Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

Benthic Carbon Mineralization and Nutrient Turnover in a Scottish Sea Loch: An Integrative In Situ Study

Based on in situ microprofiles, chamber incubations and eddy covariance measurements, we investigated the benthic carbon mineralization and nutrient regeneration in a ~65-m-deep sedimentation basin of Loch Etive, UK. The sediment hosted a considerable amount of infauna that was dominated by the brittle star A. filiformis. The numerous burrows were intensively irrigated enhancing the benthic in situ O₂ uptake by ~50 %, and inducing highly variable redox conditions and O₂ distribution in the surface sediment as also documented by complementary laboratory-based planar optode measurements. The average benthic O₂ exchange as derived by chamber incubations and the eddy covariance approach were similar (14.9 ± 2.5 and 13.1 ± 9.0 mmol m^?2 day^?1) providing confidence in the two measuring approaches. Moreover, the non-invasive eddy approach revealed a flow-dependent benthic O₂ flux that was partly ascribed to enhanced ventilation of infauna burrows during periods of elevated flow rates. The ratio in exchange rates of ΣCO₂ and O₂ was close to unity, confirming that the O₂ uptake was a good proxy for the benthic carbon mineralization in this setting. The infauna activity resulted in highly dynamic redox conditions that presumably facilitated an efficient degradation of both terrestrial and marine-derived organic material. The complex O₂ dynamics of the burrow environment also concurrently stimulated nitrification and coupled denitrification rates making the sediment an efficient sink for bioavailable nitrogen. Furthermore, bioturbation mediated a high efflux of dissolved phosphorus and silicate. The study documents a high spatial and temporal variation in benthic solute exchange with important implications for benthic turnover of organic carbon and nutrients. However, more long-term in situ investigations with like approaches are required to fully understand how environmental events and spatio-temporal variations interrelate to the overall biogeochemical functioning of coastal sediments.     

Scour below pipelines and around vertical piles due to second-order random waves plus a current

This paper provides a method by which the scour depth below pipelines and around single vertical piles for combined random waves plus current including effects of second-order wave asymmetry can be derived. Here the empirical formulas proposed by Sumer and Fredsøe [1996. Scour below pipelines in combined waves and current. In: Proceedings of the 15th OMAE Conference, Florence, Italy. Vol. 5, ASME, New York, pp. 595–602] for pipelines, and by Sumer and Fredsøe [2002. The mechanics of scour in the marine environment. World Scientific, Singapore] for vertical piles are used together with Stokes second-order wave theory by assuming the basic harmonic wave motion to be a stationary Gaussian narrow-band random process. Comparisons are made with the Sumer and Fredsøe [1996. Scour below pipelines in combined waves and current. In: Proceedings of the 15th OMAE Conference, Florence, Italy. Vol. 5, ASME, New York, pp. 595–602; 2001. Scour around pile in combined waves and current. Journal of Hydraulic Engineering, 127(5), 403–411] data for linear random waves plus current. An example of calculation is also presented.     

Honey, I cooled the cods: Modelling the effect of temperature on the structure of Boreal/Arctic fish ecosystems

Historically colder regions of the North Atlantic had fisheries dominated by only a few fish species; principally cod and capelin. Possible population dynamic mechanisms that lead to such dominance are investigated by considering how a charmingly simple published multispecies model of the North Sea would react if the system operated at a lower temperature. The existing model equations were modified to describe temperature effects on growth, fecundity and recruitment and the model was rerun based on typical temperatures for the North Sea and a colder system. The results suggest that total fish biomass in the colder system increases but the community is more vulnerable to a given rate of fishing mortality. In the colder system, within species density dependence is reduced but relative predation rates are higher. Consequently, intermediate-sized species are vulnerable to relatively high levels of predation throughout their life history and tend to be excluded, leading to a system dominated by small and large species. The model helps to explain how temperature may govern coexistence and competitive exclusion in fish communities and accounts for the observed dominance of small and large species in Boreal/Arctic ecosystems.     

False drainage anomalies (?) in a granite area, Kvalöya in Troms, Norway — a case study

An anomalous area (100 km²) revealed by a previous regional overbank sediment sampling survey by the Geological Survey of Norway was followed-up for Ti, Nb, Y, Zr, La and Ce by drainage and lithogeochemical sampling and analyses. The drainage samples were anomalous in the same elements as in the overbank samples and contained similar concentrations. The lithogeochemical results did not indicate mineralization and showed only a small enhancement of Ti, Zr, La and Ce in mylonitic rocks.Mineralogical studies of the drainage samples revealed, apart from proportions of quartz and feldspars, that stream sediments and heavy mineral concentrates are similar in mineralogy, with epidote predomination and several vol% of fine-grained titanite and zircon. Drainage samples contained amounts of Nb, Y, and Zr up to ten times larger than average contents of rock samples. Enhanced light REE (La and Ce) and Nb reflect host minerals, titanite, and enhanced Y possibly zircon and/or allanite.Anomalies in both media do not relate to mineralization. The overbank samples and the drainage samples provide comparable geochemical data.     

Proterozoic fluvial styles: response to changes in accommodation space (Rivieradal sandstones, eastern North Greenland)

Fluvial styles recorded by the uppermost part of the Neoproterozoic ‘Rivieradal sandstones' succession of eastern North Greenland reflect variations in rate of generated accommodation space and possibly climatic changes. Three facies associations, arranged in two genetic sequences, are recognised within the succession. The lower sequence initially records little available accommodation space. A high degree of reworking results in sheet-like, high-energy, bed-load-dominated, braided river deposits lacking recurrent facies patterns. As accommodation space increases upwards through the sequence, reduction in reworking is recorded by the development of fining- and thickening-upward muddy fluvial cycles. Evidence of desiccation or prolonged periods of drought are absent within the deposits and climate was probably relatively humid. Channel deposits in the lower sequence reflect mixed-load, braided fluvial systems with stable channel banks and floodplains, and the gradient appears to have been low to moderate. These features are generally considered favourable for the establishment of meandering river systems, but channels, nevertheless, retained an overall braided character and their deposits show no evidence of meandering. Despite indications of a climatic setting without significant periods of drought sediments indicate that large fluctuations in discharge occurred within the mixed-load streams and this is suggested to be the main cause for the absence of meandering. The swift and rather dramatic response of the fluvial systems to changes in precipitation, probably resulted from rapid runoff rates caused by the absence of vegetation. The upper sequence shows an initial return to shallow, sandy braided river deposition recording little available accommodation space. A subsequent increase in the rate of generated accommodation space is indicated by the presence of alternating sheet sandstones and sand-streaked mudstones with abundant desiccation cracks. The sheet sandstones show evidence of high-energy, unconfined ephemeral fluvial flash-flood deposition, while the mudstones are interpreted to represent muddy floodplain deposits. The change in fluvial style, combined with the widespread evidence of desiccation, suggest an evolution towards a more semi-arid climate in the upper sequence. This climatic change could account for the reduced clastic input seen in the overlying marine succession which culminated in carbonate platform deposition. The present study suggests that even under conditions considered favourable for the formation of meandering streams, these will rarely occur in Proterozoic deposits due to the lacking influence of vegetation. Although meandering deposits cannot be ruled out as having formed in pre-vegetational times, the conditions for their formation appear to have been even more restricted than previously realised.     

Preservation of pre-vegetational mixed fluvio–aeolian deposits in a humid climatic setting: an example from the Middle Proterozoic Eriksfjord Formation, Southwest Greenland

Sedimentological studies of a 30 m thick coastal cliff section within the Middle Proterozoic Eriksfjord Formation in western South Greenland reveals three distinct types of fluvial sand sheet deposits that reflect perennial streams (Type I), semi-perennial streams (Type II), and ephemeral flash floods (Type III). Perennial river sand sheets are characterised by co-sets of medium-scale trough cross-beds, interbedded with isolated medium- and large-scale, high-angle, tabular cross-beds. Indications of desiccation or subaerial exposure are absent. Semi-perennial fluvial sand sheets consist predominantly of low-angle cross-beds, interbedded with isolated sets of high-angle tabular cross-beds with common reactivation surfaces. Horizontal lamination and climbing ripple lamination form subordinate structures. Associated with the sand sheets are adhesion structures and 0.05–0.4 m thick sets of wind ripple-lamination indicating periods of subaerial exposure and aeolian reworking. High-energy ephemeral flash flood sand sheets consist almost exclusively of planar-parallel lamination and climbing ripple lamination with some isolated sets of low-angle cross-bedding. Scouring and internal truncation surfaces are common. The three types of sand sheets are considered to reflect deposition under changing climatic conditions, varying from humid to arid or semi-arid. Aeolian deposits are preserved within the sand sheets showing characteristics of dominantly perennial flow punctuated by shorter periods of desiccation (Type II), while sand sheets showing features typical of arid and or semi-arid flow conditions (Type III) contain no preserved aeolian deposits. This selective preservation is interpreted to be a result of the combined effect of groundwater table level and fluvial style which in turn are inferred to have been controlled by the climatic regime. The deposits show that during pre-vegetational times the preservation of aeolian deposits, under certain conditions, may be more optimal in fluvial systems formed in a humid climate than in fluvial systems formed under semi-arid or arid circumstances. The occurrence of aeolian deposits within a Precambrian succession of fluvial deposits therefore, need not be an indication of the most arid environmental conditions.