Nontronite synthesis at low temperatures

The low-temperature synthesis of clay minerals is possible through the aging of freshly prepared hydroxide—silica precipitates. The rapid synthesis of nontronite is only possible at surface temperatures under reducing conditions. Under oxidizing conditions, pure Fe(III)- or pure Al-smectite minerals could not be synthesized at low temperatures. It is only from Fe(II)-containing solutions that nontronite and lembergite, the di-[Fe(III)] and tri-[Fe(II)] octahedral three-layer silicates, are built up in several days at low temperatures. The presence of Fe(II) enables an octahedral layer of the brucite—gibbsite type to be formed. These are necessary for the bidimensional orientation of SiO₄ tetrahedrons, leading to clay-mineral formation. The Fe²⁺ and/or Mg²⁺ ions are necessary for the formation of the Al³⁺- and Fe³⁺-containing three-layer silicate minerals.Under reducing diagenetic conditions, the Fe contents in recent sediments are sufficient to build up Al-rich three-layer minerals under both fresh-water and salt-water conditions.     

An energy tax to reduce the greenhouse effect: An all winners concept

This is based on a concept worked out by EUROSOLAR, an Association for the Solar Energy Age, of which Hermann Scheer is chairman and Wilfrid Bach is a member of the board.     

Simulation Experiments with Cometary Analogous Material

Comet simulation experiments are discussed, in the context of physical models and the results in cometary physics, gathered especially from the GIOTTO space mission to comet P'Halley. The “status of the today knowledge” about comets, the experiments could start from, is briefly reviewed. The setup of the KOSI (German = Kometen Simulation) - experiments and the techniques to produce cometary analogous material, on the basis of that knowledge are described in general, as for the different KOSI experiments. The limitations of the simulation of physical processes at the surface of real comets in an earth-bound laboratory are discussed, and the possibilities to receive common insights in cometary physics are shown. Methods and procedures are described, and the major results reviewed. As with attempting to reproduce any natural phenomenon in the laboratory, there are short-comings to these experiments, but there are possibly major new insights to be gained. Physical laws only have the same consequences under same experimental or environmental conditions. A number of small-scale comet simulation experiments have been performed, since the early 60ties in many laboratories, but the largest and most ambitious series of comet simulation experiments to date were performed between 1987 and 1993 using the German space agency's (DLR) space hardware testing facilities in Cologne. These experiments were triggered by the scientific community after the comet P'Halley's recurrence in 1986 and the many data gathered by the space missions in this year. Simulation experiments have proved valuable in developing methods for making cometary analogues, and for exploring specific properties of such materials in detail. These experiments provided new insights into the morphology and physical behavior of aggregates formed out of silicate- /water-ice -grains likely to exist in comets. The formation of a dust mantle on the surface, and a system of ice layers below the mantle from the different admixed materials, have been detected after the insolation of the artificial comet. The mechanisms for heat transfer between the comet's surface and its interior, compositional, structural, and isotopic changes that occur near the comet's surface, were described by modeling in accordance with the experimental results. The mechanisms of the ejection of dust and ice grains from the surface, and the importance of gas-drag in propelling grains were investigated by close-up video cameras. This revised version was published online in July 2006 with corrections to the Cover Date.     

Preface

Earth, Moon, and Planets -     

Characteristics of the multi-telescope coincidence trigger of the HEGRA IACT system

The HEGRA-collaboration is operating a system of imaging atmospheric Cherenkov telescopes to search for sources of TeV-γ-rays. Air showers are observed in stereoscopic mode with several telescopes simultaneously. To trigger the telescope system a versatile two-level trigger scheme has been implemented, which allows a significant reduction of the energy threshold with respect to single telescopes. The technical implementation of this trigger scheme and the performance of the trigger system are described. Results include the dependence of single- and multi-telescope trigger rates on the trigger thresholds, on the orientation of the telescopes, and on the type of the primary particle.     

Evidence for Late Carboniferous subduction-type magmatism in mafic-ultramafic cumulates of the SW Tauern window (Eastern Alps)

Hectometric bodies of fresh mafic-ultramafic cumulates have been discovered within the Central Gneiss of the Zillertal massif, SW Tauern window (eastern Alps, Italy). The cumulates, intruded by the Central Gneiss granitoids, are amphibole-bearing harzburgites and norites made of cumulitic olivine (Fo_73-80), spinels, sulphides and plagioclase (An_79-87), included in orthopyroxene (En_76-83) and Ti-pargasite (Mg#=0.73-0.81). Major and trace element geochemistry indicates that these rocks represent olivine + spinel - plagioclase cumulates, in which interstitial melt crystallized as orthopyroxene + Ti-pargasite. The parental melt has trace element patterns typical of subduction zone magmas. The crystallization sequence, mineral compositions, and modes indicate that cumulates formed from a H₂O-rich basaltic andesite, which intruded at low-pressure (~2 kbar) and temperatures of 1,050-1,100 °C. SHRIMP U-Pb dating of zircons from ultramafic cumulates and adjacent metagranodiorite yielded ages of 309LJ and 295Dž Ma, respectively. In agreement with field relationships, these results show that the mafic-ultramafic cumulates represent a co-genetic, early product of the Late Carboniferous plutonic activity in the western Tauern window, which started in the Westphalian, earlier than previously thought. Our data on the most primitive rocks in the Zillertal massif permit, for the first time, insight into the parental magma and thus into the origin of this Late Carboniferous calc-alkaline magmatism, which was most likely related to slab break off during the Late Variscan convergence.