DasT-P-Feld der Diagenese und niedrigtemperierten Metamorphose aufgrund von Mineralreaktionen

It is attempted to determineT, P values for the lowgrade metamorphic facies. From geologic-petrographic observations and from experiments mineralreactions are outlined which characterize the zeolitic-, the glaucophane- and the greenschistfacies, respectively. Only such reactions are considered which are univariant if P_f=P_s; thus aP-T grid can be arrived at. Experimental data on the equilibria of the relevant reactions is taken from the literature and from own experiments. Experimental results are always checked against known field-observations. Contrary to current opinium, we arrive at rather higher temperatures for the beginning of the lowgrade metamorphic facies: Diagenesis. From sedimentation up to slightly below 300° C. Zeolitic facies. From slightly below 300° C up to about 400° C. Greenschistfacies. From about 400° C up to about 550° C. Glaucophaneschistfacies. Under pressures of at least 6–7 kb this facies begins somewhat above 300° C, probably at about 330° C, grading into high-pressure greenschistfacies.     

Leaching and differential recrystallization of metamict zircon under experimental hydrothermal conditions

We report results of hydrothermal experiments on four alluvial zircons from Sri Lanka, which cover a wide range of radiation damage, at 450 °C and 1.3 kbar for 744 h with 2 M CaCl₂ solution as reactive fluid. After the hydrothermal treatment, the most metamict samples show micrometer-thick reaction rims, which surround apparently unreacted zircon, as revealed by cathodoluminescence (CL) and Nomarski differential interference contrast (NDIC) images. These rims have sharp, curved, and transgressive boundaries with unreacted zircon and are, in some cases, spread out along cracks. The thickness of reaction rims increases with increasing cumulated !-dosage of the starting materials. The reaction rims are strongly enriched in Ca (up to 7000 ppm) and a water species and depleted in radiogenic Pb, Zr, and Si, as revealed by electron microprobe analyses. A significant Th loss from the reaction rims was detected in the case of the most metamict sample, whereas U remained in the structure. FT-infrared spectrometry and X-ray diffraction measurements revealed that the bulk run products were recrystallized. Using micro-Raman spectrometry, we were able to demonstrate that differential recrystallization took place. The reaction rims are strongly recrystallized, whereas the unreacted grain interiors underwent only minor recrystallization. Recrystallization of the rims is accompanied by an enhancement of the integral CL intensity. It is suggested that recrystallization in the reaction rims was catalyzed by water infiltration and ion exchange and prevented significant congruent zircon dissolution under the given experimental conditions. Previous zircon studies have shown that (1) a transgressive morphology, (2) a reduced Th-U ratio, and (3) an enhanced CL emission are also characteristics of rims in zircons from high-grade metamorphic rocks. Based on these similarities between natural and experimentally produced rims, it is suggested that leaching-catalyzed recrystallization is an important alteration process in zircon under wet geological conditions and can account for many complex core-rim structures found in natural zircons. Furthermore, the strong enrichment of Ca in the reaction rims supports previous assumptions that high Ca concentrations in natural zircons are of secondary origin. It is suggested that lower U-Pb concordia intercept ages obtained from single-phase zircons with high Ca contents date a leaching event.     

Revision of the Conchostracan Genus Tenuestheria from the Upper Cretaceous Lanxi Formation in Zhejiang and Its Biostratigraphic Significance in Southeast China

The diagnosis of the conchostracan genus Tenuestheria from the Lanxi Formation in Jinhua, Zhejiang Province in Southeast China is revised following an examination of the type species under a scanning electron microscope, which revealed some morphological features on the carapace that had not been recognized previously. The importance of the Tenuestheria Fauna is considered in the context of correlation of six Turonian–Santonian formations in this region of China. The value of the Cenomanian Nemestheria and Turonian Linhaiella faunas in correlating the underlying early Late Cretaceous formations is also noted.     

The topographic imprint of a transient climate episode: the western Andean flank between 15·5° and 41·5°S

Mountain‐range topography is determined by the complex interplay between tectonics and climate. However, often it is not clear to what extent climate forces topographic evolution and how past climatic episodes are reflected in present‐day relief. The Andes are a tectonically active mountain belt encompassing various climatic zones with pronounced differences in rainfall, erosion, and glacier extent under similar plate‐boundary conditions. In the central to south‐western Andes, climatic zones range from hyperarid desert with mean annual rainfall of 5 mm/a (22·5°S) to year‐round humidity with 2500 mm/a (40°S). The Andes thus provide a unique setting for investigating the relationship between tectonics, climate, and topography. We present an analysis of 120 catchments along the western Andean watersheds between 15·5° and 41·5°S, which is based on SRTMV3‐90m data and new medium‐resolution rainfall, tropical rainfall measurement mission (TRMM) dataset. For each basin, we extracted geometry, relief, and climate parameters to test whether Andean topography shows a climatic imprint and to analyze how climate influences relief. Our data document that elevation and relief decrease with increasing rainfall and descending snowline elevation. Furthermore, we show that local relief reaches high values of 750 m in a zone between 28°S to 35°S. During Pleistocene glacial stages this region was affected by the northward shifting southern hemisphere Westerlies, which provided moisture for valley‐glacier formation and extended glacial coverage as well as glacial erosion. In contrast, the southern regions between 35°S to 40°S receive higher rainfall and have a lower local relief of 200 m, probably related to an increased drainage density. We distinguish two different, climatically‐controlled mechanisms shaping topography: (1) fluvial erosion by prolonged channel‐hillslope coupling, which smoothes relief, and (2) erosion by valley glaciers that generates relief. Finally, Our results suggests that the catchment‐scale relief of the Andes between 28°S to 35°S is characterized by a pronounced transient component reflecting past climatic conditions. Copyright © 2010 John Wiley & Sons, Ltd.     

Stockholm, Rio and beyond: Lessons from two decades of international environmental politics

Conclusion Studies that include moderate climate forecasts, farmer adaptation, carbon fertilization, and warm-loving crops tend to show that climate change will have only mild impacts on average global agricultural output and may even improve temperate agricultural production. On this point, recent studies yield strikingly consistent results. Of course, impact estimates still contain uncertainties. Key questions include how agriculture might change by 2060, how tropical and subtropical farming will be affected, and how effects will be distributed regionally. The most likely threat to agriculture from climate warming is regional damages in relatively poor areas that lack either the knowledge or the financial resources to adjust. Although it is not clear which regions will actually suffer, the ones that are most vulnerable lie predominantly in or near the tropics (IPCC, 1995). Nonetheless, on average, the factors discussed in this essay will help mitigate the impact of climate change on agriculture.The authors are grateful to the Electric Power Research Institute (EPRI) for financial support. We also wish to thank Richard Adams, Cynthia Rosenzweig, Kathleen Segerson, Joel Smith, Robert Unsworth and Thomas Wilson for their helpful comments. The authors alone are responsible for any remaining errors or omissions.     

Prograded foredunes of Western Australia's macro‐tidal coast – implications for Holocene sea‐level change and high‐energy wave impacts

The Holocene evolution of the Canning Coast of Western Australia has largely been overlooked so far mainly due to its remoteness and low population density. We report on new data from a sequence of foredunes inside the macro‐tidal Admiral Bay, 110 km southwest of Broome. Based on sediment cores, differential global positioning system (dGPS)‐based elevation transects, and stratigraphical analyses on outcrops of the relict foredunes, we aim at reconstructing Holocene coastal changes and relative sea levels (RSLs), as well as identifying and dating imprints of extreme‐wave events. Sedimentary analyses comprise the documentation of bedding structures, foraminiferal content and macrofaunal remains, grain size distribution, and organic matter. The chronological framework is based on 26 carbon‐14 accelerator mass spectrometry (¹⁴C‐AMS) datings. Marine flooding of the pre‐Holocene surface landward of the 2.5 km‐wide foredune barriers occurred 7400–7200 cal bp , when mangroves colonized the area. After only 200–400 years, a high‐energy inter‐tidal environment established and prevailed until c. 4000 cal bp , before turning into the present supralittoral mudflat. During that time, coastal regression led to beach progradation and the formation of aligned foredunes. Drivers of progradation were a stable RSL or gradual RSL fall after the mid‐Holocene and a positive sand budget. The foredunes overlie upper beach deposits located up to >2 m above the present upper beach level and provide evidence for a higher mid‐Holocene RSL. Discontinuous layers of coarse shells and sand are intercalated in the foredunes, indicating massive coastal flooding events. One such layer was traced over three dune ridges and dated to c. 1700–1550 cal bp . However, it seems that most tropical cyclones induce net erosion rather than deposition at aligned foredunes and thus, they are only suitable for reconstructing temporal variability if erosional features or sedimentation reliably tied to these events can be identified and dated accurately. Copyright © 2014 John Wiley & Sons, Ltd.     

Evaluation and application of dialysis porewater samplers for microbiological studies at sediment-water interfaces

The equilibrium diffusion technique has become a valuable tool for ecological and biogeochemical studies in aquatic environments. In sediment ecosystems, changes in concentration of microbial metabolites with increasing depth can be determined dependably and reproducibly with this technique. Since the permeation characteristics of the membranes employed are crucial, selecting the proper membrane requires knowledge about its behavior under conditions which prevail in the natural environment. Thirteen polymer sheets were evaluated comparing permeation terms for biogeochemically relevant solutes, biodegradability, and mechanical strength. Cellulose-based dialysis membranes are most satisfactory when employed in low temperature anoxic environments. For this membrane, correction terms were calculated to account for diffusion losses during retrieval and sampling. Optimal incubation times can now be predicted from experimentally determined permeation coefficients for several porewater solutes. Dialysis porewater samplers (DPS) have been successfully applied during more than 100 independent experiments for the collection of interstitial water from surface sediments. DPS were used for water depths as deep as 290 meters.