Marble-hosted ruby deposits from Central and Southeast Asia: Towards a new genetic model

Marble-hosted ruby deposits represent the most important source of colored gemstones from Central and South East Asia. These deposits are located in the Himalayan mountain belt which developed during Tertiary collision of the Indian plate northward into the Eurasian plate. They are spatially related to granitoid intrusions and are contained in platform carbonates series that underwent high-grade metamorphism. All occurrences are located close to major tectonic features formed during Himalayan orogenesis, directly in suture zones in the Himalayas, or in shear zones that guided extrusion of the Indochina block after the collision in South East Asia. Ar–Ar dating of micas syngenetic with ruby and U–Pb dating of zircon included in ruby gives evidence that these deposits formed during Himalayan orogenesis, and the ages document the extensional tectonics that were active, from Afghanistan to Vietnam, between the Oligocene and the Pliocene.The petrography shows that ruby-bearing marbles formed in the amphibolite facies (T = 610 to 790 °C and P ~ 6 kbar). A fluid inclusion study defines the conditions of gem ruby formation during the retrograde metamorphic path (620 < T < 670 °C and 2.6 < P < 3.3 kbar) for the deposits of Jegdalek, Hunza and northern Vietnam.Whole rock analyses of non-ruby-bearing marbles indicate that they contain enough aluminum and chromiferous elements to produce all the ruby crystals that they contain. In addition, (C, O)-isotopic analyses of carbonates from the marbles lead to the conclusion that the marbles acted as a metamorphic closed fluid system that were not infiltrated by externally-derived fluids. The carbon isotopic composition of graphite in marbles reveals that it is of organic origin and that it exchanged C-isotopes with the carbonates during metamorphism. Moreover, the O-isotopic composition of ruby was buffered by metamorphic CO₂ released during devolatilisation of marble and the H-isotopic composition of mica is consistent with a metamorphic origin for water in equilibrium with the micas. The (C, O, H)-isotopic compositions of minerals associated with marble-hosted ruby are all in agreement with the hypothesis, drawn from the unusual chemistry of CO₂–H₂S–COS–S₈–AlO(OH)-bearing fluids contained in fluid inclusions, that gem ruby formed at P ~ 3 kbar and 620 < T < 670 °C, during thermal reduction of evaporite by organic matter, at high temperature-medium pressure metamorphism of platform carbonates during the Tertiary India–Asia collision. The carbonates were enriched in Al- and chromiferous-bearing detrital minerals, such as clay minerals that were deposited on the platform with the carbonates, and in organic matter. Ruby formed during the retrograde metamorphic path, mainly by destabilization of muscovite or spinel. The metamorphic fluid system was rich in CO₂ released from devolatilisation of carbonates, and in fluorine, chlorine and boron released by molten salts (NaCl, KCl, CaSO₄). Evaporites are key to explaining the formation of these deposits. Molten salts mobilized in situ Al and metal transition elements contained in marbles, leading to crystallization of ruby.     

Annual growth zones in stems of Hypericum irazuense (Guttiferae) in the Costa Rican páramos

The high peaks of the Cordillera de Talamanca in Costa Rica support shrub- and grass-dominated páramo ecosystems that experience stand-replacing wildfires. The dry season that facilitates these fires results in dormancy in plant growth and provides an opportunity to use dendrochronological analyses to determine ages of plants in burn sites to support studies of fire history and postfire vegetation recovery. This study investigates the formation of annual growth zones in stems of the common shrub Hypericum irazuense. Unlike other páramo shrubs, H. irazuense rarely resprouts following fire, instead recovering through seedling recruitment following seed dispersal from the unburned periphery. Laboratory analysis of 19 prepared cross sections from 15 stems shows that samples of H. irazuense from burned areas can provide an estimate of the minimum number of years since the previous fire, supporting earlier work based on field examination of stems. Including a time lag for seedling recruitment or resprouting refines that estimate. Counts of growth zones in most sections coincided with dates of the last known fires. The presence of annual growth zones in H. irazuense places the species within a relatively small group of woody Neotropical species for which annual rings or growth zones have been demonstrated.     

Condensation sur des particules salines au-dessous de 0°C

Résumé Nous avons étendu aux températures négatives les mesures de l'humidité relative critiqueh _c juste suffisante pour permettre la condensation de vapeur d'eau sur des noyaux géants constitués par divers sels.Pour chaque sel étudié, un point de la courbe donnanth _c en fonction de la températuret° C est facilement obtenu en recherchant pour quelle valeurt _c de la températureh _c coïncide avec l'humidité relative en équilibre avec la glace à la même températuret _c .Les valeurs obtenues pour NaCl, NH₄Cl, KCl, KNO₃ tendent à valider l'extrapolation des valeurs déjà connues pour les températures positives.

---

Summary We have enlarged to negative temperatures the measures of critical relative humidityh _c just sufficient to allow the condensation of water vapour on giant nuclei constituted by different salts.For every salt studied, a point of the curve givingh _c as a function of the temperaturet° C is easily obtained by measuring for what valuet _c of the temperature,h _c coincides with the relative humidity in equilibrium with ice at the same temperaturet _c .The values obtained for NaCl, NH₄Cl, KCl, KNO₃ tend to validate the extrapolation of the values known for positive temperatures.

     

The Ebro Deep-Sea Fan system

The Ebro Fan System consists of en echelon channel-levee complexes, 50×20 km in area and 200-m thick. A few strong reflectors in a generally transparent seismic facies identify the sand-rich channel floors and levee crests. Numerous continuous acoustic reflectors characterize overbank turbidites and hemipelagites that blanket abandoned channel-levee complexes. The interlobe areas between channel complexes fill with homogeneous mud and sand from mass flow and overbank deposition; these exhibit a transparent seismic character. The steep continental rise and sediment “drainage” of Valencia Trough at the end of the channel-levee complexes prevent the development of distributary channels and midfan lobe deposits.     

Evolution des hydrocarbures,des peuplements bacteriens et microphytiques dans les sediments des marais maritimes de l'iie grande pollues par l'amoco cadiz: 1, evolution des hydrocarbures et des bacteries

The evolution of hydrocarbons in sediments was studied from 1978 to 1980 at eight stations in the Ile Grande marshes (Brittany) polluted by the Amoco Cadiz oil spill. Generally, in 1980 (except for one heavily polluted site) the amounts of hydrocarbons were found to be far less important than in 1978 and sometimes biogenic hydrocarbons were found. In the superficial layer of the sediments biodegradation processes were generally important with the preferential degradation of n-alkanes. On the other hand, aromatic hydrocarbons seem not to have been altered after three years. Degradation of percolated hydrocarbons proceeds more slowly than in the surface layer. The number of degrading bacteria decreases when n-alkanes disappear.     

A re-evaluation of metal diapir breakup and equilibration in terrestrial magma oceans

Due to mechanisms such as impact heating, early atmospheric thermal blanketing, and radioactive heating, the presence of at least one global magma ocean stage in the early histories of terrestrial planets seems unavoidable. In such a context, a key question to constrain the early thermo–chemical evolution of the Earth is how much iron diapirs provided by differentiated impactors emulsified during their sinking towards the bottom of an early magma ocean.In the past years, several workers have focused on this question, using however various approaches and making different assumptions. While most studies favor rapid breakup and equilibration of iron bodies during their sinking through the magma ocean, recent work suggests that iron bodies of size comparable or greater than a few tens of kilometers may preserve most of their initial volume as they reach the bottom of a magma ocean, therefore leading to metal–silicate disequilibrium.To clarify the discrepancies and the differences among studies I have conducted a series of numerical simulations and theoretical calculations to derive the conditions and the timing for the breakup of metal diapirs of any size, sinking through a silicate magma ocean, with a large range of plausible viscosity values. The obtained breakup criterion is used to derive stable diapir sizes and their ability to equilibrate with the surrounding silicates. I show that for plausible magma ocean viscosities, diapirs with initial radii smaller than the thickness of a magma ocean rapidly break up into stable diapir sizes smaller than 0.2 m, at which metal–silicate equilibration is rapidly achieved.     

Assessment of water body change and sedimentation rate in Moulay Bousselham wetland,Morocco, using geospatial technologies

Coastal lagoons have significant biodiversity and ecologic and socio-economic interest. Several resident and migratory birds live in coastal lagoons as well as fish and other aquatic biota. Over the years, lagoons worldwide have been subject to considerable sediment deposition coming especially from soil erosion due of agricultural activities, and the lagoon's inflows have resulted in an accelerated sedimentation which can drastically affect the aquatic ecosystem balance. A new, fast, and cost-effective approach was developed, using water surface change as a proxy, to evaluate the sediment deposition rate. In the current research, this methodology was applied in the Moulay Bousselham Lagoon in Morocco, and a combination of Landsat 8 and Landsat 5 imagery acquired at four points in time over 30 years(1985-2015) was used. Following geometric correction and enhancement, the interpretation of the acquired images provided important insight on the current conditions of the water surface change using the Normalized Difference Water Index(NDWI). Several iterations were done to determine a suitable threshold for effective water surface detection. In order to validate the automatically extracted water surface features, many band combinations of Landsat and Sentinel 2 were used as references to run the accuracy assessment. The results show that the Moulay Bousselham Lagoon lost 17.60%(106 ha) of its water surface area, and 530,000 m^3 to 1,060,000 m^3 of its water volume during the last three decades.Converting water surface loss into sedimentation returned a rate of 0.58 cm/yr. These results have been confirmed by previous field work using sedimentological approaches. Proper management should be applied to sustain the vitality of this lagoon environment.     

Minor elements in sediments of Great Bay estuary,New Hampshire

Concentrations of copper, zinc, chromium, lead, cadmium, and phosphorus were obtained from 81 samples of unconsolidated estuarine sediment from Great Bay, New Hampshire. Dispersal of aqueous chromium from localized industrial effluent is believed responsible for an increase in sediment chromium throughout the entire estuary. High phosphorus concentrations exist in sediment near the outfalls from several waste-water treatment plants. There is no evidence for any increase of copper, zinc, lead, or cadmium in this estuary, except for localized high concentrations close to industrial outfalls. Fine-grained sediments and organic carbon correlate highly with all the elements studied, except for chromium. This suggests that conventional agents of sedimentary adsorption are not adequate to explain the incorporation of chromium into sediment under the conditions of heavy industrial discharge which exist in this estuary. Sediment phosphorus correlates highly with minor elements, suggesting that it is an adsorption agent, similar to more typical sedimentary parameters such as organic matter and clay minerals. In such a capacity phosphorus may enhance the sedimentary uptake of other aqueous species, and account for higher chromium sediment concentrations. Comparative data from other sedimentary environments emphasize the environmental significance of these elements in Great Bay.     

The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset II: Land use,hydrology and sediment production monitoring in Houay Pano,northern Lao PDR

Mountain regions of the humid tropics are characterized by steep slopes and heavy rains. These regions are thus prone to both high surface runoff and soil erosion. In Southeast Asia, uplands are also subject to rapid land-use change, predominantly as a result of increased population pressure and market forces. Since 1998, the Houay Pano site, located in northern Lao PDR (19.85°N 102.17°E) within the Mekong basin, aims at assessing the long-term impact of the conversion of traditional slash-and-burn cultivation systems to commercial perennial monocultures such as teak tree plantations, on the catchment hydrological response and sediment yield. The instrumented site monitors hydro-meteorological and soil loss parameters at both microplot (1 m²) and small catchment (0.6 km²) scales. The monitored catchment is part of the network of critical zone observatories named Multiscale TROPIcal CatchmentS (M-TROPICS). The data shared by M-TROPICS in Houay Pano are (1) rainfall, (2) air temperature, air relative humidity, wind speed, and global radiation, (3) catchment land use, (4) stream water level, suspended particulate matter, bed particulate matter and stones, (5) soil surface features, and (6) soil surface runoff and soil detachment. The dataset has already been used to interpret suspended particulate matter and bed particulate matter sources and dynamics, to assess the impact of land-use change on catchment hydrology, soil erosion, and sediment yields, to understand bacteria fate and weed seed transport across the catchment, and to build catchment-scale models focused on hydrology and water quality issues. The dataset may be further used to, for example, assess the role of headwater catchments in large tropical river basin hydrology, support the interpretation of new variables measured in the catchment (e.g., contaminants other than faecal bacteria), and assess the relative impacts of both climate and land-use change on the catchment.     

The Imaclim-R model: infrastructures, technical inertia and the costs of low carbon futures under imperfect foresight

This paper analyzes the transition costs of moving towards a low carbon society when the second-best nature of the economy is accounted for. We emphasize the consequences on mitigation costs of considering the interplay between a) technical systems inertia, including slow infrastructure turnover in transportation and construction; and b) imperfect foresight influencing investment decisions. To this end, the hybrid general equilibrium modeling framework Imaclim-R is employed as it allows for transitory partial adjustments of the economy and captures their impact on the dynamics of economic growth. The modeling exercise quantitatively emphasizes the a) specific risks that the interplay between inertia and imperfect foresight leads to high macroeconomic costs of carbon abatement measures; b) opportunities of co-benefits from climate policies permitted by the correction of sub-optimalities in the reference scenarios. The article draws insights for the framing of future climate architectures by studying the role of measures that act complementarily to carbon pricing in the transport sector. In particular, reallocating public investment towards low-carbon transport infrastructure significantly reduces the overall macroeconomic costs of a given GHG stabilization target and even creates the room for long-term net economic benefits from climate policies.