Complex formation in the ternary system Mg(II)-CO2-H2O

The carbonato and hydrogencarbonato complexes of Mg²⁺ were investigated at 25 and 50° in solutions of the constant ClO₄^? molality (3 M) consisting preponderantly of NaClO₄. The experimental data could be explained assuming the following equilibria: Mg²⁺ + CO_2B + H₂O ag MgHCO⁺₃ + H⁺, $\text{log}{}^1\text{β}{}_1\text{= ?7.64}{}_4\text{± 0.01}{}_7\text{(25°), ?7.46}{}_2\text{± 0.01}{}_1\text{(50°)}$, Mg²⁺ + 2 CO_2g + 2 H₂Oag Mg(HCO₃)⁰₂ ± 2 H⁺, $\text{log}{}^1\text{β}{}_2\text{= ?15.00 ± 0.14 (25°)}$, ?15.37 ± 0.39 (50°), Mg²⁺ + CO_2g + H₂Oag MgCO⁰₃ + 2 H⁺, $\text{log}{}^1\text{k}{}_1\text{= ?15.64 ± 0.06 (25°)}$,?15.23 ± 0.02 (50°), with the assumption γ_MgCO3⁰ = γ_Mg(HCO3)⁰2, ΔG⁰(I = 0) for the reaction MgCO⁰₃ + CO_2g + H₂O = Mg(HCO₃)⁰₂ was estimated to be ?3.9₁ ± 0.8₆ and 0.6 ± 2.4 kJ/mol at 25 and 50°C, respectively. The abundance of carbonate linked Mg(II) species in fresh water systems is discussed.     

The Venus ionosphere at grazing incidence of solar radiation: Transport of plasma to the night ionosphere

Using a quasi-two-dimensional model of the Venus ionosphere, we calculated the ion number densities and horizontal ion bulk velocities expected for a range of solar zenith angles near the terminator (80 to 100°), and compared them with data obtained from the Pioneer Venus Orbiter retarding potential analyzer. The calculated ion bulk velocity arises entirely from the solar EUV-induced plasma pressure gradient and has a magnitude consistent with observations; ionization by suprathermal electrons is neglected in those computations. We find that while photoionization is the dominant source of ionospheric plasma for solar zenith angles less than 92°, plasma transport from the dayside is the dominant plasma source for solar zenith angles greater than 95°. We also show that the main nightside plasma peak at approximately 140 km altitude is of the F₂ type (i.e., is diffusion controlled). Its altitude and shape are thus quite insensitive to the altitude of the ion source.     

First Results from Viper: Detection of Small-scale Anisotropy at 40 GHz

Using all available major samples of Seyfert galaxies and their corresponding closely matched control samples of nonactive galaxies, we find that the bar ellipticities (or axial ratios) in Seyfert galaxies are systematically different from those in nonactive galaxies. Overall, there is a deficiency of bars with large ellipticities (i.e., "thin" or "strong" bars) in Seyfert galaxies compared to nonactive galaxies. Accompanied with a large dispersion due to small number statistics, this effect is strictly speaking at the 2 sigma level. To obtain this result, the active galaxy samples of near-infrared surface photometry were matched to those of normal galaxies in type, host galaxy ellipticity, absolute magnitude, and, to some extent, redshift. We discuss possible theoretical explanations of this phenomenon within the framework of galactic evolution, and, in particular, of radial gas redistribution in barred galaxies. Our conclusions provide further evidence that Seyfert hosts differ systematically from their nonactive counterparts on scales of a few kiloparsecs.     

Ion winds in Saturn's southern auroral/polar region

We present profiles of the line-of-sight (l.o.s.) ionospheric wind velocities in the southern auroral/polar region of Saturn. Our velocities are derived from the measurement of Doppler shifting of the H₃⁺ν₂Q(1,0⁻) line at 3.953 microns. The data for this study were obtained using the facility high-resolution spectrometer CSHELL on the NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii, during the night of February 6, 2003 (UT). The l.o.s. velocity profiles finally derived are consistent with an extended region of the upper atmosphere sub-corotating with the planet: the ion velocities in the inertial reference are only 1/3 of those expected for full planetary corotation. We discuss the results in the light of recent proposals for the kronian magnetosphere, and suggest that, in this region, Saturn's ion winds may be under solar wind control.     

Why the fundamental plane of black hole activity is not simply a distance driven artifact

The fundamental plane of black hole activity is a non-linear correlation among radio core luminosity, X-ray luminosity and mass of all accreting black holes, both of stellar mass and supermassive, found by Merloni et al. [Merloni, A., Heinz, S., di Matteo, T. 2003. MNRAS 345, 1057 (MHD03)] and, independently, by Falcke et al. [Falcke, H., Körding, E., Markoff, S., 2004. A& A 414, 895]. Here we further examine a number of statistical issues related to this correlation. In particular, we discuss the issue of sample selection and quantify the bias introduced by the effect of distance in two of the correlated quantities. We demonstrate that the fundamental plane relation cannot be a distance artifact, and that its non-linearity must represent an intrinsic characteristic of accreting black holes. We also discuss possible future observational strategies to improve our understanding of this correlation.