Organic matter in anoxic marine pore water: oxidation effects

A series of cores were obtained from the Great Bay Estuary, New Hampshire during 1980 and 1981 in order to investigate the effects on the dissolved organic matter of exposure of anoxic marine pore water to atmospheric oxygen during laboratory handling. Sediment sections from these cores were homogenized and split into two equal parts, one of which was handled in a glove bag under a nitrogen atmosphere, and the other exposed to atmospheric oxygen during laboratory processing. Analysis of the pore water for dissolved organic carbon (DOC) indicated two effects: (1) in the top 15 cm, DOC was lost from the pore water of the oxidized subsections, probably as a consequence of co-precipitation with iron (III) oxi-hydroxides, whereas (2) deeper in the cores, the pore water from the oxidized subsections showed a net increase in DOC, possibly due to oxidation of sedimentary organic matter. In addition, structural changes in the dissolved organic matter in anoxic pore water following oxidation was indicated by high pressure liquid chromatography and ultrafiltration analysis.     

THE DEGRADABILITY OF PARTICULATE ORGANIC MATTER IN THE GIRONDE ESTUARY, FRANCE

The degradability of particulate organic matter(POM)in the Gironde Estuary(France)was measuredusing the incubation technique.The influence of sample treatment and incubation conditions on the re-sults was evaluated.A mathematical model was successfully used to describe the various degradationcurves.Results showed that the upstream POM had very high degradability;the central estuaryPOM had low degradability;and that the mouth POM degradability was between that of central POM(low degradability)and marine POM(high degradability).     

African Easterly Waves and convective activity in wet and dry sequences of the West African Monsoon

Janicot and Sultan (Geophys Res Lett 28(3):523–526, 2001) and Sultan et al. (J Clim 16(21):3389–3406, 2003) showed evidence of an intraseasonal signal of Sahelian rainfall corresponding to wet and dry sequences of the West African Monsoon. Using NCEP/NCAR reanalysis, NOAA outgoing longwave radiation (OLR) and observed daily rainfall over West Africa from 1968 to 1990, this paper investigates the variability of 3 to 5-day African Easterly Waves (AEWs), convection and their relationship with rainfall in these wet and dry sequences. The mean daily value rainfall during wet sequences is twice the mean value during dry sequences but the number of dry or wet sequences per year is not correlated with the annual rainfall. Wet sequences account for 39% of the annual accumulated rainfall while dry sequences account for 22%. The number of 3 to 5-day AEWs increases during wet years in wet sequences and the activity tends to be larger during wet years in both wet and dry sequences. These AEWs explain 40% of the accumulated rainfall during wet sequences whereas they contribute to 26% of the accumulated rainfall observed during dry sequences. Generally, they contribute to the increase of rainfall during these sequences. Mean convection is stronger and there are twice as many low OLR days (<225W/m²) during wet than dry sequences. The mean rainfall for days with high convective activity (convective days) is also twice as great during wet sequences. Rainfall that occurs during days without low OLR (weak convection with warm cloud tops or isolated deep convection) contributes to 69% of the total rainfall during dry sequences and 45% during wet sequences. A composite study was performed from day D ₀−10 to day D ₀+10 in each sequence. Wet (dry) sequences of the African monsoon start with a decrease (slight increase) of the negative meridional Ertel Potential Vorticity (PV) gradient at 700 hPa, associated with an increase (decrease) of the spectral density of AEWs. During the wet sequence, the African Easterly Jet (AEJ), detected by 700 hPa zonal wind, decreases and moves northward, whereas the Tropical Easterly Jet (TEJ), detected at 200 hPa, increases and shifts southward. Convective activity increases from D ₀−6 to D ₀−3 and remains high for 4 days in wet sequences. The daily rainfall increases (decreases) between D ₀−6 and D ₀ and returns to the mean value at D ₀+4 for wet (dry) sequences.     

The location of infinite electrodes in pole–pole electrical surveys: consequences for 2D imaging

In 2D-multielectrode electrical surveys using the pole–pole array, the distance to ‘infinite electrodes' is actually finite. As a matter of fact, the available cable length generally imposes a poor approximation of theoretical location of these electrodes at infinity. This study shows that in most of the cases, the resulting apparent resistivity pseudosection is strongly distorted. Numerical simulation validated by field test also shows that a particular finite array provides results that are as close as possible to the ones of the ideal pole–pole array. This is achieved when two conditions that are weaker than an infinite location are fulfilled: (i) the ‘infinite electrodes' are placed symmetrically on both sides of the in-line electrodes with a spread angle of 30° and (ii) the length of ‘infinite lines' is at least 20 times the greatest distance between in-line electrodes. The electrical 2D image obtained with this enhanced array is the least distorted one with respect to the pole–pole image. The apparent resistivities are generally underestimated, but this deviation is almost homogeneous. Though the shift cannot be determined a priori, the interpretation of such an image with direct or inverse software designed for pole–pole data provides an accurate interpretation of the ground geometry.     

Organic matter dynamics and budgets in the turbidity maximum zone of the Seine Estuary (France)

Organic matter was studied in the turbidity maximum zone (TMZ) of the Seine Estuary during 8 tidal cycles from April to October in 2001, 2002 and 2003, covering a salinity range from 0 to 27. The hydrological conditions were quite varied (extremely wet in 2001, unusually dry in 2003). A particularly striking feature is the high organic matter content in the suspended solids (SS) of the Seine estuary (4–5%).     

Variations of the suspended matter and the particulate organic carbon in the entry of the Gironde Estuary,France

The effects of using different types of glass fiber filters (GF/F, GF/C) and of sample treatments were evaluated. Studies on the variation of suspended matter (SM) and particulate organic carbon (POC) showed that: 1) the transversal and day to night variations are important and must be taken into account in order to get a correct river flux; 2) no regular seasonal variations of SM and POC were observed, as they are controlled essentially by the climatological, hydrologic, physiochemical, biological, and geological conditions of the drainage area. Contribution No 2246 from the Institute of Oceanology, Chinese Academy of Sciences.     

Emissions of Polycyclic aromatic hydrocarbons by savanna fires

Although Polycyclic aromatic hydrocarbons (PAH) are known as anthropogenic compounds arising from the combustion or the pyrolysis of fossil fuels, they may be also emitted by the combustion of vegetation. A field study was carried out in January 1991 at Lamto (Ivory Coast) as part of the FOS DECAFE experiment (Fire Of Savanna). Some ground samplings were devoted to the qualitative and quantitative characterization of atmospheric emissions by savanna fires during prescribed burns and under background conditions. Specific collections for gaseous and particulate PAHs have shown that the African practice of burning the savanna biomass during the winter months is an important source of PAHs. These compounds are emitted mainly in gaseous form but a significant fraction, essentially heavy PAHs, is associated with fine carbonaceous particles and can therefore represent a hazard for human health, since some of these compounds are mutagenic and carcinogenic. Twelve compounds were identified during the fire episodes and in the atmospheric background. The total concentration in the fires is of the order of 10 ng m^–3 for the gas phase and from 0.1 to 1 ng m^–3 in the aerosols. In the atmospheric background the mean concentrations are regular, 0.15 ng m^–3 and 2 pg m^–3, respectively. These concentrations are comparable with what is observed in European rural zones. The particulate emissions of PAHs by the savanna fires are distinguished by the abundance of some compounds which can be considered as tracers, although they are also slightly emitted by fossil fuel sources. These compounds are essentially pyrene, chrysene and coronene. In the gas phase, although no individual PAH may be considered as specific of the biomass combustion emissions, the relative abundances of the main PAHs are characteristic of the biomass burning. The concentrations of pyrene and fluorene are always predominant; these compounds could be considered as characteristic emission products of smoldering and flaming episodes, respectively. In the background the PAH composition shows that in a tropical region the air consists of a mixture coming from the various sources, but the biomass combustion is by far the most important source.The fluxes of total PAH emitted by savanna biomass burning in Africa were estimated to be of the order of 17 and 600 ton yr^–1, respectively, for the particulate PAHs and the gaseous PAHs, respectively.