Measurement of soluble reactive phosphorus concentration profiles and fluxes in river-bed sediments using DET gel probes

DET (diffusive equilibrium in thin films) gel probes were used for sampling river-bed sediment porewaters, to characterise in situ soluble reactive phosphorus (SRP) concentration profiles and fluxes. DET probes were deployed in three contrasting rural streams: (1) a headwater ‘pristine’ stream, with minimal P inputs from low intensity grassland and no point sources, (2) an intensively cultivated arable catchment, and (3) a stream subject to high P loadings from sewage effluent and intensive arable farming. The DET results showed highly enriched porewater SRP concentrations of between ca. 400 and 5000 μg-P l⁻¹ in the sewage-impacted stream. In contrast, the arable and pristine streams had porewater SRP concentrations <70 μg-P l⁻¹ and <20 μg-P l⁻¹, respectively. Porewater SRP concentration profiles in both the sewage-impacted and arable-impacted streams showed well-defined vertical structure, indicating internal sources and sinks of SRP within the sediment. However, there was little variability in porewater SRP concentrations in the pristine stream. The DET porewater profiles indicated net diffusion of SRP (a) from the overlying river water into the surface sediment and (b) from subsurface sediment upwards towards the sediment–water interface. A mass balance for the sewage-impacted site showed that the influx of SRP into the surface sediments from the overlying river water was small (ca. 1% of the daily river SRP load). The DET results indicated that, in the arable and sewage-impacted streams, the surface ‘cap’ of fine sediment may play an important role in inhibiting upward movement of SRP from subsurface porewaters into the overlying river water, under steady-state, low-flow conditions.     

Assigning a magmatically defined tectonic environment to Chitradurga metabasalts,India, by geochemical methods

The major and trace-element patterns in a set of 45 analyses of the Precambrian Chitradurga metabasalts have been interpreted by geochemical methods to classify the magma-types and to determine the tectonic environment of eruption.During amphibolitization of the tholeiites, the order of relative chemical stability is: SiO₂ > MgO > Al₂O₃ > FeO > CaO > Na₂O > K₂O > P₂O₅. On the ACFN plot the Chitradurga amphibolites approximate the unaltered basalts in their N component, show considerable depletion in F and A, and enrichment in the C components. With respect to the Keweenawan metadomains (pumpellyite and epidote), the Chitradurga amphibolites show considerable enrichment in N and depletion in the C constituents. The calc-alkaline (mol.props.) index, SiO₂ (wt.%) and “F”MA plots have shown the differentiation of the parent olivine normative tholeiite through the transitional calc-alkalic basalts to basaltic andesites; the ferrofemic index being 67.Discriminant functional analysis of the major-element patterns has classified the magma-types into ocean-floor basalts (9 analyses) and the volcanic arc series containing low-potassium tholeiites (24 analyses), calc-alkalic basalts (6 analyses) and basaltic andesites (6 analyses). The effective discrimination of the ocean-floor basalts from low-potassium tholeiites is accomplished due to the relatively low eigenvalues in functions F₁ and F₂ for SiO₂, K₂O and high values for MgO, TiO₂ in the former as compared to the latter. The low-K tholeiites are discriminated from calc-alkalic and basaltic andesites by the gradational increase in eigenvalues for K₂O, SiO₂ and Al₂O₃ in functions F₂ and F₃. The discriminant analyses of the trace-element patterns have classified the ocean-floor basalts from low-K tholeiites on TiCr, TiZr and Ti(× 10^?2)ZrY(× 3) plots. The TiO₂K₂OP₂O₅ plot has discriminated ocean-floor basalts, low-K tholeiites and the calc-alkalic group containing the basaltic andesite members. Thus the discriminant analysis of the major and trace-element patterns have shown noteworthy consistency, thereby attesting to the high success rate of classification.The Ca-Mg rich, low SiO₂, K₂O and alumina, olivine normative characteristics, and the normative pyroxene content of 36.15–45.88% of the ocean-floor basalts compare closely with those of the oceanic magma type of the Dalma volcanic suite of the north-eastern part of the Precambrian Indian shield of Bihar. These compositional features indicate their mantle origin, amphibolite and plagioclase—pyrolite assemblage of the upper mantle and relatively low-temperature, moderate pressure and hydrous environment of pyrolite.The presence of ocean-floor basalts at Chitradurga implies the existence of an oceanic rise and their eruption through its axial rift region. The mean Ti content (0.77%) of ocean-floor basalts compares closely with that of the Dalma suite (0.76%). The low-alumina content indicates faster spreading of the ocean floor.Identification of the magma-types of volcanic arc series containing a wide range of Zr and Y is attributed to quartz-normative fractionation of the magma and its differentiation to calc-alkalic and basaltic andesite members due to incorporation of sialic material by accretion in the marginal regions of the volcanic belt.Attention is focussed on the synonymous tectonic evolutionary trends of the two typical volcanic belts of the two geographically widely separated regions of the Indian Precambrian shield; the basis being: (1) low-alumina, enriched Ca-Mg and almost identical concentrations of Ti in the ocean-floor magma type, and (2) the presence of a pronounced volcanic arc magma type in the Chitradurga area and two analyses of a volcanic arc magma type in the Dalma area.     

Salinity-induced survival strategy of Vibrio cholerae associated with copepods in Cochin backwaters

The occurrence of Vibrio cholerae in water, sediment and copepods was studied over a wide range of salinity using conventional and polymerase chain reaction (PCR) techniques in the Cochin backwaters. V. cholerae occurred either as culturable or non-culturable form in this tropical estuary. During the pre monsoon period when high salinity prevailed (35.5psu) V. cholerae was associated with copepods only in non-culturable form, but with the onset of monsoon when lower salinity prevailed, copepod-associated-V. cholerae reverted back to culturable form. The optimum salinity range for culturability was found to be 15-20psu. This points to the fact that salinity is a major factor that which influences V. cholerae's culturability and its association with copepods in Cochin backwaters.     

Thallium isotopes as a potential tracer for the origin of cratonic eclogites

Cratonic eclogites are inferred to originate either from subducted ocean crust or mantle melts accreted onto the roots of continents. These models have different implications for the growth of continents, but it is currently difficult to determine the origin of individual eclogite suites.Upper ocean crust altered at low temperatures and marine sediments both display high thallium (Tl) concentrations and strongly fractionated Tl isotope signatures relative to the ambient upper mantle. In this study we carry out the first examination of the suitability of Tl isotopes as a tracer for an ocean-crust origin of cratonic eclogites. We have analysed the Tl isotope composition of clinopyroxene and garnet in six eclogites from the Kaalvallei and Bellsbank kimberlite pipes in South Africa. Minerals were pre-cleaned with an HCl leaching technique and the leachates display variably light Tl isotope ratios. These most likely reflect low-temperature hydrothermal alteration occurring after eruption of the kimberlite that carried the eclogites to the surface.The leached mineral pairs all display identical Tl isotope ratios, strongly suggesting that the source of the analysed Tl is identical for each mineral pair. It is, however, not possible to exclude the possibility that the analysed Tl originates from kimberlitic material that was not removed by the cleaning procedure.Only one of the six samples exhibits a Tl isotope composition different from ambient mantle. Assuming that the Tl isotope signatures indeed represent the eclogite minerals and not any form of contamination, the Tl isotope composition in this sample is consistent with containing a minor component (<3%) of ocean crust altered at low temperatures.Thallium isotopes may become one of the most sensitive indicators for the presence of low-T altered ocean crust because of the stark contrast in Tl concentration and isotopic composition between the mantle and altered ocean crust. In fact, no other chemical or isotopic tracer could have provided an indication that any of the samples studied here had a subduction origin. However, much work is still required before it becomes clear if Tl isotope measurements are a viable means to establish the origin of cratonic eclogites.     

Decadal variations in a Venus general circulation model

The Community Atmosphere Model (CAM), a 3-dimensional Earth-based climate model, has been modified to simulate the dynamics of the Venus atmosphere. The most current finite volume version of CAM is used with Earth-related processes removed, parameters appropriate for Venus introduced, and some basic physics approximations adopted. A simplified Newtonian cooling approximation has been used for the radiation scheme. We use a high resolution (1° by 1° in latitude and longitude) to take account of small-scale dynamical processes that might be important on Venus. A Rayleigh friction approach is used at the lower boundary to represent surface drag, and a similar approach is implemented in the uppermost few model levels providing a ‘sponge layer’ to prevent wave reflection from the upper boundary. The simulations generate superrotation with wind velocities comparable to those measured in the Venus atmosphere by probes and around 50-60% of those measured by cloud tracking. At cloud heights and above the atmosphere is always superrotating with mid-latitude zonal jets that wax and wane on an approximate 10 year cycle. However, below the clouds, the zonal winds vary periodically on a decadal timescale between superrotation and subrotation. Both subrotating and superrotating mid-latitude jets are found in the approximate 40-60 km altitude range. The growth and decay of the sub-cloud level jets also occur on the decadal timescale. Though subrotating zonal winds are found below the clouds, the total angular momentum of the atmosphere is always in the sense of superrotation. The global relative angular momentum of the atmosphere oscillates with an amplitude of about 5% on the approximate 10 year timescale. Symmetric instability in the near surface equatorial atmosphere might be the source of the decadal oscillation in the atmospheric state. Analyses of angular momentum transport show that all the jets are built up by poleward transport by a meridional circulation while angular momentum is redistributed to lower latitudes primarily by transient eddies. Possible changes in the structure of Venus’ cloud level mid-latitude jets measured by Mariner 10, Pioneer Venus, and Venus Express suggest that a cyclic variation similar to that found in the model might occur in the real Venus atmosphere, although no subrotating winds below the cloud level have been observed to date. Venus’ atmosphere must be observed over multi-year timescales and below the clouds if we are to understand its dynamics.     

Monthly prediction of rainfall over India and its homogeneous zones during monsoon season: a supervised principal component regression approach on general circulation model products

A supervised principal component regression (SPCR) technique has been employed on general circulation model (GCM) products for developing a monthly scale deterministic forecast of summer monsoon rainfall (June–July–August–September) for different homogeneous zones and India as a whole. The time series of the monthly observed rainfall as the predictand variable has been used from India Meteorological Department gridded (1°?×?1°) rainfall data. Lead 0 (forecast initialized in the same month) monthly products from GCMs are used as predictors. The sources of these GCMs are International Research Institute for Climate and Society, Columbia University, National Center for Environmental Prediction, and Japan Agency for Marine Earth Science and Technology. The performance of SPCR technique is judged against simple ensemble mean of GCMs (EM) and it is found that over almost all the zones the SPCR model gives better skill than EM in June, August, and September months of monsoon. The SPCR technique is able to capture the year to year observed rainfall variability in terms of sign as well as the magnitude. The independent forecasts of 2007 and 2008 are also analyzed for different monsoon months (Jun–Sep) in homogeneous zones and country. Here, 1982–2006 have been considered as development year or training period. Results of the study suggest that the SPCR model is able to catch the observational rainfall over India as a whole in June, August, and September in 2007 and June, July, and August in 2008.     

A photochemical model of the martian atmosphere

The factors governing the amounts of CO, O2, and O3 in the martian atmosphere are investigated using a minimally constrained, one-dimensional photochemical model. We find that the incorporation of temperature-dependent CO2 absorption cross sections leads to an enhancement in the water photolysis rate, increasing the abundance of OH radicals to the point where the model CO abundance is smaller than observed. Good agreement between models and observations of CO, O2, O3, and the escape flux of atomic hydrogen can be achieved, using only gas-phase chemistry, by varying the recommended rate constants for the reactions CO + OH and OH + HO2 within their specified uncertainties. Similar revisions have been suggested to resolve discrepancies between models and observations of the terrestrial mesosphere. The oxygen escape flux plays a key role in the oxygen budget on Mars; as inferred from the observed atomic hydrogen escape, it is much larger than recent calculations of the exospheric escape rate for oxygen. Weathering of the surface may account for the imbalance. Quantification of the escape rates of oxygen and hydrogen from Mars is a worthwhile objective for an upcoming martian upper atmospheric mission. We also consider the possibility that HOx radicals may be catalytically destroyed on dust grains suspended in the atmosphere. Good agreement with the observed CO mixing ratio can be achieved via this mechanism, but the resulting ozone column is much higher than the observed quantity. We feel that there is no need at this time to invoke heterogeneous processes to reconcile models and observations.     

Numerical Simulations of the Impacts of Land-Cover Change on a Southern Sea Breeze in South-West Western Australia

A sea-breeze event in south-west Western Australia is simulated using the Regional Atmospheric Modelling System (RAMS) version 6.0. The model is evaluated against high resolution soundings as well as station observations and is shown to reproduce the qualitative features of the sea breeze well. Sensitivity tests are carried out to investigate the effects of historical land-cover change and changes in soil moisture on the dynamics of the sea breeze. It is found that land-cover change alone, i.e., a change from wooded grasslands to bare soil, with no change in soil moisture initialisation, does not significantly alter the overall structure of the sea breeze but results in higher surface winds due to the reduced vegetation roughness length, which leads to enhanced surface moisture advection inland. On the other hand, land-cover change in conjunction with increased soil moisture results in a considerably weaker, shallower, and less penetrative sea breeze, and delays its onset and duration. A sea-breeze scaling analysis highlights the impact of increasing soil moisture on reducing the sea-breeze volume flux scale.