Contrasting variability in foraminiferal and organic paleotemperature proxies in sedimenting particles of the Mozambique Channel (SW Indian Ocean)

Accurate sea surface temperature (SST) proxies are important for understanding past ocean and climate systems. Here, we examine material collected from a deep-moored sediment trap in the Mozambique Channel (SW Indian Ocean) to constrain and compare both inorganic (δ¹⁸O, Mg/Ca) and organic (, TEX₈₆) temperature proxies in a highly dynamic oceanographic setting for application in paleoceanography. High-resolution time-series current velocity data from long-term moorings (2003 - present) deployed across the Mozambique Channel reveal the periodic migration of four to six meso-scale eddies through the channel per year. These meso-scale eddies strongly influence water mass properties including temperature and salinity. Despite the dynamic oceanographic setting, fluxes of the surface-dwelling planktonic foraminifera Globigerinoidesruber and Globigerinoides trilobus follow a seasonal pattern. Temperatures reconstructed from G. ruber and G. trilobus δ¹⁸O and Mg/Ca closely mirror seasonal SST variability and their flux-weighted annual mean SSTs of 28.1 °C and 27.3 °C are in close agreement with annual mean satellite SST (27.6 °C). The sub-surface dwelling foraminifera Neogloboquadrina dutertrei and Globigerinoides scitula recorded high-frequency temperature variations that, on average, reflect conditions at water depths of 50-70 m and 200-250 m, respectively. Concentrations and fluxes of organic compounds (alkenones and crenarchaeol) display no or only moderate seasonality but flux weighted means of the associated temperature signatures, , and of 28.3 °C and 28.1 °C, respectively, also closely reflect mean annual SST. We analyzed all time-series data using multiple statistical approaches including cross-correlation and spectral analysis. Eddy variability was clearly expressed in the statistical analysis of physical oceanographic parameters (current velocity and sub-surface temperature) and revealed a frequency of four to six cycles per year. In contrast, statistical analysis of proxy data from the sediment trap did not reveal a significant coupling between eddy migration and organic compound fluxes or reconstructed temperatures. This is likely a result of the relatively low resolution (21 days) and short (2.5 years) duration of the time series, which is close to the detection limit of the eddy frequency.     

Direct terrestrial-marine correlation demonstrates surprisingly late onset of the last interglacial in central Europe

An interdisciplinary study of a small sedimentary basin at Neumark Nord 2 (NN2), Germany, has yielded a high-resolution record of the palaeomagnetic Blake Event, which we are able to place at the early part of the last interglacial pollen sequence documented from the same section. We use this data to calculate the duration of this stratigraphically important event at 3400 ± 350 yr. More importantly, the Neumark Nord 2 data enables precise terrestrial-marine correlation for the Eemian stage in central Europe. This shows a remarkably large time lag of ca. 5000 yr between the MIS 5e ‘peak’ in the marine record and the start of the last interglacial in this region.     

UHP metamorphism recorded by kyanite-bearing eclogite in the Seve Nappe Complex of northern Jämtland,Swedish Caledonides

The first evidence for ultrahigh-pressure (UHP) metamorphism in the Seve Nappe Complex of the Scandinavian Caledonides is recorded by kyanite-bearing eclogite, found in a basic dyke within a garnet peridotite body exposed close to the lake Friningen in northern Jämtland (central Sweden). UHP metamorphic conditions of ~ 3 GPa and 800 °C, within the stability field of coesite, are constrained from geothermobarometry and calculated phase equilibria for the peak-pressure assemblage garnet + omphacite + kyanite + phengite. A prograde metamorphic evolution from a lower P–T (1.5–1.7 GPa and 700–750 °C) stage during subduction is inferred from inclusions of pargasitic amphibole, zoisite and kyanite in garnet cores. The post-UHP evolution is constrained from breakdown textures, such as exsolutions of kyanite and silica from the Ca-Eskola clinopyroxene. Near isothermal decompression of eclogite to lower crustal levels (~ 0.8–1.0 GPa ) led to formation of sapphirine, spinel, orthopyroxene and diopside at granulite facies conditions. Published age data suggest a Late Ordovician (460–445 Ma) age of the UHP metamorphism, interpreted to be related to subduction of Baltoscandian continental margin underneath an outboard terrane, possibly outermost Laurentia, during the final stages of closure of the Iapetus Ocean. The UHP rocks were emplaced from the hinterland collision zone during Scandian thrusting of the nappes onto the Baltoscandian foreland basin and platform. The record of P–T conditions and geochonological data from UHP rocks occurring within the allochthonous units of the Scandinavian Caledonides indicate that Ordovician UHP events may have affected much wider parts of the orogen than previously thought, involving deep subduction of the continental crust prior to final Scandian collision between Baltica and Laurentia.     

Effect of ENSO events on sediment production in a large coastal basin in northern Peru

Although the importance of ENSO on hydrological anomalies has been recognized, variations in sediment fluxes caused by these extreme events are poorly documented. The effect of ENSO is not limited to changes in sediment mobilization. Since ENSO events can affect terrestrial ecosystems, they may have important effects on sediment production and transport in river basins over time spans that are longer than the duration of the event itself. The Catamayo‐Chira basin is an interesting casestudy for investigating these geomorphic implications. The objectives were: (i) to study the effect of ENSO on stream flow and sediment yields in the basin, (ii) to investigate if ENSO events affect sediment yields in the post‐ENSO period and (iii) to understand which factors control the ENSO and post‐ENSO basin response. During strong negative ENSO periods, mean annual stream flow discharge at the inlet of the Poechos reservoir in the lower basin was 5.4 times higher than normal annual discharges, while average sediment fluxes exceeded those of normal years by a factor of about 11. In two heavily affected periods, 45.9% of the total sediment yield in the 29 years observation period was generated. Sediment fluxes in the post‐ENSO period are lower than expected, which proves post‐ENSO event dynamics are significantly different from pre‐event dynamics. Our analysis indicates the increase of vegetation growth in the lower basin is not the main reason explaining considerable sediment flux decrease in post‐ENSO periods. During strong ENSO events, sediment in alluvial stores in the lower part of the basin is removed due to enlarging and deepening of channels. In post‐ENSO periods, normal discharges and persisting sediment supplies from the middle/upper basin lead to river aggradation and storage of large amounts of sediment in alluvial plains. The decrease in sediment export will last for several years until the equilibrium is re‐established. Copyright © 2011 John Wiley & Sons, Ltd.     

Long-term evolution of sand waves in the Marsdiep inlet. II: Relation to hydrodynamics

A discussion is presented about the mechanisms that govern the spatial and seasonal variability in sand-wave height and migration speed in the 4 km wide Marsdiep tidal inlet, the Netherlands. Since 1998, current velocities and water depths have been recorded with an ADCP that is mounted under the ferry ‘Schulpengat’. In this paper, the current measurements were used to explain the sand-wave observations presented in Buijsman and Ridderinkhof [this issue. Long-term evolution of sand waves in the Marsdiep inlet. I: high-resolution observations. Continental Shelf Research, doi:10.1016/j.csr.2007.10.011]. Across nearly the entire inlet, the sand waves migrate in the flood direction. In the flood-dominated southern part of the inlet, the ‘measured’ (i.e. based on sand-wave shape and migration speed) and predicted bedload transport agree in direction, magnitude, and trends, whereas in the ebb-dominated northern part the predicted bedload and suspended load transport is opposite to the sand-wave migration. In the southern part, 55% of the bedload transport is due to tidal asymmetries and 45% due to residual currents. In addition to the well-known tidal asymmetries, asymmetries that arise from the interaction of _M2${\mathrm{M}}_2$ and its overtides with _S2${\mathrm{S}}_2$ and its compound tides are also important. It is hypothesised that in the northern part of the inlet the advection of suspended sand and lag effects govern the sand-wave migration. The relative importance of suspended load transport also explains why the sand waves have smaller lee-slope angles, are smaller, more rounded, and more three-dimensional in the northern half of the inlet. The sand waves in this part of the inlet feature the largest seasonal variability in height and migration speed. This seasonal variability may be attributed to the tides or a seasonal fluctuation in fall velocity. In both cases sediment transport is enhanced in winter, increasing sand-wave migration and decreasing sand-wave height. The influence of storms and estuarine circulation on the sand-wave variability is negligible.     

Modeling bio-geomorphological influences for offshore sandwaves

The coastal environment shows a wide range of bed patterns, for which sandwaves and sandbanks are among the most common. Less known in this context is the high benthic diversity in the coastal environment, which gives rise to the question to what extend the benthos interacts with the shape of the seabed. This paper reviews field and flume experiments on bio-geomorphological influences between benthos and sediment and tests the hypothesis that both the occurrence and the dimensions of sandwaves are dependent on the benthic diversity in the North Sea. Mathematical inclusions to account for biological activity in idealized models reveal that biota is able to influence the wavelength of sandwaves significantly, compared to the default case. More importantly, the models indicate that biota is able to induce bed patterns under conditions when the physical parameters suggest a stable flat bed and vice versa. Present model explorations indicate that future research should focus on the parameterization of subtidal biological activity on sediment dynamics and thereby on seabed patterns. Such knowledge will enable process-based modeling of the spatial and temporal variation in biological activity on seabed morphodynamics and validate the proposed modeling approach with field measurements.     

Macrocrystal phlogopite Rb–Sr dates for the Ekati property kimberlites, Slave Province, Canada: evidence for multiple intrusive episodes in the Paleocene and Eocene

New Rb–Sr age determinations using macrocrystal phlogopite are presented for 27 kimberlites from the Ekati property of the Lac de Gras region, Slave Province, Canada. These new data show that kimberlite magmatism at Ekati ranges in age from at least Late Paleocene (61 Ma) to Middle Eocene time (45 Ma). Older, perovskite-bearing kimberlites from Ekati extend this age range to Late Cretaceous time (74 Ma). Within this age range, emplacement episodes at 48, 51–53, 55–56 and 59–61 Ma can be recognized. Middle Eocene kimberlite magmatism of the previously dated Mark kimberlite (47.5 Ma) is shown to include four other pipes from the east-central Ekati property. A single kimberlite (Aaron) may be younger than the 47.5 Ma Mark kimberlite. The economically important Panda kimberlite is precisely dated in this study to be 53.3±0.6 Ma using the phlogopite isochron method, and up to six additional kimberlites from the central Ekati property have Early Eocene ages indistinguishable from that of Panda, including the Koala and Koala North occurrences. Late Paleocene 55–56 Ma kimberlite magmatism, represented by the Diavik kimberlite pipes adjacent to the southeastern Ekati property, is shown to extend onto the southeastern Ekati property and includes three, and possibly four, kimberlites. A precise eight-point phlogopite isochron for the Cobra South kimberlite yields an emplacement age of 59.7±0.4 Ma; eight other kimberlites from across the Ekati property have similar Late Paleocene Rb–Sr model ages. The addition of 27 new emplacement ages for kimberlites from the Ekati property confirms that kimberlite magmatism from the central Slave Province is geologically young, despite ages ranging back to Cambrian time from elsewhere in the Slave Province. With the available geochronologic database, Lac de Gras kimberlites with the highest diamond potential are currently restricted to the 51–53 and 55–56 Ma periods of kimberlite magmatism.     

Trace element distribution in the soils above deeply weathered pegmatites, Virginia, U.S.A.: implications for exploration

Chemical partitioning data are of fundamental interest to exploration geochemists. This paper is one of the few studies which has investigated the relative proportions of the rare elements in various soil extracts. The dispersion of trace elements from weathering pegmatites in Powhatan Country, Virginia, was found to be restricted to the immediate vicinity of the pegmatites. A sequential extraction procedure was used to measure the distribution of Be, La, Nb, Sn, U, Li, and Ni,among the following fractions of the B soil horizons: exchangeable, Fe and Mn oxyhydroxide, residual, and aqua regia digestion. The elements Sn, Be, Li, and U were found to be associated with soils over the complex Herbb No. 2 pegmatite, whereas La and Ni were generally associated with the background soils.A geochemical exploration model was developed using stepwise discriminant function analysis to determine the combination of elements and soil extracts that best differentiates between complex pegmatitic, simple pegmatitic, and background soils. Log-transformed aqua regia extract concentrations of Sn, La, U, and Li were the most effective variables when used to separate complex pegmatitic from simple pegmatitic soils.     

Deformation and recrystallisation mechanisms in naturally deformed cordierite

Cordierite — (Mg,Fe)₂Al₄Si₅O₁₈ — occurs as porphyroclasts within metapelitic and metavolcanic rocks from the Kemiö-Orijärvi belt, SW Finland. After crystallisation the cordierites have been deformed at temperatures between 550–825° C and pressures of 3–5 kbar. Optical microscopy reveals the following deformation-induced microstructures: a bimodal size distribution between host, 0.3 to 4.0 mm, and recrystallised (new) grains, 0.1 to 0.5 mm; the intracrystalline defect-structures of host grains yield undulatory extinction, subgrains and some twinning. Recrystallised grains are optically strain free. Grain and subgrain boundaries are generally straight and parallel to crystallographic low-index planes. Orientation distribution diagrams for host and recrystallised grains yield similar fabric diagrams, i.e. [010] perpendicular to foliation -S-, [001] and [100] parallel to S and [001] parallel to lineation -L-. The fabric diagrams indicate that [001] (010) is the dominant slip system. Transmission electron microscopy reveals straight free dislocations, glide and climb loops, minor {130} and {110} microtwins, isolated nodal points and dislocation walls. Contrast analyses yield Burgers vector b = [001] being dominant and b = [100] subordinate. Climb loops consist of 〈c〉-dislocations that are dissociated in (001) planes, glide loops are defined by [100] [010] and [001] (100). The cordierite microstructures have been interpreted to be generated by dislocation creep. The dominant recrystallisation mechanism is thought to be subgrain rotation subsequently followed by minor grain or twin-band boundary migration.