Diffusion of Ar in muscovite

Hydrothermal treatment of closely sized muscovite aggregates in a piston-cylinder apparatus induced ⁴⁰Ar^∗ loss that is revealed in ⁴⁰Ar/³⁹Ar step heating spectra. Age spectra and Arrhenius data, however, differ from that expected from a single diffusion length scale. A numerical model of episodic loss assuming the presence of multiple diffusion domains yields excellent fits between synthetic and actual degassing spectra. We used this model to isolate ⁴⁰Ar^∗ loss from the grains that remained intact during hydrothermal treatment at 10 kbar permitting calculation of diffusion coefficients in the temperature range 730-600 °C. Diffusion data generated in this manner yield an activation energy (E) of 63 ± 7 kcal/mol and frequency factor (D_o) of 2.3  cm²/s. Experiments at 20 kbar yield diffusivities lower by about an order of magnitude and correspond to an activation volume of ∼14 cm³/mol. Together, these parameters predict substantially greater retentivity of Ar in muscovite than previously assumed and correspond to a closure temperature (T_c) of 425 °C for a 100 μm radius grain cooling at 10 °C/Ma at 10 kbar (T_c = 405 °C at 5 kbar. Age and log (r/r_o) spectra for the run products show strong correlations indicating that muscovites can retain Ar diffusion boundaries and mechanisms that define their natural retentivity during vacuum step heating. This may permit the application of high resolution, continuous ⁴⁰Ar/³⁹Ar thermochronology to low grade, regionally metamorphosed terranes.     

Potential of Satellite Remote Sensing and GIS for Landslide Hazard Assessment in Southern Kyrgyzstan (Central Asia)

Big landslides are one of the main natural hazards in Kyrgyzstan, which are concentrated in the foothills of the high mountain ranges along the Eastern rim of the Fergana Basin. Because of the high number of landslides and their occurrence over large areas there is a strong need for effective and objective landslide hazard assessment at a regional scale. In Kyrgyzstan satellite remote sensing data represent the only source of multitemporal information about surface conditions covering large areas. Against this background the goal is the development of a satellite remote sensing and GIS-based system for quantitatively oriented and spatially differentiated hazard assessment. During the presented pilot investigations in the area of the Upper Maili Suu river basin a methodological framework has been developed incorporating remote sensing and GIS techniques for various levels of information extraction. So far, methodological investigations have been focused on the potential of satellite remote sensing data from different optical (Landsat-(E)TM, ASTER, MOMS-2P) and radar (ERS-1/2) systems for the creation of an improved knowledge basis for hazard assessment. This includes landslide identification, generation of topographic information and characterization of the geological setting. The derived primary information have been analyzed in a GIS environment to gain an improved process understanding as a main prerequisite for successful hazard assessment. The results show that currently available satellite remote sensing data are suitable for landslide investigation in Kyrgyzstan. Full exploitation of their information potential requires combined analysis with other thematic information based on methods of interactive and automated information extraction.     

Über den Einfluß von Meeresspiegelschwankungen auf Flachwassersedimente im Schwäbischen Jura

Zusammenfassung Im Ablagerungsbecken des Unteren Lias und Dogger dürften, wenn nicht Ebbe und Flut, so doch aperiodische Schwankungen des Meeresspiegels um mehrer Meter aufgetreten sein. Durch die Spiegelschwankungen wird das Sedimentgefüge in von Ort zu Ort wechselndem Ausmaß geändert, austretendes Porenwasser trägt außerdem zur Sedimentbildung bei.

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Summary Aperiodic fluctuations of sea level, caused by wind, during some periods of Lower and Middle Jurassic in Southern Germany should have had similar effects as tides in Watten today, altering the fabric of sediments and bringing pore water low in pH and eH to the surface. Glauconite and Chamosite may have been formed by mixing of normal sea water with pore water.

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Mit 1 Textabbildung

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Herrn Professor Dr.F. Machatschki zum 70. Geburtstag gewidmet.     

Escape models of the Alpine-Carpathian-Pannonian region in the light of palaeomagnetic observations

Recent tectonic models of the Alpine-Carpatho-Pannonian region (ALCAPA) assume a large eastward shift of the Transdanubian Range domain, in the Cenozoic. Since palaeomagnetism is one of the most powerful tools in solving geodynamic processes, the authors present an approach to the escape problem by using all available and relevant palaeomagnetic data. This data set demonstrates consistency with models put forward by geologists for Jurassic and older ages. From the mid-Jurassic on the Northern Calcareous Alps (NCA) did not share the rotations of the Transdanubian Range domain and of the Southern Alps. After individual movements from Neocomian to Miocene, the Transdanubian Range domain must have drifted northward in the mid-Miocene up to the Southern margin of the Northern Calcareous Alps, before starting the escape in the geologists' definition.     

Zircon formation during fluid circulation in eclogites (Monviso, Western Alps): implications for Zr and Hf budget in subduction zones

The zircons from an eclogite and an enclosed eclogite-facies vein from the Monviso ophiolite (Western Alps) display contrasting chemical and morphologic features and document different stages of the evolution of the ophiolite. The zircons from the eclogite show a typical magmatic zoning and are enriched in heavy rare earth elements (HREEs) over middle rare earth elements (MREEs) and have an accentuated negative Eu anomaly, which indicates that the grains co-crystallised with plagioclase. These magmatic zircons document the formation of oceanic crust at 163 ± 2 Ma. In contrast, zircons from the vein contain inclusions of garnet, omphacite, and rutile, which indicate that they crystallised under eclogite-facies conditions. The vein zircons have Th/U ratios < 0.09, lack Eu anomalies, and are only weakly enriched in HREE with respect to MREE. These features are consistent with a garnet-bearing, plagioclase-free, i.e., eclogite-facies paragenesis. Vein zircons yield an age of 45 ± 1 Ma, which is evidence for Eocene subduction-zone metamorphism of the Monviso ophiolite.In the vein, the apparent coexistence of zircon, omphacite, and garnet permits the determination of a set of trace element distribution coefficients among these minerals at high pressure. This set of partitioning can demonstrate chemical equilibrium among these phases in rocks that show less clear evidence of textural equilibrium. In addition, zircon age can now be linked to sensors of metamorphic pressure-temperature conditions. The presence of zircon and rutile in the vein is another example of high field strength element (HFSE) mobility over short distances in aqueous fluids at eclogite-facies conditions. However, the concentrations of Zr and Hf in the aqueous fluid are estimated to be at least a factor of 10 less than primitive mantle values.Mass balance calculations demonstrate that zircon hosts > 95% of the bulk Zr, 90% of Hf, and ∼25% of U in the vein. Zircon is a residual phase in subducted basalts and sediments up to temperatures of at least 800 to 900 °C. Therefore, residual zircon in subducted crust, together with rutile, control the HFSE in liberated subduction zone fluids/melts and might be partly responsible for negative Zr and Hf anomalies in subduction zone magmas.     

Environmental changes in southeastern Amazonia during the last 25,000 yr revealed from a paleoecological record

New pollen, micro-charcoal, sediment and mineral analyses of a radiocarbon-dated sediment core from the Serra Sul dos Carajás (southeast Amazonia) indicate changes between drier and wetter climatic conditions during the past 25,000 yr, reflected by fire events, expansion of savanna vegetation and no-analog Amazonian forest communities. A cool and dry last glacial maximum (LGM) and late glacial were followed by a wet phase in the early Holocene lasting for ca. 1200 yr, when tropical forest occurred under stable humid conditions. Subsequently, an increasingly warm, seasonal climate established. The onset of seasonality falls within the early Holocene warm period, with possibly longer dry seasons from 10,200 to 3400 cal yr BP, and an explicitly drier phase from 9000 to 3700 cal yr BP. Modern conditions with shorter dry seasons became established after 3400 cal yr BP. Taken together with paleoenvironmental evidence from elsewhere in the Amazon Basin, the observed changes in late Pleistocene and Holocene vegetation in the Serra Sul dos Carajás likely reflect large-scale shifts in precipitation patterns driven by the latitudinal displacement of the Inter-Tropical Convergence Zone and changes in sea-surface temperatures in the tropical Atlantic.     

Spatial and temporal changes in dry-snow line altitude on the Antarctic Peninsula

Drastic changes were detected in glacial systems of the Antarctic Peninsula in the last decades. The observed phenomena comprise the disintegration of ice shelves, acceleration and thinning of glaciers, and retreat of glacier fronts. However, due to the lack of consistent systematic observations in particular of the higher parts of the glacial systems, it is difficult to predict further responses of the Antarctic Peninsula glaciers to climatic change. The present paper analyses spatial and temporal variations of changes in the dry-snow line altitude on the Antarctic Peninsula as extracted from a time series (1992–2005) of ERS-1/2 SAR and Envisat ASAR data. Upward changes in dry-snow line altitude were observed in general, and are attributed to extreme high-temperature events impacting the central plateaus of the Antarctic Peninsula and the increasing duration of warming periods. A mean decrease in dry-snow line altitude was detected on the west side of the peninsula and is identified as a response to recorded increase in precipitation and accumulation. These results validate the capability of SAR data for deriving superficial parameters of glaciers to be used as indicators of climatic changes in high-latitude regions where operational restrictions limit conventional meteorological observations.