Geological and SHRIMP II U-Pb constraints on the age and origin of the Breves Cu-Au-(W-Bi-Sn) deposit,Carajás,Brazil

The Breves deposit in the Carajás Copper-Gold Belt, Brazil, a member of the Cu-Au-(W-Bi-Sn) group of deposits, contains about 50 Mt of 1.22% Cu, 0.75 g/t Au, 2.4 g/t Ag, 1,200 g/t W, 70 g/t Sn, 175 g/t Mo and 75 g/t Bi. It is hosted by sandstones and siltstones of the Águas Claras Formation (minimum age of 2,681±5 Ma) in the roof zone of a complex, highly altered granite intrusion. The mineralisation is disseminated in a greisenized zone, resulting from alteration of probable monzogranites and syenogranites. The ore-bearing greisen contains abundant xenomorphic quartz in association with Fe-chlorite and muscovite. The gangue assemblage also includes fluorite, tourmaline, and minor amounts of monazite, xenotime, chlorapatite, thorite, zircon, calcite, siderite and bastnäesite. Copper mineralisation is dominated by chalcopyrite associated with pyrite, arsenopyrite, pyrrhotite and molybdenite. Gold particles, in equilibrium with native bismuth, are common as inclusions in chalcopyrite. The greisen contains sub-economic concentrations of tungsten and niobium that are related to the presence of ferberite, qitianlingite and Nb-rutile. SHRIMP II zircon dating of the host granites gives ²⁰⁷Pb/²⁰⁶Pb ages of 1,878±8 and 1,880±9 Ma for two phases, and a combined age of 1,879±6 Ma. SHRIMP II dating of monazite and xenotime grains in late- to post-mineralisation veins gives a combined ²⁰⁷Pb/²⁰⁶Pb age of 1,872±7 Ma, indistinguishable from the ages of the granites. This provides a genetic connection between the Breves deposit and the ca. 1.88 Ga A-type granite magmatism that typifies the Carajás Belt as part of a much larger, intracratonic magmatic province that extends over much of the Amazonian Craton. The recognition of this association has exploration implications, not only for the geophysical signature of the granite roof zones, but also for likely geochemical dispersion around the deposits of this type.Editorial handling: G. Beaudoin     

Downward longwave radiation estimates for clear and all-sky conditions in the Sertãozinho region of São Paulo, Brazil

The accurate estimate of the surface longwave fluxes contribution is important for the calculation of the surface radiation budget, which in turn controls all the components of the surface energy budget, such as evaporation and the sensible heat fluxes. This study evaluates the performance of the various downward longwave radiation parameterizations for clear and all-sky days applied to the Sertãozinho region in São Paulo, Brazil. Equations have been adjusted to the observations of longwave radiation. The adjusted equations were evaluated for every hour throughout the day and the results showed good fits for most of the day, except near dawn and sunset, followed by nighttime. The seasonal variation was studied by comparing the dry period against the rainy period in the dataset. The least square linear regressions resulted in coefficients equal to the coefficients found for the complete period, both in the dry period and in the rainy period. It is expected that the best fit equation to the observed data for this site be used to produce estimates in other regions of the State of São Paulo, where such information is not available.     

Model prediction capacity of ephemeral gully evolution in conservation tillage systems

Ephemeral gully (EG) erosion has an important impact on agricultural soil losses and increases field surface hydrology connectivity and transport of pollutants to nearby water bodies. Watershed models including an EG component are scarce and not yet properly evaluated. The objective of this study is to evaluate the capacity of one such tool, AnnAGNPS, to simulate the evolution of two EG formed in a conservation tillage system. The dataset for model testing included runoff measurements and EG morphological characteristics during 3 years. Model evaluation focused on EG evolution of volume, width, and length model outputs, and included calibration and testing phases and a global sensitivity analysis (GSA). While the model did not fully reproduce width and length, the model efficiency to simulate EG volume was satisfactory for both calibration and testing phases, supporting the watershed management objectives of the model. GSA revealed that the most sensitive factors were EG depth, critical shear stress, headcut detachment exponent coefficient b, and headcut detachment leading coefficient a. For EG outputs the model was additive, showing low sensitivity to interactions between the inputs. Prediction of EG spatial evolution on conservation tillage systems requires improved development of gully erosion components, since many of the processes were developed originally for traditional tillage practices or larger channel systems. Our results identify the need for future research when EG form within conservation tillage systems, in particular to study gully headcut, soil erodibility, and width functions specific to these practices.     

Camacho inlet southern Brazil - Instability causes and user conflicts

Inlet stabilization is a common practice in Brazil, as it is worldwide. In this paper we present results of the analysis of the stabilization practices of the Camacho Inlet, located in Santa Catarina State, southern Brazil. This inlet is maintained intermittently, in accordance with a regime designed to benefit both local fishermen and rice farmers. Fishermen require this inlet to be open as a navigation channel during the fishing season; rice farmers needs it closed during the irrigation period to allow the pumping of fresh water from the Congonhas River which drains into the Camacho’s backbarrier lagoon. An additional complication arises from the tendency of this inlet to close naturally due to infilling by dune migration. Aerial images spanning a 65 year time period (1938-2003) were analyzed, demonstrating the variability in the inlet’s width between 0 (closed) and 360 m. The analysis of inlet stability and user needs indicate that an appropriate solution is the implementation of an annual inlet dredging program in the austral autumn. This would allow for the inlet to remain open from May to September and then close naturally for the rest of the year, providing for a backbarrier fresh water reservoir during the irrigation period.     

Stratigraphic evolution of the nearshore to fluvial plain of the Upper Cuyo Group,Neuquén,Argentina

The upper portion of the Cuyo Group in the Zapala region, south‐eastern Neuquén Basin (Western Argentina), encompasses marine and transitional deposits (Lajas Formation) overlain by alluvial rocks (Challacó Formation). The Challacó Formation is covered by the Mendoza Group above a second‐order sequence boundary. The present study presents the stratigraphic framework and palaeophysiographic evolution of this Bajocian to Eo‐Calovian interval. The studied succession comprises the following genetic facies associations: (i) offshore and lower shoreface–offshore transition; (ii) lower shoreface; (iii) upper shoreface; iv) intertidal–subtidal; (v) supratidal–intertidal; (vi) braided fluvial to delta plain; (vii) meandering river; and (viii) braided river. The stratigraphic framework embraces four third‐order depositional sequences (C1 to C4) whose boundaries are characterized by the abrupt superposition of proximal over distal facies associations. Sequences C1 to C3 comprise mostly littoral deposits and display well‐defined, small‐scale transgressive–regressive cycles associated with fourth‐order depositional sequences. Such high‐frequency cycles are usually bounded by ravinement surfaces associated with transgressive lags. At last, the depositional sequence C4 delineates an important tectonic reorganization probably associated with an uplift of the Huincul Ridge. This is suggested by an inversion of the transport trend, north‐westward during the deposition of C1 to C3 depositional sequences (Lajas Formation) to a south‐west trend during the deposition of the braided fluvial strata related to the C4 depositional sequence (Challacó Formation).     

Metals in eggs and hatchlings of Dermochelys coriacea (testudines) in Espírito Santo,Brazil and their relation to hatching and emergence success

Certain concentration of metal may influence survival in embryonic stages, reducing the birthrate and hatching emergence. This study aimed to evaluate concentration of metal in eggs and hatchlings of Dermochelys coriacea and correlate metal concentrations in eggs with hatching and emergence success. The samples were collected at Biological Reserve Station, ES, Brazil. At the nests' opening, unhatched eggs and stillborn hatchlings were collected to survey the successful hatching and emergence of D. coriacea. The eggs shell, egg content, and dead hatchlings metal concentrations were compared to hatching and emergence success. A positive correlation was found between the concentration of copper (Cu) in the hatchlings and the success of the emergence (r² = .28, p < .05), and a moderate positive correlation between the concentrations of iron (Fe) and barium (Ba; r² = .44, p < .05) and success hatching. The concentrations of metals in eggs and hatchlings of D. coriacea in the Espírito Santo are below the levels that could be considered harmful to the species. In summary, there is a positive correlation between metals levels and hatching and emergence success.     

Performance of CMORPH,TMPA, and PERSIANN rainfall datasets over plain,mountainous, and glacial regions of Pakistan

The present study aims at the assessment of six satellite rainfall estimates (SREs) in Pakistan. For each assessed products, both real-time (RT) and post adjusted (Adj) versions are considered to highlight their potential benefits in the rainfall estimation at annual, monthly, and daily temporal scales. Three geomorphological climatic zones, i.e., plain, mountainous, and glacial are taken under considerations for the determination of relative potentials of these SREs over Pakistan at global and regional scales. All SREs, in general, have well captured the annual north-south rainfall decreasing patterns and rainfall amounts over the typical arid regions of the country. Regarding the zonal approach, the performance of all SREs has remained good over mountainous region comparative to arid regions. This poor performance in accurate rainfall estimation of all the six SREs over arid regions has made their use questionable in these regions. Over glacier region, all SREs have highly overestimated the rainfall. One possible cause of this overestimation may be due to the low surface temperature and radiation absorption over snow and ice cover, resulting in their misidentification with rainy clouds as daily false alarm ratio has increased from mountainous to glacial regions. Among RT products, CMORPH-RT is the most biased product. The Bias was almost removed on CMORPH-Adj thanks to the gauge adjustment. On a general way, all Adj versions outperformed their respective RT versions at all considered temporal scales and have confirmed the positive effects of gauge adjustment. CMORPH-Adj and TMPA-Adj have shown the best agreement with in situ data in terms of Bias, RMSE, and CC over the entire study area.     

Early contamination of European flounder (Platichthys flesus) by PCDD/Fs and dioxin-like PCBs in European waters

Contamination levels and profiles of 7 polychlorinated-p-dioxins, 10 polychlorinated furans (PCDD/Fs) and 12 dioxin-like polychlorinated biphenyls (dl-PCBs) were investigated in juvenile European flounder (Platichthys flesus) captured in different nursery areas in the northeastern Atlantic coast across its geographical distribution range. The toxic equivalent concentrations (WHO-TEQ_fish) were also determined in order to evaluate which P. flesus population was more exposed to dioxin-like toxicity. Juveniles caught in the Sørfjord (Norway) showed the lowest WHO-TEQ_fish concentration (0.052 pg WHO-TEQ_fish g⁻¹ wet weight) whereas the highest value was observed in fish from the Wadden Sea (The Netherlands; 0.291 pg WHO-TEQ_fish g⁻¹ ww), mainly due to the greater contribution of 2,3,7,8-tetrachlorodibenzo-p-dioxin, the most toxic congener. Nonetheless, when comparing the results with existent tissue residue-based toxicity benchmarks, no adverse effects resulting from PCDD/Fs and dl-PCBs are expected to occur in flounder from the studied systems.     

Platiniferous gold–tourmaline aggregates in the gold–palladium belt of Minas Gerais,Brazil: implications for regional boron metasomatism

Mineralogy and Petrology - The platiniferous gold–palladium belt of Minas Gerais, Brazil, forms an approximately 240-km-long, roughly north–south-trending domain that includes numerous...     

Talc mineralisation associated with soft hematite ore, Gongo Soco deposit, Minas Gerais, Brazil: petrography, mineral chemistry and boron-isotope composition of tourmaline

Talc mineralisation occurs as hematite–talc schist between soft hematite ore and dolomitic itabirite at Gongo Soco, Quadrilátero Ferrífero of Minas Gerais, Brazil. The hematite–talc schist and soft hematite have a prominent tectonic foliation of tabular hematite. Tabular hematite without preferential orientation is superimposed on the tectonic foliation. The talcose schist is enriched in F and has a constant Fe/S ratio. Electron-microprobe analyses indicate trace amounts of S in different generations of hematite. The whole-rock Fe/S ratio possibly represents sulfate S from hematite-hosted fluid inclusions. Fluid inclusions in foliation-overprinting hematite and chlorite geothermometry from talcose rocks suggest, respectively, temperatures from <200°C to ~300°C. Tourmaline, a rarely observed mineral in the hematite–talc schist, belongs to the alkali group and falls in the dravite compositional field. Boron-isotope determinations of tourmaline crystals, using secondary ion mass spectrometry, vary from −20‰ to −12‰ δ¹¹B. This compositional isotopic range and the tourmaline chemical composition suggest a meta-evaporitic origin. A non-marine evaporitic setting is the most likely source of acidic, highly oxidising fluids, which resulted in the abundant F-bearing talc and the presence of otherwise immobile Ti in hematite. Oxidising brines were channelled along shear zones and converted dolomitic itabirite into the Gongo Soco soft hematite and the talc mineralisation. The latter is envisaged as the hydrothermal wall-rock alteration of dolomitic itabirite, which gave rise to the soft hematite ore.