The multiple chronological techniques applied to the Lake Suigetsu SG06 sediment core,central Japan

The varved sediment of Lake Suigetsu (central Japan) provides a valuable opportunity to obtain high‐resolution, multi‐proxy palaeoenvironmental data across the last glacial/interglacial cycle. In order to maximize the potential of this archive, a well‐constrained chronology is required. This paper outlines the multiple geochronological techniques being applied – namely varve counting, radiocarbon dating, tephrochronology (including argon–argon dating) and optically stimulated luminescence (OSL) – and the approaches by which these techniques are being integrated to form a single, coherent, robust chronology. Importantly, we also describe here the linkage of the floating Lake Suigetsu (SG06) varve chronology and the absolute (IntCal09 tree‐ring) time scale, as derived using radiocarbon data from the uppermost (non‐varved) portion of the core. This tie‐point, defined as a distinct (flood) marker horizon in SG06 (event layer B‐07–08 at 1397.4 cm composite depth), is thus derived to be 11 255 to 11 222 IntCal09 cal. years BP (68.2% probability range).     

Acidic deposition impacts mediated by sulfur cycling in a coastal plain forest ecosystem

Deposition in the New Jersey Pinelands was very acidic (pH=4.17) and contained high levels of SO₂ ⁻² based on bulk deposition measurementsfrom July 1984–July 1986. Streamwater over the same interval in undisturbed watersheds was less acidic (pH =4.52) and had proportionately less SO₄ ⁻². A preliminary alkalinity budget for undisturbed watersheds suggested that SO₄ ⁻² retention within Pinelands watersheds accounted for a large portion of the total alkalinity generated and thereby lessened the impact of acidic deposition on surface waters. The only process capable of explaining the retention of SO₄ ⁻² was microbial sulfate reduction in the extensive wetlands surrounding Pinelands streams which occurred at high rates.     

The surface of labradorite feldspar after acid hydrolysis

After reaction with a pH < 4, the surface of labradorite is extensively enriched in Si and H, and depleted in Al, Ca and Na relative to an unreacted crystal. However, the amount of hydrogen measured in the reacted surface is less than that predicted on the basis of exchange of hydrogen (or hydronium) ions for cations in the feldspar. By analogy with studies of silicate glass, this low concentration of hydrogen suggests that some silanol groups in the reacted surface repolymerize subsequent to ion-exchange and depolymerization reactions. The net result is a relatively porous, Si-rich leached layer which is amorphous to electron diffraction, and which allows rapid diffusion of unreactive solutes.

Both the surface area of the reacted feldspar and the porosity increase with acid hydrolysis. Modeling of nitrogen sorption onto the surface suggests that the pores have a nominal radius of 20–80 Å or less. This distribution of pore sizes resembles other acid-reacted silicate materials, such as glass, chrysotile and kaolinite. Although the mineral surface clearly becomes more porous during acid hydrolysis, the increase in powder area also does not coincide with an increase in the flux of dissolved Si from the powder. We thus attribute most of this increase in area to spallation of the silica-rich surface from the feldspar upon drying.     

Cumulate gabbros from the Southwest Indian Ridge, 54°S-7° 16′ E: implications for magmatic processes at a slow spreading ridge

A diverse volcanic and plutonic rock suite was recovered from the center of the 80 km long ridge segment of the Southwest Indian Ridge (54°S, 7°16 E) between the Islas Orcadas and Shaka Fracture Zones. The cumulus nature of the gabbroic rocks in the suite is indicated by phase, modal and cryptic layering, igneous lamination, and low incompatible element abundances. We present a mass-balance model for calculating the proportions and compositions of cumulus phases and crystallized intercumulus liquid from bulk-rock major element compositions. The model is based on the ability to define a compositional array of basaltic liquids and on the assumption that cumulus minerals are initially in equilibrium with trapped liquid. Calculated proportions of trapped liquid range from 3%–15%; values that are characteristic of adcumulates to mesocumulates. Models of postcumulus crystallization indicate significant enrichments of incompatible elements and buffering of compatible elements in residual trapped liquids, thus explaining the high TiO₂ contents observed in magnesian clinopyroxenes. Cumulus phase assemblages and compositions suggest solidification in shallow level magma chambers, but disequilibrium plagioclase compositions suggest some crystallization at greater depth. Furthermore, basalt compositions projected onto the olivine-clinopyroxenequartz pseudoternary suggest magma generation over a range of pressures (from less than 10 to greater than 20 kb) as well as polybaric fractional crystallization. We suggest that the Southwest Indian Ridge is characterized by low magma supply with small batches of melt that either ascend directly to the surface having undergone limited polybaric crystallization or are trapped in shallow crustal magma chambers where they evolve and solidify to form cumulate gabbros. The adcumulus nature of the gabbros investigated here suggests slow cooling rates typical of large intrusions implying relatively large, but ephemeral magma chambers below segments of the Southwest Indian Ridge.     

Modern and ancient geotherms beneath southern Africa

Estimates of subsurface temperatures in the Archean craton of southern Africa during the Archean derived from diamond thermobarometry studies are remarkably similar to temperatures estimated for the same depths today, even though heat production in the earth and the mean global heat flow were probably substantially higher in the Archean. We present multi-dimensional numerical models for the thermal environment of the Archean craton in southern Africa during the Archean in which deep mantle heat is diverted away from the craton toward the surrounding oceanic lithosphere by a lithospheric root beneath the craton. Extrapolation of present-day models to thermal conditions appropriate for the Archean is inadequate to explain the similarity of present-day and Archean temperatures in the cratonic root. Reconciliation of the modern and ancient temperature estimates requires either relaxation of the constraints that the cratonic crustal heat production and/or the earth's mean mantle temperature were higher in the Archean than they are today, or that substantial “erosion” of the lithosphere comprising the cratonic root has occurred since the Archean. The latter possibility could perhaps result from revolatilization of the cratonic root in association with thermal perturbations in the mantle, for which there is evidence in southern Africa in the form of post-Archean tectonic and igneous activity.     

High-resolution garnet chronometry and the rates of metamorphic processes

Garnets in an amphibolite-facies metasediment from Sulitjelma, North Norway yield precise and concordant SmNd, UPb and RbSr ages that relate directly to the pressure (P) and temperature (T) conditions of mineral growth. Differential mineral reaction between graphitic and non-graphitic layers within this sample preserves a record of theP-T and time (t) history experienced during Barrovian regional metamorphism. Garnets in graphitic layers grew during prograde metamorphism at462 ± 16°C and5.2 ± 0.5 kbar under conditions of lowaH₂O, and yield indistinguishable¹⁴⁷Sm¹⁴³Nd and²³⁸U²⁰⁶Pb ages of434.1 ± 1.2 Ma and433.9 ± 1.0 Ma, respectively. In contrast, garnet growth in adjacent graphite-free layers did not occur untilP-T conditions of540 ± 18°C and8.0 ± 1.0 kbar were attained, with continued growth in response to minor heating and decompression with final matrix equilibration at544 ± 16°C and7.0 ± 1.0 kbar. The inclusion-free garnet rims in this assemblage record indistinguishable¹⁴⁷Sm¹⁴³Nd and²³⁸U²⁰⁶Pb ages of424.6 ± 1.2 Ma and423.4± 1.7 Ma, respectively. These results provide precise estimates for average heating and burial rates during prograde metamorphism of 8.6_−4.4^+7.5°C Ma⁻¹ and 0.8_−0.5^+0.9 km Ma⁻¹, respectively. Rb and Sr exchange between coexisting silicates in the graphite-free assemblage continued for some 37 Ma after the “peak” of metamorphism, and require an average cooling rate of about 4.0°C Ma⁻¹ during uplift. These results illustrate a clear relationship between reaction history and the timing of mineral growth and provide definitive constraints on the rates of thermal and tectonic processes accompanying regional metamorphism.     

A numerical investigation of the JASIN atmospheric boundary layer

A numerical model of the cloudy marine boundary layer is described and used to investigate the role of entrainment instability on the developing boundary layer. In general, previous studies have been limited to boundary layers capped by convectively stable inversions or have described only cumulus fields. Here we extend a stratus-capped boundary-layer model to consider the transition to a convectively unstable cloud layer capped by an inversion across which there is a rapid decrease in wet-bulb or equivalent potential temperature. In this case, the inversion is very active and the entrainment rate is determined by the active instability at the interface, in contrast to the mean turbulent motion within the boundary layer.The model is used to interpret the observed boundary layer from the JASIN experiment. Cool, dry air is modified by prolonged passage over increasingly warmer ocean which leads to the development of a convectively unstable cloud layer.     

The status and prospects of risk assessment

After discussing the changing nature of perceived risk problems, the status of risk assessment is described in relation to its origins and in particular to its roots in the environmental impact statement process. The nature of risk, its component elements and the manner in which existing concepts of risk have been reflected in risk assessment methods are described. The paper considers two emerging schools of thought in current risk assessment studies: one that calls for more accurate measures of risk and increasingly comprehensive event prediction models to determine risk acceptability and another which argues that the acceptance of risk is less dependent on the accuracy of risk analyses than it is on the nature of the decision-making process and in particular on whether compensation is provided for those bearing a disproportionate share of risk.     

Finite strain patterns and their significance in Permian rocks of the Alpes Maritimes (France)

More finite strain data has been obtained from autochthonous Permian mudstones of the Alpes Maritimes, S.E. France. These new data were computed from field measurements of green spots on all available sections, deformed mudcracks and from the quantitative correlation between magnetic susceptibility anisotropy and finite strain in these rocks. Previously published finite strain data and the new results are presented on a series of structural maps and cross-sections for the Dôme de Barrot, the Tinée and Vionène region and the Roya region. As in previous studies difficulties arise in explaining the apparently variable extension parallel with the 100°, subhorizontal bedding-cleavage intersection: either this is real or there were large volume changes during the tectonic deformation. Study of quartz fibres, developed in deformed mudcracks in the Tinée valley, suggest that early in the tectonic history incremental stretching directions were parallel with the bedding—cleavage intersection, while later they were down-dip in the 100° trending cleavage. Since these Permian rocks have remained stuck to the Argentera basement they also record displacements and deformations in the basement. The early 100°, subhorizontal stretching is consistent with NW-SE dextral, strike-slip basement faulting, while later, down-dip stretching in the cleavage is consistent with contraction faults in the basement. This information and new palaeomagnetic data on the same samples are combined with recent geophysical evidence and regional tectonic studies, to provide a new precision to the tectonic history of this part of the Western Alpine External Zone.