耦合模式长期积分中东亚夏季风与ENSO联系的不稳定性

通过对挪威卑尔根全球大气-海洋-海冰耦合模式300a控制积分结果进行交叉子波分析,揭示了东亚夏季风（EASM）与同期Nio3区（90°W～150°W,5°S～5°N）海洋表面温度异常的相关关系在长期变化中是不稳定的,呈现出明显的阶段性特征.气候要素场在二者联系的紧密（HCP）和微弱（LCP）时期差别显著,在HCP时期,西北太平洋对流层低层出现一对耦合的异常气旋和反气旋性环流系统;东南亚地区对流层低层表现为强东风异常,风速的年际变率加大;热带西太平洋对流层温度和位势高度场的年际变率普遍加强.此外,中国夏季降水与同期Nio3区海洋表面温度异常的相关关系在上述两种时期也存在较大差别.     

高纬度淡水强迫增强背景下大西洋经向翻转环流的响应及其机制

利用卑尔根海洋-大气-海冰耦合气候模式 (Bergen Climate Model, 简称BCM), 研究在北冰洋及北欧海淡水强迫增强的背景下, 大西洋经向翻转环流 (Atlantic Meridional Overturning Circulation, 简称AMOC) 的响应及其机制, 着重讨论了海表热力性质、 北大西洋深层水 (North Atlantic Deep Water, 简称NADW) 的生成率、 海洋内部等密度层间的垂直混合 (Diapycnal Mixing, 简称DM) 以及大气风场等物理过程随AMOC的响应所发生的时间演变特征.结果显示, 在持续150年增强 (强度为0.4 Sv) 的淡水强迫下 (淡水试验, FW1), AMOC的强度表现为前50年的快速减弱和在接下来100年中的逐渐恢复.同时, 在淡水试验的前50年北大西洋高纬度海表盐度 (Sea Surface Salinity, 简称SSS) 减小, 海水密度降低, 冬季对流混合减弱, 导致NADW生成率快速减弱; 在接下来的100年中, 尽管增强的淡水强迫依然维持, 由于海洋内部自身的调节和海气相互作用, 导致了AMOC的逐渐恢复.恢复机制可以概括为: (1) 随着向南的NADW的减少, 大西洋中低纬度海水垂直层结逐渐减弱, DM随之逐渐增强, 有利于中低纬度海盆内深层水的上升; (2) 南半球西风应力增强与东风应力的减弱及北半球东风的增强使得大西洋向北的埃克曼体积通量净传输恢复; (3) 大西洋向北的盐度传输逐渐恢复及次极地回旋区降水的减弱, 导致SSS和NADW生成率的恢复, 与之对应, AMOC逐渐恢复.研究还发现, 淡水试验中, NADW的恢复主要以厄尔明格海 (Irminger Sea) 为主, 冬季北大西洋海平面气压场 (SLP) 呈现类似正北大西洋涛动 (NAO+) 的模态, 热带降水中心移到赤道以南, 大西洋热带SSS增强.     

Simulating the effects of the 1991 Mount Pinatubo volcanic eruption using the ARPEGE atmosphere general circulation model

The climate changes that occured following the volcanic eruption of Mount Pinatubo in the Phillippines on 15 June 1991 have been simulated using the ARPEGE atmosphere general circulation model （AGCM）. The model was forced by a reconstructed spatial-time distribution of stratospheric aerosols intended for use in long climate simulations. Four statistical ensembles of the AGCM simulations with and without volcanic aerosols over a period of 5 years following the eruption have been made, and the calculated fields have been compared to available observations. The model is able to reproduce some of the observed features after the eruption, such as the winter warming pattern that was observed over the Northern Hemisphere （NH） during the following winters. This pattern was caused by an enhanced Equator-to-pole temperature gradient in the stratosphere that developed due to aerosol heating of the tropics. This in turn led to a strengthening of the polar vortex, which tends to modulate the planetary wave field in such a way that an anomalously positive Arctic Oscillation pattern is produced in the troposphere and at the surface, favouring warm conditions over the NH. During the summer, the model produced a more uniform cooling over the NH.     

1000 m long gas blow-out pipes

This study presents seismic observation of pipe anomalies from offshore Nigeria, outcrops of blow-out pipes from Rhodes, Greece, and geophysical modelling of an acoustic pipe. The studies give insight into how pipes form, their internal structure, the seismic image and geophysical artefacts related to the pipes. Over one hundred seafloor craters, 100 m-700 m wide and up to 30 m deep, have been observed on the seafloor offshore Nigeria. They are underlain by interpreted cones and seismic pipe anomalies that can be traced down to reservoir zones at 1000 m-1300 m below the seafloor. The seismic pipe anomalies are 50 m-150 m wide and almost vertical. They are interpreted as up-scaled pipes found in outcrops on Rhodes, Greece. The outcrops show pipe-related structures at three levels. Lowest, the reservoir rock contains metre-sized cavities which are filled with a mixture of clay derived from the overlying cap rock. In the middle, several circular to oval structures in plane view of pipes are observed in the lowest part of the cap rock. Highest, 15 m into the clay cap rock, strongly sheared country rock forms circular structures with a core of structureless clay. Based on outcrop observation on Rhodes we constructed an acoustic model of a 50 m wide and 1000 m long pipe. Seismic modelling proves that such pipes would be expressed in seismic data, that they are similar to the seismic pipe anomalies offshore Nigeria but this study also revealed that prominent intra-pipe reflections are artefacts. A formation model for the pipes is suggested: High fluid overpressure in the reservoir generated hydro fractures from the reservoir to seafloor where a mixture of gas and fluid flowed at high speed to form pipes, cones and seafloor craters. After hours to weeks of gas and fluid flow through the pipe the pore pressure in the reservoir dropped and the blow-out terminated. Muddy slurry fell back and plugged the cavity in the reservoir and the pipe.     

On the potential for CO2 mineral storage in continental flood basalts – PHREEQC batch- and 1D diffusion–reaction simulations

Continental flood basalts (CFB) are considered as potential CO₂ storage sites because of their high reactivity and abundant divalent metal ions that can potentially trap carbon for geological timescales. Moreover, laterally extensive CFB are found in many place in the world within reasonable distances from major CO₂ point emission sources. Based on the mineral and glass composition of the Columbia River Basalt (CRB) we estimated the potential of CFB to store CO₂ in secondary carbonates. We simulated the system using kinetic dependent dissolution of primary basalt-minerals (pyroxene, feldspar and glass) and the local equilibrium assumption for secondary phases (weathering products). The simulations were divided into closed-system batch simulations at a constant CO₂ pressure of 100?bar with sensitivity studies of temperature and reactive surface area, an evaluation of the reactivity of H₂O in scCO₂, and finally 1D reactive diffusion simulations giving reactivity at CO₂ pressures varying from 0 to 100?bar. Although the uncertainty in reactive surface area and corresponding reaction rates are large, we have estimated the potential for CO₂ mineral storage and identified factors that control the maximum extent of carbonation. The simulations showed that formation of carbonates from basalt at 40?C may be limited to the formation of siderite and possibly FeMg carbonates. Calcium was largely consumed by zeolite and oxide instead of forming carbonates. At higher temperatures (60 ?C 100?C), magnesite is suggested to form together with siderite and ankerite. The maximum potential of CO₂ stored as solid carbonates, if CO₂ is supplied to the reactions unlimited, is shown to depend on the availability of pore space as the hydration and carbonation reactions increase the solid volume and clog the pore space. For systems such as in the scCO₂ phase with limited amount of water, the total carbonation potential is limited by the amount of water present for hydration of basalt.     

Disinfection by-products and ecotoxicity of ballast water after oxidative treatment – Results and experiences from seven years of full-scale testing of ballast water management systems

Since 2005, five different ballast water management systems (BWMSs) based on chlorination treatment have been tested by Norwegian Institute for Water Research (NIVA) according to guidelines from the International Maritime Organization (IMO). 25% and >50% of all the tested discharge samples exhibited acute and chronic toxic effects on algae, respectively. In most cases this toxicity was plausibly caused by a high free residual oxidant (FRO) level (>0.08 mg Cl/l). Of the 22 disinfection by-products (DBPs) that were identified in treated water at discharge, four compounds were at times found at concentrations that may pose a risk to the local aquatic environment. However, there seemed to be no clear indication that the measured DBP concentrations contributed to the observed algal toxicity. The addition of methylcellulose instead of lignin in the test water to comply with IMO requirements seemed to limit the formation of DBP.     

Diagnostic lipid biomarker and stable carbon isotope signatures of microbial communities mediating the anaerobic oxidation of methane with sulphate

The anaerobic oxidation of methane (AOM) with sulphate is the most important sink for methane in marine environments. This process is mediated by a consortium of methanotrophic archaea and sulphate reducing bacteria. So far, three groups of anaerobic methane oxidisers (ANME-1, -2 and -3) related to the methanogenic Methanosarcinales and Methanomicrobiales were discovered. The sulphate reducing partner of ANME-1 and -2 are two different eco-types of SRB related to the Desulfosarcina/Desulfococcus cluster (Seep-SRB1), whereas ANME-3 is associated with Desulfobulbus spp. (DBB). In this article, we reviewed literature data to assign statistically significant lipid biomarker signatures for a chemotaxonomic identification of the three known AOM communities. The lipid signatures of ANME-2/Seep-SRB1 and ANME-3/DBB are intriguingly similar, whereas ANME-1/Seep-SRB1 shows substantial differences to these AOM communities. ANME-1 can be distinguished from ANME-2 and -3 by a low ratio of the isoprenoidal dialkyl glycerol diethers sn2-hydroxyarchaeol and archaeol combined with a comparably low stable carbon isotope difference of archaeol relative to the source methane. Furthermore, only ANME-1 contains substantial amounts of isoprenoidal glycerol dialkyl glycerol tetraethers (GDGTs), however, with the probable exception of the ANME-2c sub-cluster. In contrast to the ANME-1 archaea, the tail to tail linked hydrocarbon tetramethylhexadecane (crocetane) is unique to ANME-2, whereas pentamethylicosenes (PMIs) with 4 and 5 double bonds without any higher saturated homologues were only found in ANME-3. The sulphate reducing partner of ANME-1 can be discerned from those of ANME-2 and -3 by a low ratio of the fatty acids (FAs) C_16:1ω5 relative to i-C_15:0 and, although to a lesser degree, by a high abundance of ai-C_15:0 relative to i-C_15:0. Furthermore, substantial amounts of ¹³C depleted non-isoprenoidal monoalkyl glycerol ethers (MAGEs) were only found in the sulphate reducing partners of ANME-2 and -3. A differentiation of these SRB is possible based on the characteristic presence of the FAs cy-C_17:0ω5,6 and C_17:1ω6, respectively. Generally, the data analysed here show overlaps between the different AOM communities, which highlights the need to use multiple lipid signatures for a robust identification of the dominating microbes involved.     

一个淡水扰动试验中垂直混合对于北大西洋经圈环流的影响

It has been reported recently that the simulated Atlantic meridional overturning circulation(AMOC) using the coupled Bergen climate model(BCM) showed initial intensity declines followed by gradual recoveries over a 150-year enhanced freshwater input experiment.Stratification-dependent oceanic diapycnal mixing has been hypothesized as a reason for the simulated recovery of the AMOC.This study investigated the role of diapycnal mixing in transient responses of simulated AMOCs.Our results showed that stratification-dependent diapycnal mixing can cause stronger upwelling of deep water in the tropical Atlantic than that produced under conditions of fixed diapycnal mixing.Moreover,simulated AMOCs were more sensitive to active stratification-dependent diapycnal mixing than fixed mixing.However,stratification-dependent diapycnal mixing cannot be conclusively singled out as the critical cause of the recoveries of simulated AMOCs under enhanced-freshwater inputs.     

Variability in terrigenous sedimentation processes off northwest Africa and its relation to climate changes: Inferences from grain-size distributions of a Holocene marine sediment record

Variations in deposition of terrigenous fine sediments and their grain-size distributions from a high-resolution marine sediment record offshore northwest Africa (30°51.0′N; 10°16.1′W) document climate changes on the African continent during the Holocene. End-member grain-size distributions of the terrigenous silt fraction, which are related to fluvial and aeolian dust transport, indicate millennial-scale variability in the dominant transport processes at the investigation site off northwest Africa as well as recurring periods of dry conditions in northwest Africa during the Holocene. The terrigenous record from the subtropical North Atlantic reflects generally humid conditions before the Younger Dryas, during the early to mid-Holocene, as well as after 1.3 kyr BP. By contrast, continental runoff was reduced and arid conditions were prevalent at the beginning of the Younger Dryas and during the mid- and late Holocene. A comparison with high- and low-latitude Holocene climate records reveals a strong link between northwest African climate and Northern Hemisphere atmospheric circulation throughout the Holocene. Due to its proximal position, close to an ephemeral river system draining the Atlas Mountains as well as the adjacent Saharan desert, this detailed marine sediment record, which has a temporal resolution between 15 and 120 years, is ideally suited to enhance our understanding of ocean-continent-atmosphere interactions in African climates and the hydrological cycle of northern Africa after the last deglaciation.