Preservation of pre-vegetational mixed fluvio–aeolian deposits in a humid climatic setting: an example from the Middle Proterozoic Eriksfjord Formation, Southwest Greenland

Sedimentological studies of a 30 m thick coastal cliff section within the Middle Proterozoic Eriksfjord Formation in western South Greenland reveals three distinct types of fluvial sand sheet deposits that reflect perennial streams (Type I), semi-perennial streams (Type II), and ephemeral flash floods (Type III). Perennial river sand sheets are characterised by co-sets of medium-scale trough cross-beds, interbedded with isolated medium- and large-scale, high-angle, tabular cross-beds. Indications of desiccation or subaerial exposure are absent. Semi-perennial fluvial sand sheets consist predominantly of low-angle cross-beds, interbedded with isolated sets of high-angle tabular cross-beds with common reactivation surfaces. Horizontal lamination and climbing ripple lamination form subordinate structures. Associated with the sand sheets are adhesion structures and 0.05–0.4 m thick sets of wind ripple-lamination indicating periods of subaerial exposure and aeolian reworking. High-energy ephemeral flash flood sand sheets consist almost exclusively of planar-parallel lamination and climbing ripple lamination with some isolated sets of low-angle cross-bedding. Scouring and internal truncation surfaces are common. The three types of sand sheets are considered to reflect deposition under changing climatic conditions, varying from humid to arid or semi-arid. Aeolian deposits are preserved within the sand sheets showing characteristics of dominantly perennial flow punctuated by shorter periods of desiccation (Type II), while sand sheets showing features typical of arid and or semi-arid flow conditions (Type III) contain no preserved aeolian deposits. This selective preservation is interpreted to be a result of the combined effect of groundwater table level and fluvial style which in turn are inferred to have been controlled by the climatic regime. The deposits show that during pre-vegetational times the preservation of aeolian deposits, under certain conditions, may be more optimal in fluvial systems formed in a humid climate than in fluvial systems formed under semi-arid or arid circumstances. The occurrence of aeolian deposits within a Precambrian succession of fluvial deposits therefore, need not be an indication of the most arid environmental conditions.     

Viscous overstability and eccentricity evolution in three-dimensional gaseous discs

We investigate the growth or decay rate of the fundamental mode of even symmetry in a viscous accretion disc. This mode occurs in eccentric discs and is known to be potentially overstable. We determine the vertical structure of the disc and its modes, treating radiative energy transport in the diffusion approximation. In the limit of very long radial wavelength, an analytical criterion for viscous overstability is obtained, which involves the effective shear and bulk viscosity, the adiabatic exponent, and the opacity law of the disc. This differs from the prediction of a two-dimensional model. On shorter wavelengths (a few times the disc thickness), the criterion for overstability is more difficult to satisfy because of the different vertical structure of the mode. In a low-viscosity disc a third regime of intermediate wavelengths appears, in which the overstability is suppressed as the horizontal velocity perturbations develop significant vertical shear. We suggest that this effect determines the damping rate of eccentricity in protoplanetary discs, for which the long-wavelength analysis is inapplicable and overstability is unlikely to occur on any scale. In thinner accretion discs and in decretion discs around Be stars overstability may occur only on the longest wavelengths, leading to the preferential excitation of global eccentric modes.     

Forward induced seismic hazard assessment: application to a synthetic seismicity catalogue from hydraulic stimulation modelling

The M _w 3.2-induced seismic event in 2006 due to fluid injection at the Basel geothermal site in Switzerland was the starting point for an ongoing discussion in Europe on the potential risk of hydraulic stimulation in general. In particular, further development of mitigation strategies of induced seismic events of economic concern became a hot topic in geosciences and geoengineering. Here, we present a workflow to assess the hazard of induced seismicity in terms of occurrence rate of induced seismic events. The workflow is called Forward Induced Seismic Hazard Assessment (FISHA) as it combines the results of forward hydromechanical-numerical models with methods of time-dependent probabilistic seismic hazard assessment. To exemplify FISHA, we use simulations of four different fluid injection types with various injection parameters, i.e. injection rate, duration and style of injection. The hydromechanical-numerical model applied in this study represents a geothermal reservoir with preexisting fractures where a routine of viscous fluid flow in porous media is implemented from which flow and pressure driven failures of rock matrix and preexisting fractures are simulated, and corresponding seismic moment magnitudes are computed. The resulting synthetic catalogues of induced seismicity, including event location, occurrence time and magnitude, are used to calibrate the magnitude completeness M _c and the parameters a and b of the frequency-magnitude relation. These are used to estimate the time-dependent occurrence rate of induced seismic events for each fluid injection scenario. In contrast to other mitigation strategies that rely on real-time data or already obtained catalogues, we can perform various synthetic experiments with the same initial conditions. Thus, the advantage of FISHA is that it can quantify hazard from numerical experiments and recommend a priori a stimulation type that lowers the occurrence rate of induced seismic events. The FISHA workflow is rather general and not limited to the hydromechanical-numerical model used in this study and can therefore be applied to other fluid injection models.     

The photoelectron spectra of some Tl-Sb sulphosalts

The results of X-ray induced photoelectron spectroscopy (XPS) experiments on several phases of the ternary system Tl-Sb-S are reported. The binding energies of the inner S, Sb and Tl electrons increase with increasing quantities of Sb and decreasing amounts of Tl in these compounds. This is explained by the influences of the proportions of the bonded metals on the effective electron affinity of S. The higher proportions of the more electronegative element bonded to S cause the increase of its effective electron affinity. The results for Tl₂S (carlinite), Tl₃SbS₃, TlSbS₂ (weissbergite), TlAsS₂ (lorandite) and Sb₂S₃ (antimonite) can be interpreted in this way. The results for Tl₄S₃ suggest a predominantly covalent character of bonding for both Tl(III) and Tl(I), which are present in this sulfide. From comparison with Tl₃SbS₄ it could be supposed that Tl(III)-S bond has a more covalent character than Sb(V)-S bond. The results for Tl₃SbS₄ are in agreement with crystal structure data and the results of Moessbauer spectroscopy. For AsS (realgar) the binding energies of the inner electrons of As and S significantly increase, showing that the electrons in molecular orbitals are less strongly bonded to individual atoms, as compared to pure elements. The results for the amorphous TlSb₅S₈ (corresponding in composition to parapierrotite) suggest that in amorphous compound the Tl-S bonding is stronger and the coordination of Tl more regular than in a crystalline one.     

Gas hydrate disturbance fabrics of southern Hydrate Ridge sediments (ODP Leg 204): Relationship with texture and physical properties

Soupy and mousse-like fabrics are disturbance sedimentary features that result from the dissociation of gas hydrate, a process that releases water. During the core retrieval process, soupy and mousse-like fabrics are produced in the gas hydrate-bearing sediments due to changes in pressure and temperature conditions. Therefore, the identification of soupy and mousse-like fabrics can be used as a proxy for the presence of gas hydrate in addition to other evidence, such as pore water freshening or anomalously cool temperature. We present here grain-size results, mineralogical composition and magnetic susceptibility data of soupy and mousse-like samples from the southern Hydrate Ridge (Cascadia accretionary complex) acquired during Leg 204 of the Ocean Drilling Program. In order to study the relationship between sedimentary texture and the presence of gas hydrates, we have compared these results with the main textural and compositional data available from the same area. Most of the disturbed analyzed samples from the summit and the western flank of southern Hydrate Ridge show a mean grain size coarser than the average mean grain size of the hemipelagic samples from the same area. The depositional features of the sediments are not recognised due to disturbance. However, their granulometric statistical parameters and distribution curves, and magnetic susceptibility logs indicate that they correspond to a turbidite facies. These results suggest that gas hydrates in the southern Hydrate Ridge could form preferentially in coarser grain-size layers that could act as conduits feeding gas from below the BSR. Two samples from the uppermost metres near the seafloor at the summit of the southern Hydrate Ridge show a finer mean grain-size value than the average of hemipelagic samples. They were located where the highest amount of gas hydrates was detected, suggesting that in this area the availability of methane gas was high enough to generate gas hydrates, even within low-permeability layers. The mineralogical composition of the soupy and mousse-like sediments does not show any specific characteristic with respect to the other samples from the southern Hydrate Ridge.     

Honey, I cooled the cods: Modelling the effect of temperature on the structure of Boreal/Arctic fish ecosystems

Historically colder regions of the North Atlantic had fisheries dominated by only a few fish species; principally cod and capelin. Possible population dynamic mechanisms that lead to such dominance are investigated by considering how a charmingly simple published multispecies model of the North Sea would react if the system operated at a lower temperature. The existing model equations were modified to describe temperature effects on growth, fecundity and recruitment and the model was rerun based on typical temperatures for the North Sea and a colder system. The results suggest that total fish biomass in the colder system increases but the community is more vulnerable to a given rate of fishing mortality. In the colder system, within species density dependence is reduced but relative predation rates are higher. Consequently, intermediate-sized species are vulnerable to relatively high levels of predation throughout their life history and tend to be excluded, leading to a system dominated by small and large species. The model helps to explain how temperature may govern coexistence and competitive exclusion in fish communities and accounts for the observed dominance of small and large species in Boreal/Arctic ecosystems.     

Scour below pipelines and around vertical piles due to second-order random waves plus a current

This paper provides a method by which the scour depth below pipelines and around single vertical piles for combined random waves plus current including effects of second-order wave asymmetry can be derived. Here the empirical formulas proposed by Sumer and Fredsøe [1996. Scour below pipelines in combined waves and current. In: Proceedings of the 15th OMAE Conference, Florence, Italy. Vol. 5, ASME, New York, pp. 595–602] for pipelines, and by Sumer and Fredsøe [2002. The mechanics of scour in the marine environment. World Scientific, Singapore] for vertical piles are used together with Stokes second-order wave theory by assuming the basic harmonic wave motion to be a stationary Gaussian narrow-band random process. Comparisons are made with the Sumer and Fredsøe [1996. Scour below pipelines in combined waves and current. In: Proceedings of the 15th OMAE Conference, Florence, Italy. Vol. 5, ASME, New York, pp. 595–602; 2001. Scour around pile in combined waves and current. Journal of Hydraulic Engineering, 127(5), 403–411] data for linear random waves plus current. An example of calculation is also presented.     

Oxygen and organic carbon fluxes in sediments of the Bay of Biscay

The relationship between particulate organic carbon (POC) concentrations measured in modern sediment and fluxes of exported POC to the sediment surface needs to be understood in order to use POC content as a proxy of paleo-environmental conditions. The objective of our study was to compare POC concentrations, POC mineralization rates calculated from O₂ consumption and POC burial rates. Benthic O₂ distributions were determined in 58 fine-grained sediment cores collected at different periods at 14 stations in the southeastern part of the Bay of Biscay with depths ranging from 140 to 2800 m. Depth-dependent volume-specific oxygen consumption rates were used to assess rates of aerobic oxidation of organic matter (OM), assuming that O₂ consumption solely was related to heterotrophic activity at the sediment–water interface. Heterogeneity of benthic O₂ fluxes denoted changes in time and space of fresh organic material sedimentation. The most labile fraction of exported POC engendered a steep decrease in concentration in the upper 5 mm of vertical O₂ profiles. The rupture in the gradient of O₂ microprofile may be related to the bioturbation-induced mixing depth of fast-decaying carbon. Average diffusive O₂ fluxes showed that this fast-decaying OM flux was much higher than buried POC, although diffusive O₂ fluxes underestimated the total sediment oxygen demand, and thus the fast-decaying OM flux to the sediment surface. Sedimentary POC burial was calculated from sediment mass accumulation rate and the organic carbon content measured at the top of the sediment. The proportion of buried POC relative to total exported POC ranged at the most between 50% and 10%, depending on station location. Therefore, for a narrow geographic area like the Bay of Biscay, burial efficiency of POC was variable. A fraction of buried POC consisted of slow-decaying OM that was mineralized within the upper decimetres of sediment through oxic and anoxic processes. This fraction was deduced from the decrease with depth in POC concentration. At sites located below 500 m water depth, where the fast-decaying carbon did not reach the anoxic sediment, the slow-decaying pool may control the O₂ penetration depth. Only refractory organic material was fossilized in sedimentary records at locations where labile OM did not reach the anoxic portion of the sediment.