Tracing the history of submarine hydrothermal inputs and the significance of hydrothermal hafnium for the seawater budget—a combined Pb-Hf-Nd isotope approach

Secular variations in the Pb isotopic composition of a mixed hydrogenous-hydrothermal ferromanganese crust from the Bauer Basin in the eastern Equatorial Pacific provide clear evidence for changes in hydrothermal contributions during the past 7 Myr. The nearby Galapagos Rise spreading center provided a strong hydrothermal flux prior to 6.5 Ma. After 6.5 Ma, the Pb became stepwise more radiogenic and more similar to Equatorial Pacific seawater, reflecting the westward shift of spreading to the presently active East Pacific Rise (EPR). A second, previously unrecognized enhanced hydrothermal period occurred between 4.4 and 2.9 Ma, which reflects either off-axis hydrothermal activity in the Bauer Basin or a late-stage pulse of hydrothermal Pb from the then active, but waning Galapagos Rise spreading center.Hafnium isotope time-series of the same mixed hydrogenous-hydrothermal crust show invariant values over the past 7 Myr. Hafnium isotope ratios, as well as Nd isotope ratios obtained for this crust, are identical to that of hydrogenous Equatorial Pacific deep water crusts and clearly indicate that hydrothermal Hf, similar to Nd, does not travel far from submarine vents. Therefore, we suggest that hydrothermal Hf fluxes do not contribute significantly to the global marine Hf budget.     

Chlorite geothermometry and the temperature conditions at the Variscan thrust front in eastern Belgium

Geologie en Mijnbouw -     

The short term response to eutrophication abatement

We compare results of a new model for predicting the short term inter annual changes in chlorophyll-a (chl-a) in lakes after reductions in total phosphorus (TP) to predictions made by least squares regression models. In the new method, slopes of chl-a/TP graphs (both axes in mg · m^–3) are depicted in frequency diagrams and used to extract information on the expected, short term chl-a/TP response. The short term response for nine shallow (< 10 m deep) and nutrient rich lakes to changes in TP was found to be: Chl-a = 0.49 · TP + 17.3, and for nine deep, P-limited lakes: Chl-a = 0.08 · TP + 3.5. If the TP-reduction is known to be greater than 10 mg · m^–3, the expected slope increases to 0.58 for shallow lakes and to 0.26 for deep lakes. The slope, 0.58, is 8% lower than the slope for the long term response calculated by regression for the shallow lakes. For deep lakes the slope, 0.26, is 2 to 3 times higher than that calculated by regression, indicating that reductions in TP for deep lakes give greater effects than least squares regression equations suggest. We have also calculated the reduction in TP which will give about 80% probability that a reduction in chl-a will be observed next year. For shallow, P-limited lakes this reduction is about 30 mg · m^–3 (5% of average initial in-lake TP concentration), and for deep lakes about 14 mg · m^–3 (35% of average initial in-lake TP concentration).     

An objective test of earthquake migrations in Turkey

An objective method for the examination of supposed migration of earthquake epicenters is discussed and tested for the Turkey region.     

Heavy Oil and Oil (Tar) Sands in North America: An Overview & Summary of Contributions

As conventional oil and gas reservoirs become depleted other unconventional energy sources have to be recovered and produced. Four of the major unconventional resources that are strategic for North American interests are heavy oil, oil sands, oil shales, and coal-bed methane. Recent interest and activity in Canada’s vast oil sands are progressing rapidly as soaring oil prices are fueling a ‘gold rush’ in oil sands development in Alberta. This interest is evident by the record-number of oil sands and heavy oil presentations at Energy Minerals Division (EMD)-sponsored sessions at the 2004 and 2005 Annual Conventions of the American Association of Petroleum Geologists (AAPG), held in Dallas, TX and Calgary, AB.     

Absolute dating of the youngest sediments of the Swiss Molasse basin by apatite fission track analysis

A set of ash layer samples within the uppermost Upper Freshwater Molasse (OSM) sediments (N and E of Frauenfeld, Switzerland) was dated by apatite fission track (FT) means. The ages indicate an early Tortonian (perhaps latest Serravallian) eruption and sedimentation age of 11.5 ± 0.3 Ma. The age is in agreement with time constraints by Mammalian relicts which point to MN7-8. Due to the position of the ash layers close to the erosional gap and overlying Quaternary cover, the age represents a maximum age for the cessation of OSM sedimentation in the Swiss Molasse Basin. However, the end of Molasse sedimentation in this region had not stopped before the cover of OSM sediments by volcanic ash layers at the Höwenegg volcano (southern Germany), an event further constrained by an apatite FT age of 9.8 (?0.7/+0.8) Ma from a hornblende-bearing ash layer at Höwenegg. An isolated bentonitic ash layer occurring 25 km to the WSW of the main set of dated ashes (near Humlikon) has an age component identical to the OSM ash layers near Frauenfeld. The age suggests a source for this material within the Hegau, but is too young to be related to the volcanic activity at the Kaiserstuhl.The apatites from the ash layer samples show two distinct compositional populations, one very close to a Cl end member and one with apatites of equal proportions of Cl and OH end member. These populations are interpreted to have possibly originated from at least two distinct igneous sources for the ashes, separated by their eruption site or eruption time or both. The distinct compositional data on the volcanic apatites may provide a basis to clarify their origin in future work.     

The use of (14)C tracer technique to assess the functional response of zooplankton community grazing to toxic impact

The use of functional endpoints in risk assessment of pollutants for marine pelagic communities is scarce, especially for the function of zooplankton communities. This work presents a rapid, inexpensive and ecologically relevant technique to assess the effect of toxic compounds on the grazing rates of zooplankton communities. The combination of a (14)C-tracer labelling technique with a fast (< 3 h) and representative sub-sampling and handling makes it possible to measure changes in food uptake of freshly collected natural zooplankton communities in a short-term assay. The methodology is described and its validity is determined by a full account of the fate of isotope tracers (up to 15% taken up by zooplankton). Egg production of Acartia tonsa cultures exposed to DCOI yielded EC(50) values of 118+/-33 nM DCOI after three days, where EC(50) values from grazing of natural zooplankton communities was 136+/-29 nM DCOI, indicating that grazing was the more sensitive variable. Finally the method was tested in a mesocosm experiment designed to evaluate the toxicity of the antifouling compound zinc pyrithion (ZPT) with an EC(50) value of 17 nM ZPT (SD=3.3 nM, n=3). The method was found to be reproducible both at the community (CV=8-39%) and individual level (CV=23-53%), and could detect small changes in response to a toxicant in a natural pelagic system. The use of natural communities in combination with the fast and cost-effective procedure makes this technique a powerful tool in risk assessment, where lack of ecological relevance or reproducible results often results in unwanted high uncertainties.     

Contrasting behaviour of trace metals in the Scheldt estuary in 1978 compared to recent years

Dissolved and particulate trace metals (Cu, Cd, Pb, Zn, Ni, Fe and Mn) measured at six stations along the Scheldt estuary in October/November 1978 are compared with more recent data. Based on Ca content in the suspended matter, three distinct geochemical regions could be distinguished: the upper estuary (salinity 1–7) dominated by fluvial mud, mid-estuary (salinity 7–17) where the composition of the suspended matter remained relatively constant, and the lower estuary where marine mud prevailed. Re-suspension of sediments is the major factor controlling the composition of the particles in the upstream region. Anoxic conditions prevailed in the upper part of the estuary extending to a salinity of 15 in 1978, while at present the seaward boundary of the anoxic water body is located at less saline waters. Furthermore, the present-day metal load is much lower than in 1978. As a consequence of the changed situation, maxima in dissolved concentrations of redox-sensitive metals in the mid/lower estuary have moved as well, which affects the trace metal re-distribution pattern. In the anoxic zone, exchange processes between dissolved and particulate metal fractions were strongly redox regulated, with Fe and Mn as excellent examples. Iron was removed from the dissolved phase in the early stages of mixing resulting in an increase in the suspended particulate matter of the leachable ‘non-residual' Fe fraction from 2 to 3.5%. Due to its slower kinetics, removal of Mn from solution occurred in mid-estuary where oxygen concentrations increased. Cu, Cd and Zn on the contrary were mobilised from the suspended particles during estuarine mixing. External inputs of Pb, and to a lesser extent of Cu, in the lower estuary resulted in the increase of their particulate and the dissolved concentrations. Calculated K_d (distribution coefficient) values were used to assess the redistribution between the dissolved and particulate phase of the investigated metals. Due to the existence of the anoxic water body in the upper estuary, the importance of redox processes in determining the K_d values could be demonstrated. The sequence of K_d values in the upper estuary (Fe, Cd, Zn, Pb > Cu > Ni, Mn) is significantly different from that in the lower estuary (Fe > Mn > Pb, Ni, Zn, Cu, Cd). Thus, in such a dynamic estuary single metal-specific K_d values cannot be used to describe redistribution processes.     

High voltage transmission lines and their effect on reindeer: a research programme in progress

We review literature on high voltage transmission lines and their effect on wild reindeer ( Rangifer tarandus ) migration patterns and area use. We conclude that reliable knowledge is lacking on the effects of transmission lines on reindeer ecology. This condition relates to the lack of long-term monitoring of reindeer migration patterns in relation to existing lines. It is also related to the fact that nothing is known about hearing in reindeer (or any other deer species in Norway) in relation to transmission line noise, which is considered an obstacle for migrating reindeer.
We then outline a research programme that includes a laboratory study to determine the audiogram in reindeer and two field studies to examine the proximate effects of transmission lines - independently as well as combined with ambient environmental variables - on reindeer behaviour. The audiogram in two yearling male reindeer has been determined; this part of the study will be completed this year with the determination of a corresponding audiogram in two female yearlings. The behaviour study of domestic reindeer under high voltage transmission lines was completed in September 1999. The behaviour study of wild reindeer in the area crossed by a 420 kV power line will continue this year and its completion is anticipated in 2001.