Fluxes of amino acids and hexosamines to the deep Arabian Sea

Results of organic carbon, total nitrogen, amino acid and hexosamine analyses of samples collected during time-series sediment trap investigations in the Arabian Sea are presented. Samples were taken over a period of years at two depths at each of three locations in the western, central and eastern part of the basin. Seasonal changes in amino acid contents and their spectral distributions show that degradation of organic matter in the water column is reduced during the monsoons, which are the high-flux periods in the western and central Arabian Sea. At the eastern site more degraded material of possibly recycled marine or terrestrial origin reaches the traps during the late summer peak fluxes. The results of hexosamine analyses suggest that bacterial biomass is relatively enriched on particles sinking in the water column and, to a larger extent, at the sediment-water interface. Decomposition between intermediate and deep water results in a loss of 30–40% of total organic carbon and more than 40% of amino acids. Comparison of the measured accumulation rates of organic carbon in sediment traps with those of organic carbon preserved in sediments show that more than 85% is lost before final burial in the sediments. Organic matter preservation in the Arabian Sea is higher than the average for the open ocean; this maybe due to the abundance of refractory organic matter of recycled marine or terrestrial origin.     

Impact of Land Surface Heterogeneity on Mesoscale Atmospheric Dispersion

Prior numerical modelling studies show that atmospheric dispersion is sensitive to surface heterogeneities, but past studies do not consider the impact of a realistic distribution of surface heterogeneities on mesoscale atmospheric dispersion. While these focussed on dispersion in the convective boundary layer, the present work also considers dispersion in the nocturnal boundary layer and above. Using a Lagrangian particle dispersion model (LPDM) coupled to the Eulerian Regional Atmospheric Modeling System (RAMS), the impact of topographic, vegetation, and soil moisture heterogeneities on daytime and nighttime atmospheric dispersion is examined. In addition, the sensitivity to the use of Moderate Resolution Imaging Spectroradiometer (MODIS)-derived spatial distributions of vegetation characteristics on atmospheric dispersion is also studied. The impact of vegetation and terrain heterogeneities on atmospheric dispersion is strongly modulated by soil moisture, with the nature of dispersion switching from non-Gaussian to near-Gaussian behaviour for wetter soils (fraction of saturation soil moisture content exceeding 40%). For drier soil moisture conditions, vegetation heterogeneity produces differential heating and the formation of mesoscale circulation patterns that are primarily responsible for non-Gaussian dispersion patterns. Nighttime dispersion is very sensitive to topographic, vegetation, soil moisture, and soil type heterogeneity and is distinctly non-Gaussian for heterogeneous land-surface conditions. Sensitivity studies show that soil type and vegetation heterogeneities have the most dramatic impact on atmospheric dispersion. To provide more skilful dispersion calculations, we recommend the utilisation of satellite-derived vegetation characteristics coupled with data assimilation techniques that constrain soil-vegetation-atmosphere transfer (SVAT) models to generate realistic spatial distributions of surface energy fluxes.     

Gold Mineralization in Kottathara Prospect, Attappadi Valley, Kerala, India: a Preliminary Appraisal

The Kottathara gold prospect of Attappadi Valley in Kerala is located within the Southern Indian Granulite Terrain comprising charnockite and gneisses with enclaves of high-grade supracrustals. The gold mineralization associated with the basic members of the Attappadi supracrustals and the quartz veins traversing them are confined within the Bhavani Shear Zone. Primarily the gold-quartz lode is emplaced in rheologically preferred zones along the contact of the basic members with the enclosing gneisses subsequent to a period of retrogression and shearing. Ore-mineralogical studies reveal that gold got remobilized and this remobilization is identified with the regional Bhavani Shear. SEM studies indicate that gold occurs in free state and also within sulphides especially pyrite. Variation in grain morphology is clearly discernible in gold occurring within oxidised and in non-oxidised zones.Sequencing of deformational events with associated emplacements of known ages suggests the age of gold mineralization of Attappadi area as between 2 Ga. and 2.5 Ga. The secondary mobilization has to be <2.0 Ga or younger possibly of younger Pan-African age related with the Moyar-Bhavani Shear System. The inherent gold content of the komatiitic metapyroxenites together with the auriferous quartz lodes assigns a lithological control on gold mineralisation. Subsequent folding and remobilization due to the regional shear constrained the geometry of the lode zones implying structural control.     

Granite-molybdenite association in Kerala in relation to taphrogenic metallogeny

Two molybdenite-bearing granites from the Kerala region, namely, the Chengannoor and the Ambalavayal granites are discussed here in terms of their salient geochemical characters. The geochemistry of the host rocks indicates a peraluminous, calc-alkaline to alkali-calcic nature and the element levels show good fit with the proposed ‘finger-prints’ for granite-molybdenite systems. Fluid inclusion studies suggest that Mo was probably partitioned in vapour phase, which subsequently combined with available sulphur. Regional distribution of molybdenite strongly favours the view of a molybdenum province in the southern part of the Indian shield. Associations of rare metal mineralization with the riftcontrolled acid magmatic phase in the Kerala region are suggestive of a late Precambrian —Early Palaeozoic taphrogenic metallogeny.