Miocene to Quaternary basin evolution at the southeastern Andean Plateau (Puna) margin (ca. 24°S lat,Northwestern Argentina)

The Andean Plateau of NW Argentina is a prominent example of a high‐elevation orogenic plateau characterized by internal drainage, arid to hyper‐arid climatic conditions and a compressional basin‐and‐range morphology comprising thick sedimentary basins. However, the development of the plateau as a geomorphic entity is not well understood. Enhanced orographic rainout along the eastern, windward plateau flank causes reduced fluvial run‐off and thus subdued surface‐process rates in the arid hinterland. Despite this, many Puna basins document a complex history of fluvial processes that have transformed the landscape from aggrading basins with coalescing alluvial fans to the formation of multiple fluvial terraces that are now abandoned. Here, we present data from the San Antonio de los Cobres (SAC) area, a sub‐catchment of the Salinas Grandes Basin located on the eastern Puna Plateau bordering the externally drained Eastern Cordillera. Our data include: (a) new radiometric U‐Pb zircon data from intercalated volcanic ash layers and detrital zircons from sedimentary key horizons; (b) sedimentary and geochemical provenance indicators; (c) river profile analysis; and (d) palaeo‐landscape reconstruction to assess aggradation, incision and basin connectivity. Our results suggest that the eastern Puna margin evolved from a structurally controlled intermontane basin during the Middle Miocene, similar to intermontane basins in the Mio‐Pliocene Eastern Cordillera and the broken Andean foreland. Our refined basin stratigraphy implies that sedimentation continued during the Late Mio‐Pliocene and the Quaternary, after which the SAC area was subjected to basin incision and excavation of the sedimentary fill. Because this incision is unrelated to baselevel changes and tectonic processes, and is similar in timing to the onset of basin fill and excavation cycles of intermontane basins in the adjacent Eastern Cordillera, we suspect a regional climatic driver, triggered by the Mid‐Pleistocene Climate Transition, caused the present‐day morphology. Our observations suggest that lateral orogenic growth, aridification of orogenic interiors, and protracted plateau sedimentation are all part of a complex process chain necessary to establish and maintain geomorphic characteristics of orogenic plateaus in tectonically active mountain belts.     

Spatial variations in chemical weathering and CO2 consumption in Nepalese High Himalayan catchments during the monsoon season

The major ion chemistry of the Marsyandi basin and six of its tributaries in the Nepalese Himalaya have been investigated during the monsoon months of 2002. Weekly water samples taken at 10 river monitoring stations in the Annapurna watershed over the course of 4 months provide chemical weathering data for the region at an unprecedented temporal and spatial resolution. The river chemistry of all but one basin is heavily dominated by carbonate weathering which, compared to silicate weathering, contributes 80 to 97% of the total solute load. This prevalence is due to a combination of (a) intrinsically faster dissolution kinetics of carbonates, (b) relatively high runoff and (c) glacial meltwater and low temperatures at high altitudes resulting in enhanced carbonate solubilities. Monitoring stations with headwaters in the Tethyan Sedimentary Series (TSS) are particularly carbonate-rich and slightly supersaturated with respect to calcite through half of the monsoon season. Silicate weathering in the TSS is driven largely by sulfuric acid and therefore does not contribute significantly to the drawdown of atmospheric CO₂. With respect to the tributaries in the Greater Himalayan Sequence (GHS), carbonate weathering is practically as predominant as for the TSS, in spite of the largely felsic lithology of the GHS. Relative to the TSS, the primary proton source in the GHS has shifted, with at least 80% of the protons derived from carbonic acid. Averaged over the whole field area, the CO₂ fluxes, based on silicate-derived Ca and Mg, are considerably lower than the global average. Assuming that this study area is representative of the entire range, we conclude that in situ weathering of the High Himalayas does not represent a significant sink of atmospheric carbon dioxide, despite the presence of a watershed south of the GHS that is characterized by a four times higher CO₂ consumption rate than the global average. Silicate weathering rates of all basins appear to be climate controlled, displaying a tight correlation with runoff and temperature. Given the extremely low chemical weathering under transport-limited conditions in high-altitude crystalline terrains outside of the monsoon season, this would result in virtually no chemical exhumation for 2/3 of the year in such a cold and arid climate, north of the rain shadow cast by the High Himalayas.     

Fossil Hydrophilid Beetles (Coleoptera: Hydrophilidae) of the Late Oligocene Rott Formation (Germany)

<正>Fossil water scavenger beetles(Coleoptera:Hydrophilidae)of the latest Oligocene Rott Formation are revised,based on the examination of the type specimens,as well as numerous additional material from Statz(Los Angeles)and Kastenholz(Bonn)collections.Seven hydrophilid species are recognized,five of which are reliably attributed to the following genera:Berosus morticinus(von Heyden and von Heyden,1866),Paracymus excitatus (von Heyden and von Heyden,1866),Paracymus sp.,Hydrobiomorpha fraterna(von Heyden,1859),and Hydrophilus rottensis(Statz,1939).Coccinella? protogaeae Germar 1837 is attributed to the subtribe Hydrophilina, and Cymbiodyta? austera Statz 1939 to the subfamily Hydrophilinae.Hydrous ebeninus Statz 1939 and Paracymus excitatus(form 3)are excluded from the Hydrophiloidea.Berosus capitatus Statz 1939 is synonymized with Berosus morticinus,and Hydrous neptunus von Heyden and von Heyden 1866 with Hydrobiomorpha fraterna.Lectotypes of Philydrus morticinus von Heyden and von Heyden 1866 and Hydrous ebeninus Statz 1939 are designated.The significance of the hydrophilid fossils for paleoecological reconstructions of the former Rott Lake is briefly discussed.     

Winter and summer characterization of biogenic enantiomeric monoterpenes and anthropogenic BTEX compounds at a Mediterranean Stone Pine forest site

Measurements of biogenic gases including enantiomeric monoterpenes and isoprene, and anthropogenic gases such as benzene, toluene, ethylbenzene, ortho-, meta- and para- xylene (BTEX) compounds were made by GC-MS in November and December 2008 within a stone pine (Pinus pinea L) forest located on the Southwest coast of Spain (37.10°N, 6.70°W). Mixing ratios of the biogenic species were found to be low (mean circa 10 pptv) consistent with previously observed low wintertime regional forest emission rates. In contrast, anthropogenic species were significantly higher (mean 10–156 pptv), the dominant emissions originating from the city of Huelva and associated petrochemical activities, located 25 km north west of the measurement site. In wintertime the monoterpene (?)-α-pinene was found to be in slight enantiomeric excess over (+)-α-pinene at night but by day the measured ratio was closer to one i.e. racemic. Samples taken the following summer in the same location showed much higher monoterpene mixing ratios and revealed a strong enantiomeric excess of (?)-α-pinene. This indicates a strong seasonal variance in the enantiomeric emission ratio which is not manifested in the day/night temperature cycles in wintertime. Mixing ratios of the xylene isomers (meta- and para-) and ethylbenzene, which are all well resolved on the beta-cyclodextrin column, were exploited to estimate average OH radical exposures to VOCs from the Huelva industrial area. These were compared to empirical estimates of OH based on JNO₂ measured at the site. The deficiencies of each estimation method are discussed.     

Review and revision of Cenozoic tropical planktonic foraminiferal biostratigraphy and calibration to the geomagnetic polarity and astronomical time scale

Planktonic foraminifera are widely utilized for the biostratigraphy of Cretaceous and Cenozoic marine sediments and are a fundamental component of Cenozoic chronostratigraphy. The recent enhancements in deep sea drilling recovery, multiple coring and high resolution sampling both offshore and onshore, has improved the planktonic foraminiferal calibrations to magnetostratigraphy and/or modified species ranges. This accumulated new information has allowed many of the planktonic foraminiferal bioevents of the Cenozoic to be revised and the planktonic foraminiferal calibrations to be reassessed. We incorporate these developments and amendments into the existing biostratigraphic zonal scheme.In this paper we present an amended low-latitude (tropical and subtropical) Cenozoic planktonic foraminiferal zonation. We compile 187 revised calibrations of planktonic foraminiferal bioevents from multiple sources for the Cenozoic and have incorporated these recalibrations into a revised Cenozoic planktonic foraminiferal biochronology. We review and synthesize these calibrations to both the geomagnetic polarity time scale (GPTS) of the Cenozoic and astronomical time scale (ATS) of the Neogene and late Paleogene. On the whole, these recalibrations are consistent with the previous work; however, in some cases, they have led to major adjustments to the duration of biochrons. Recalibrations of the early–middle Eocene first appearance datums of Globigerinatheka kugleri, Hantkenina singanoae, Guembelitrioides nuttalli and Turborotalia frontosa have resulted in large changes in the durations of Biochrons E7, E8 and E9. We have introduced (upper Oligocene) Zone O7 utilizing the biostratigraphic utility of ‘Paragloborotalia’ pseudokugleri. For the Neogene Period, major revisions are applied to the fohsellid lineage of the middle Miocene and we have modified the criteria for recognition of Zones M7, M8 and M9, with additional adjustments regarding the Globigerinatella lineage to Zones M2 and M3. The revised and recalibrated datums provide a major advance in biochronologic resolution and a template for future progress of the Cenozoic time scale.     

On the added value of regional climate modeling in climate change assessment

Regional climate models represent a promising tool to assess the regional dimension of future climate change and are widely used in climate impact research. While the added value of regional climate models has been highlighted with respect to a better representation of land-surface interactions and atmospheric processes, it is still unclear whether radiative heating implies predictability down to the typical scale of a regional climate model. As a quantitative assessment, we apply an optimal statistical filter to compare the coherence between observed and simulated patterns of Mediterranean climate change from a global and a regional climate model. It is found that the regional climate model has indeed an added value in the detection of regional climate change, contrary to former assumptions. The optimal filter may also serve as a weighting factor in multi-model averaging.     

Temporal and azimuthal dependence of sound propagation in shallowwater with internal waves

The short time scale (minutes) and azimuthal dependence of sound wave propagation in shallow water regions due to internal waves is examined. Results from the shallow water acoustics in random media (SWARM-95) experiment are presented that reflect these dependencies. Time-dependent internal waves are modeled using the dnoidal solution to the nonlinear internal wave equations, so that the effects of both temporal and spatial variability can be assessed. A full wave parabolic equation model is used to simulate broadband acoustic propagation. It is shown that the short term temporal variability and the azimuthal dependence of the sound field are strongly correlated to the internal wave field     

Microbially induced cementation of carbonate sands: are micritic meniscus cements good indicators of vadose diagenesis?

Characteristic fabrics such as micrite envelopes, calcified filaments and micritic grain-to-grain bridges are observed in a modern subtidal firmground (Wood Cay, Bahamas) and in a variety of firm- and hardgrounds of Lower Cretaceous and Upper Jurassic platform carbonates (Swiss and French Jura Mountains). Their similarity to microbial fabrics described in grapestones and in intertidal to continental vadose environments suggests that microbial activity played an important role in the initial stabilization and cementation of carbonate sands. 'Meniscus-type cements' (to distinguish them from vadose meniscus cements), which clearly formed in subtidal environments, are related to filament calcification, trapping of percolating micrite and microbially induced carbonate formation. Such meniscus-type cements are commonly micritic, but meniscus-shaped precipitation of fibrous aragonite or sparitic calcite around organic filaments is also observed. Therefore, an interpretation of vadose early diagenesis should not be based on meniscus cements alone. Similarly, subtidally formed filamentous structures can strongly resemble alveolar septal structures and be interpreted incorrectly as related to subaerial exposure.