A rifted inside corner massif on the Mid-Atlantic Ridge at 5°S

The structure of the Mid-Atlantic Ridge at 5°S was investigated during a recent cruise with the FS Meteor. A major dextral transform fault (hereafter the 5°S FZ) offsets the ridge left-laterally by 80 km. Just south of the transform and to the west of the median valley, the inside corner (IC – the region bounded by the ridge and the active transform) is marked by a major massif, characterized by a corrugated upper surface. Fossil IC massifs can also be identified further to the west. Unusually, a massif almost as high as the IC massif also characterizes the outside corner (OC) south of the inactive fracture zone and to the east of the median valley. This OC massif has axis-parallel dimensions identical to the IC massif and both are bounded on their sides closest to the spreading axis by abrupt, steep slopes. An axial volcanic ridge is well developed in the median valley both south of the IC/OC massifs and in an abandoned rift valley to the east of the OC massif, but is absent along the new ridge-axis segment between the IC and OC massifs. Wide-angle seismic data show that between the massifs, the crust of the median valley thins markedly towards the FZ. These observations are consistent with the formation of the OC massif by the rifting of an IC core complex and the development of a new spreading centre between the IC and OC massifs. The split IC massif presents an opportunity to study the internal structure of the footwall of a detachment fault, from the corrugated fault surface to deeper beneath the fault, without recourse to drilling. Preliminary dredging recovered gabbros from the scarp slope of the rifted IC massif, and serpentinites and gabbros from the intersection of this scarp with the corrugated surface. This is compatible with a concentration of serpentinites along the detachment surface, even where the massif internally is largely plutonic in nature.     

Melting of β-quartz up to 2.0 GPa and thermodynamic optimization of the silica liquidus up to 6.0 GPa

Melting relations of β-quartz were experimentally determined at 1.0 GPa (1900±20 °C), 1.5 GPa (2033±20 °C), and 2.0 GPa (2145±20 °C) using a new high-pressure assembly in a piston–cylinder apparatus and substantial differences were found with data previously reported. The new melting data of β-quartz were combined and optimized with all available thermodynamic, volumetric, and phase equilibria data for β-cristobalite, β-quartz and coesite to produce a P–T liquidus diagram for silica valid up to 6.0 GPa. Using the new optimized thermodynamic parameters, the invariant point β-cristobalite+β-quartz+liquid and β-quartz+coesite+liquid were determined to lie at 1687±17 °C and 0.457 GPa, and 2425±25 °C and 5.00 GPa, respectively.     

Synthetic Seismograms and Wide-angle Seismic Attributes from the Gaussian Beam and Reflectivity Methods for Models with Interfaces and Velocity Gradients

— The effects of interfaces and velocity gradients on wide-angle seismic attributes are investigated using synthetic seismograms. The seismic attributes considered include envelope amplitude, pulse instantaneous frequency, and arrival time of selected phases. For models with interfaces and homogeneous layers, head waves can propagate which have lower amplitudes, as well as frequency content, compared to the direct arrivals. For media with interfaces and velocity gradients, higher amplitude diving waves and interference waves can also occur. The Gaussian beam and reflectivity methods are used to compute synthetic seismograms for simple models with interfaces and gradients. From the results of these methods, seismic attributes are obtained and compared. It was found that both methods were able to simulate wide-angle seismic attributes for the simple models considered. The advantage of using the Gaussian beam method for seismic modeling and inversion is that it is fast and also asymptotically valid for laterally varying media.     

Modelling Seismic Waves Around Underground Openings in Fractured Rock

—?The potential for large excavation-induced seismic events may be recognised, even if the timing of an event may be inherently unpredictable. In this case, modelling the wave propagation from a potential event could allow the dynamic motions around an excavation to be projected, and for areas of danger to be anticipated. However, the above and other potential applications require accurate models of wave interaction with the openings, as well as with the fractured rock which surrounds such excavations. This paper considers real recorded waveforms and how well these waveforms are modelled by explicit mechanical models of the source, the medium and the excavation. Models of experiments at three different scales of the problem are presented: small and large amplitude waveforms recorded around a deep-level mining tunnel in a synthetic rockburst experiment; waveforms from laboratory experiments of waves through plates of steel representing fractures; waveforms from active pulses in an acoustic emission experiment in a small volume of fractured rock at the surface of an underground excavation. The results show that elastic wave propagation around an excavation was a first approximation for small amplitude waves, but was less successful for modelling large amplitude waves and more fractured rock. Fractures in the models were represented explicitly with displacement discontinuities. Waveforms through known fracture geometries were particularly well-reproduced, and indicate the importance of fracture stiffness, the in situ stress state, and stress-dependence of the fractures in such models. Overall, the models are sufficiently successful at representing recorded behaviour, to be encouraging for the goal of representing accurate wave motions around excavations.     

The molecular universe

Helen J Fraser , Martin R S McCoustra and David A Williams present a simple guide to astrochemistry.
Molecules play a fundamental role in many regions of our universe. The science where chemistry and astronomy overlap is known as astrochemistry, a branch of astronomy that has risen in importance over recent years. In this article we review the significance of chemistry in several astronomical years. IN this article we review the significance of chemistry in several astronomical environments including the early universe, interstellar clouds, starforming regions and protoplanetary disks. We discuss theoretical models, laboratory experiments and observational data, and present several recent and exciting results that challenge our perception of the "molecular universe".     

Evaluation of Subsurface Structure at Soultz Hot Dry Rock Site by the AE Reflection Method in Time-frequency Domain

—?Because the Soultz Hot Dry Rock (HDR) site, France, is to be expanded to a scientific pilot plant of greater depth, measurement of the deep area below the predeveloped artificial reservoir is gaining importance. In this paper, we present estimates of deep subsurface structure at the Soultz HDR site, obtained by a reflection method using acoustic emission (AE) signals, that is, induced seismicity, as the wave source. First, we briefly describe the AE reflection method in the time-frequency domain with wavelet transform. Then we show estimates of the subsurface structure by using 101 high-energy AE events observed in 1993. We compare and discuss the results obtained, using the AE reflection method in two wells with other independent borehole observations. Furthermore, we present the results of an investigation of the frequency dependence of reflectors identified by hodogram linearity as a possible means of further characterizing detected structures.     

Causes of Geochemical Diversity of Carbon Dioxide Water in Crystalline Rock Masses

The problem of the diversity of the geochemical types of carbon dioxide waters (CDW) in petrografically and mineralogically uniform crystalline rock masses is solved with allowance made for the effect of different boundary conditions (physicochemical parameters) on the geochemical effect of interaction in the rock–water system. The formation of the entire geochemical spectrum of CDW in crystalline rock masses is shown to be explicable on the basis of a model of interaction in granite–water systems at different mass ratios of reacting rock (S) and water (L), different temperatures T, and equilibrium concentrations of dissolved CO₂ (P _CO2).     

Late Archaean to Palaeoproterozoic geotherms in the Kaapvaal craton, South Africa: constraints on the thermal evolution of the Witwatersrand Basin

The c. 2.97–2.71 Ga Witwatersrand Basin located in the Kaapvaal craton of South Africa represents a remnant of a large Late Archaean sedimentary basin that hosts the world's premier gold deposit within a series of conglomerate horizons. Evidence of postdepositional gold mobility within these conglomerates associated with hydrothermal–metamorphic activity has led to speculation about the Late Archaean to Palaeoproterozoic geothermal gradients in the basin. We use surface heat flow and heat production data from rocks in the basin and its environs in order to calculate detailed temperature profiles for the central Kaapvaal craton that show that the steady state crustal geotherm during the Late Archaean and Palaeoproterozoic was relatively cool at 15–20 K km^?1. The geotherm in the upper crustal strata is also largely unaffected by substantial increases in the heat flow into the base of the crust. Consequently, regional greenschist facies metamorphism of the basin sediments could only have been achieved during a transient thermal event that advected heat into the upper crust. The most likely candidate for this is the Bushveld magmatic event at 2.06 Ga.