Petrographic and geochemical characterization of the granitic rocks of the Araguainha impact crater,Brazil

Petrographic and geochemical data obtained on the Araguainha impact crater (Goiás/Mato Grosso States, Brazil) indicate the existence of several molten products that originated during impact‐induced congruent melting of an alkali‐granite exposed in the inner part of the central uplift of the structure. Although previous studies have described these melts to some extent, there is no detailed discussion on the petrographic and geochemical variability in the granite and its impactogenic derivatives, and therefore, little is known about the geochemical behavior and mobility of trace elements during its fusion in the central part of the Araguainha crater. This paper demonstrates that the preserved granitoid exposed in the core of the structure is a magnesium‐rich granite, similar to postcollisional, A‐type granites, also found in terrains outside the Araguainha crater, in the Brasília orogenic belt. The molten products are texturally distinct and different from the original rock, but have very similar geochemical composition, making it difficult to separate these lithotypes based on concentrations of major and minor elements. This also applies for trace and rare earth elements (REE), thus indicating a high degree of homogenization during impact‐induced congruent melting under high pressure and postshock temperature conditions. Petrographic observations, along with geochemical data, indicate that melting occurs selectively, where some of the elements are transported with the melt. Simultaneously, there is an effective dissolution of the rock (granite), which leads to entrainment of the most resistant solid phases (intact or partially molten minerals) into the melt. Minerals more resistant to melting, such as quartz and oxides, contribute substantially to a chemical balance between the preserved granite and the fusion products generated during the meteoritic impact.     

Yardangs in terrestrial ignimbrites: Synergistic remote and field observations on Earth with applications to Mars

The conditions of formation and the form of yardangs in ignimbrites in the Central Andes of Chile, Bolivia, and Argentina may be the most convincing terrestrial analog to the processes and lithology that produce the extensive yardangs of the Medusae Fossae Formation (MFF) of Mars. Through remote and field study of yardang morphologies in the Central Andes we highlight the role that variable material properties of the host lithology plays in their final form. Here, ignimbrites typically show two main facies: an indurated and jointed facies, and a weakly to poorly indurated, ash- and pumice-rich facies. Both facies are vertically arranged in large (erupted volume >100's of km³) ignimbrites resulting in a resistant capping layer, while smaller (10's of km³) ignimbrites are made predominantly of the weakly indurated facies. The two facies have quite different mechanical properties; the indurated facies behaves as strong rock, fails by block collapse and supports steep/vertical cliffs, while the non-indurated facies is more easily eroded and forms gentle slopes and manifests as more subdued erosional forms. In response to aeolian action, the presence of an upper indurated facies results in large, elongate, high aspect ratio (1:20-1:40) megayardangs that form tall (100 m), thin ridges with steep to vertical walls. These are built on a broad apron of the weakly indurated facies with abundant fallen blocks from the upper indurated facies. These terrestrial megayardangs appear to be analogous to megayardangs with associated block fields seen on Mars. Smaller-volume, weakly indurated ignimbrites are sculpted into smaller, stubbier forms with aspect ratios of 1:5-1:10 and heights rarely exceeding 10 m. Excavation of a windward basal moat suggests an erosional progression like that seen in incipient yardangs on Mars. Excavation rates of 0.007-0.003 cm/year are calculated for the weakly indurated ignimbrites. While a persistent strong unidirectional wind is the dominant parameter controlling yardang formation and orientation, a role for flow separation and vorticity is also suggested by our observations at both yardang types. While the indurated facies is commonly pervasively jointed, jointing is of secondary importance in controlling yardang orientation. Serrated margins, a common feature on Mars, result from oblique intersections of jointing with yardang flanks or scarps of ignimbrite. The processes of yardang formation we describe from ignimbrites from the Central Andes are not necessarily specific to ignimbrites, but do connote that degree and distribution of induration is a major control in yardang formation and this has implications for the lithology of the MFF on Mars.     

Simulation of the Askervein flow. Part 2: Large-eddy simulations

Large-eddy simulations of the neutrally stratified flow over the Askervein Hill were performed, to improve the knowledge of the flow obtained from field measurements and numerical simulations with Reynolds averaged Navier-Stokes (RANS) methods. A Lagrangian dynamic subgrid model was used but, to avoid the underdissipative character near the ground, it was merged with a damped Smagorinsky model. Simulations of a flat boundary-layer flow with this subgrid model showed that the turbulent vertical motions and shear stress were better resolved using grids with a stream to spanwise aspect ratio Δx / Δy = 2 than with an aspect ratio Δx / Δy = 1. Regarding the flow over the Askervein Hill, it was found that large-eddy simulations provide an acceptable solution for the mean-velocity field and better predictions of the turbulent kinetic energy in the upstream side of the hill than the model. However, as with the model, grid convergence was not achieved in the lee side and the size of the zone with reversed flow increased with the grid refinement. Nevertheless, the existence of the intermittent separation predicted with unsteady RANS in part one of this work seems unquestionable, due to the deceleration of the flow. In our opinion, a better modelling of the decelerating boundary layer in the lee side is required to improve the results obtained using equilibrium assumptions and achieve grid convergence.     

Geotechnical Characterization by In situ and Lab Tests to the Back-Analysis of a Supported Excavation in Metro do Porto

This paper summarizes the geotechnical characterization conducted for the design and subsequent analysis of a strutted excavation in “Metro do Porto”. This region is geologically dominated by heterogeneous weathered granite masses with deep residual soil profiles. Local saprolitic soils exhibit, by their nature, a particular behavior characterized by very sensitive and weak relic micro-structures, due to their specific genesis. This study has included the interpretation of a significant volume of in situ test results, triaxial tests over undisturbed samples and monitoring data, giving rise to specific correlations between testing and design parameters. Real time monitoring enabled a back-analysis by FEM of a well instrumented section of the strutted excavation, which was calibrated taking into account the derived correlations and the deformability behavior of this specific geotechnical ambient. This geomaterial, although revealing very high initial stiffness values (for very small strain ranges) has shown low stiffness values for “medium to high” strain levels, reflecting a singular strong non-linearity in the stress-strain behavior.     

Variability over time in the sources of South Portuguese Zone turbidites: evidence of denudation of different crustal blocks during the assembly of Pangaea

This study combines geochemical and geochronological data in order to decipher the provenance of Carboniferous turbidites from the South Portuguese Zone (SW Iberia). Major and trace elements of 25 samples of graywackes and mudstones from the Mértola (Visean), Mira (Serpukhovian), and Brejeira (Moscovian) Formations were analyzed, and 363 U-Pb ages were obtained on detrital zircons from five samples of graywackes from the Mira and Brejeira Formations using LA-ICPMS. The results indicate that turbiditic sedimentation during the Carboniferous was marked by variability in the sources, involving the denudation of different crustal blocks and a break in synorogenic volcanism. The Visean is characterized by the accumulation of immature turbidites (Mértola Formation and the base of the Mira Formation) inherited from a terrane with intermediate to mafic source rocks. These source rocks were probably formed in relation to Devonian magmatic arcs poorly influenced by sedimentary recycling, as indicated by the almost total absence of pre-Devonian zircons typical of the Gondwana and/or Laurussia basements. The presence of Carboniferous grains in Visean turbidites indicates that volcanism was active at this time. Later, Serpukhovian to Moscovian turbiditic sedimentation (Mira and Brejeira Formations) included sedimentary detritus derived from felsic mature source rocks situated far from active magmatism. The abundance of Precambrian and Paleozoic zircons reveals strong recycling of the Gondwana and/or Laurussia basements. A peri-Gondwanan provenance is indicated by zircon populations with Neoproterozoic (Cadomian-Avalonian and Pan-African zircon-forming events), Paleoproterozoic, and Archean ages. The presence of late Ordovician and Silurian detrital zircons in Brejeira turbidites, which have no correspondence in the Gondwana basement of SW Iberia, indicates Laurussia as their most probable source.     

Catastrophic,rainfall-induced debris flows in Andean villages of Tarapacá, Atacama Desert,northern Chile

In March 2012, during the rainy season in the Altiplano plateau, a >100-year return period rainfall event affected the deeply incised valleys of the Precordillera of the Tarapacá Region, northern Chile. This extreme event in a very arid region triggered a number of debris and mud flows that caused severe damage and destruction in several small villages along the Camiña and Tarapacá valleys. The highly vulnerable location of the villages on top of alluvial fans due to socioeconomic and cultural reasons is a key factor to explain the level of destruction in most villages. In this paper, this unusual, remarkable landslide event is described, and the hazard faced by these settlements for future rainfall episodes and possible mitigation measures are discussed.     

Metal and metalloid leaching from tailings into streamwater and sediments in the old Ag–Pb–Zn Terramonte mine,northern Portugal

Tailings deposited over the Castanheira, a stream which flows through the old Ag–Pb–Zn Terramonte mine area, showed a great potential environmental risk due to sulphide weathering, facilitated by the tailings–water interaction. The high concentrations of Al, Fe, Pb and Zn in the tailings are associated with the exchangeable, reducible and sulphide fractions and suggest sphalerite and pyrite occurrences. Oxidation of pyrite is responsible for the low pH values (3.38–4.89) of the tailings. The water from the Castanheira stream is not suitable for human consumption due to high concentrations of SO₄ ^2?, Mn, Al, Cd, Ni, and Pb. The lowest concentrations of metals and metalloids were detected in downstream stretches of the Castanheira. However, As, Fe and Zn in deeper sediments tend to increase downstream. Significant concentrations of trivalent forms of arsenic were detected in water samples. In downstream stretches of the Castanheira, some free ions (Fe²⁺, Mn²⁺ and Zn²⁺) also predominate and the water is saturated with ferrihydrite, goethite, hematite, lepidocrosite and magnetite.     

Fate and transport of pollutants through a municipal solid waste landfill leachate in Sri Lanka

This study focuses on the characterization of leachate generated from Gohagoda dumpsite in Kandy, Sri Lanka, assessment of its spatial and temporal variations, and identification of subsurface canals and perched water bodies in the wetland system affected by the leachate flow. Leachate samples were collected monthly throughout dry and rainy seasons from different points of the leachate drainage channel over a period of 1 year and they were tested for quality parameters: pH, temperature, electrical conductivity, total dissolved soils, alkalinity, hardness, total solids, volatile solids, total suspended solids, volatile suspended solids, biochemical oxygen demand (BOD₅), chemical oxygen demand, nitrate-nitrogen, nitrite-nitrogen, phosphates, ammonium-nitrogen, chloride, dissolved organic carbon, total organic carbon and heavy metals. Sequential soil extraction procedures were performed for the characterization of leachate-affected local soil. A geophysical survey using direct current resistivity technique was conducted at locations downstream of the dumpsite. Leachate characteristics indicated that the leachate is in the methanogenic phase and the results strongly suggest that the leachate may be polluting the river where the leachate is discharged directly. Leachate exceeds the allowable limits of Sri Lankan wastewater discharge standards for many of the parameters. Significant difference (P < 0.05) was observed for most of organic and inorganic parameters among all sampling locations. Many parameters showed a negative correlation with pH. The affected soils showed high heavy metal concentrations. Resistivity study confirmed a confined leachate flow at the near surface with few subsurface canals. However, no separate subsurface plume movement was observed. The results of this research can effectively be used for the establishment of an efficient and effective treatment method for the Gohagoda landfill leachate.     

A Multiple Training Image Approach for Spatial Modeling of Geologic Domains

Characterization of complex geological features and patterns remains one of the most challenging tasks in geostatistics. Multiple point statistics (MPS) simulation offers an alternative to accomplish this aim by going beyond classical two-point statistics. Reproduction of features in the final realizations is achieved by borrowing high-order spatial statistics from a training image. Most MPS algorithms use one training image at a time chosen by the geomodeler. This paper proposes the use of multiple training images simultaneously for spatial modeling through a scheme of data integration for conditional probabilities known as a linear opinion pool. The training images (TIs) are based on the available information and not on conceptual geological models; one image comes from modeling the categories by a deterministic approach and another comes from the application of conventional sequential indicator simulation. The first is too continuous and the second too random. The mixing of TIs requires weights for each of them. A methodology for calibrating the weights based on the available drillholes is proposed. A measure of multipoint entropy along the drillholes is matched by the combination of the two TIs. The proposed methodology reproduces geologic features from both TIs with the correct amount of continuity and variability. There is no need for a conceptual training image from another modeling technique; the data-driven TIs permit a robust inference of spatial structure from reasonably spaced drillhole data.