discharges that account for the uncertainty in saturated hydraulic conductivity. The methodology can be extended to address other uncertain parameters as far as the probability density function of the parameter is defined.