X-ray absorption studies of CH3Hg-binding sites in humic substances

Methylmercury cation (CH₃Hg⁺) is known to have a strong affinity for organic matter in soil, sedimentary, and aquatic environments. The objective of this study is to determine the dominant ligands binding CH₃Hg⁺ in humic acids by evaluating several CH₃Hg⁺-ligand complexation models, using mercury L_III-edge extended X-ray absorption fine structure (EXAFS). The model CH₃Hg⁺ binding ligands examined in this study include thiol (-SH), hydrogen polysulfide (-SSH or -SSSH), sulfide (-S-), disulfide (-SS-), carboxyl (-COOH), and amine (-NH₂). Based on the atomic geometry around mercury in each model structure, we distinguished CH₃Hg⁺-binding ligands in two different humic acids (soil and aquatic). We observed CH₃Hg⁺ preferentially binds to thiol ligands. After saturating reactive thiol ligands, the majority of CH₃Hg⁺ binds to carboxyl ligands rather than to amine or other reduced sulfur ligands than thiol. We found no evidence of significant CH₃Hg⁺-sulfide/disulfide or CH₃Hg⁺-hydrogen polysulfide complexes in any samples. When CH₃Hg⁺ binds to a humic ligand, the C-Hg bond in CH₃Hg⁺ remains intact. Some heavy atoms are proximately coordinated around the mercury atom in the sample containing the highest CH₃Hg⁺ levels used in this study.     

Thermodynamic calculations on sulfide flotation systems, II. Comparisons with electrochemical experiments on the galena-ethyl xanthate system

Extensive thermodynamic calculations have been carried out to study the oxidation of galena and its flotation by potassium ethyl xanthate (KEX). In order to include some kinetic effects, three cases have been considered by assuming that sulfur oxidation can proceed as far as the formation of sulfate, thiosulfate and elemental sulfur.The results of these calculations have been compared with those of linear sweep voltammetry and intermittent galvanostatic polarization experiments conducted on galena at pH 9.2. Analysis of the experimental data indicates that in xanthate-free solutions, galena is oxidized primarily to PbO and S⁰ and, to a lesser extent, S₂O₃²⁻, rather than to the thermodynamically most favored PbOH⁺ and SO₄²⁻. Tests carried out in the presence of collector confirm the previous finding (Woods, 1971) that the interaction of xanthate with the mineral begins with chemisorption by a one-electron reaction. This cannot, of course, be predicted by calculations based on bulk thermodynamics.     

Automation of a laboratory flotation machine for improved performance

A commercial laboratory flotation machine (Denver Model D-12) has been automated for ease of operation and reproducibility. The major features of the system include two plexiglass cells of 4- and 2-1 capacity which are interchangeable for rougher and cleaner flotation, respectively, an electronic level controller and an air-flow rate controller. The level controller can be used for either pulp-level or froth-level control by adjusting the threshold setting. Two mechanical paddles on the sides of each flotation cell can be controlled to adjust the rate of froth removal. Test results demonstrate the reproducibility of the data obtained with the equipment.     

Study on laterally loaded piles with rectangular and circular cross sections

The conventional approach in the design of laterally loaded piles with rectangular cross section involves the simplification of converting the rectangular cross section of the pile to an equivalent circular cross section. An analysis to determine the response of laterally loaded rectangular or circular piles in elastic soil is presented in which this simplification is not required. The analysis is based on the solution of differential equations governing the displacements of the pile–soil system derived using energy principles. The pile geometry and the elastic constants of the soil and pile are the input parameters to the analysis. Using this analysis, comparisons are made between the response of rectangular and circular piles in elastic soil. Based on the proposed solution scheme, a user-friendly spreadsheet program (LATPAXL) was developed that can be used to perform the analysis. In addition, simple equations obtained by regression analysis of the pile head deflection and bending moment profiles are proposed. Examples illustrate the use of the analysis.     

Holocene paleoclimate changes determined using diatom assemblages from Lake Long,King George Island,Antarctica

Formation of Lake Long, King George Island, Antarctica started about 4,000 years B.P., after which the diatom community changed in response to environmental shifts driven by climatic oscillations (warm/wet and cool/dry). Successive sequences of diatoms in a 7.5-m drill core were divided into 11 assemblage zones by cluster analysis. The most obvious change was an alternation of major dominants, Achnanthes minutissima, Fragilaria alpestris and Fragilaria pinnata v. antarctica according to the climatic oscillations in the late Holocene. Variations in diatom assemblages clearly reflect two warm periods, a single cool period, and three transition periods. The recent warm period (zones 2 and 1) has persisted for approximately 450 years, perhaps sufficiently long to suggest the imminent onset of a new transition period. A recent high TOC (total organic carbon) value in the core reflects a warm period in Antarctica during the late Holocene.     

Sedimentological, geochemical and palaeontological evidence for a neoglacial cold event during the late Holocene in the continental shelf of the northern South Shetland Islands, West Antarctica

Two sediment cores obtained from the continental shelf of the northern South Shetland Islands, West Antarctica, consist of: an upper unit of silty mud, bioturbated by a sluggish current, and a lower unit of well-sorted, laminated silty mud, attributed to an intensified Polar Slope Current. Geochemical and accelerator mass spectrometry ¹⁴C analyses yielded evidence for a late Holocene increase in sea-ice extent and a decrease in phytoplankton productivity, inferred from a reduction in the total organic carbon content and higher C : N ratios, at approximately 330 years B.P., corresponding to the Little Ice Age. Prior to this, the shelf experienced warmer marine conditions, with greater phytoplankton productivity, inferred from a higher organic carbon content and C : N ratios in the lower unit. The reduced abundance of Weddell Sea ice-edge bloom species ( Chaetoceros resting spores, Fragilariopsis curta and Fragilariopsis cylindrus ) and stratified cold-water species ( Rhizosolenia antennata ) in the upper unit was largely caused by the colder climate. During the cold period, the glacial restriction between the Weddell Sea and the shelf of the northern South Shetland Islands apparently hindered the influx of ice-edge bloom species from the Weddell Sea into the core site. The relative increases in the abundance of Actinocyclus actinochilus and Navicula glaciei , indigenous to the coastal zone of the South Shetland Islands, probably reflects a reduction in the dilution of native species, resulting from the diminished influx of the ice-edge species from the Weddell Sea. We also document the recent reduction of sea-ice cover in the study area in response to recent warming along the Antarctic Peninsula.     

Groundwater Impacts from the M5.8 Earthquake in Korea as Determined by Integrated Monitoring Systems

This paper describes the impacts of the M5.8(5.1) Gyeongju earthquakes on groundwater levels using data obtained from a unique coastal monitoring well. The monitoring strategy integrates conventional water level monitoring with periodic, continuous measurements of temperature and electrical conductivity (EC) within the water column of the well. Another important component of the monitoring system is a new instrument, the InterfacEGG, which is capable of dynamically tracking the freshwater-saltwater interface. Although the system was set up to monitor seawater intrusion related to over-pumping, as well as rainfall and tidal effects, it recorded impacts associated with a large earthquake and aftershocks approximately 241 km away. Seismic energies associated with the M5.8(5.1) Gyeongju earthquakes induced groundwater flows to the monitoring well through fractures and joints in the crystalline basement rocks. Temperature and EC logging data showed that the EC vertical profile declined from an average of approximately 5300 to 4800 μS/cm following the earthquakes. The temperature profile showed a trend toward lower temperatures as the depth increased, a feature not commonly observed in previous studies. Data from the InterfacEGG suggested that the rise in EC was not due to the saltwater intrusion, but from the tendency for brackish water entering the borehole to induce convective mixing at deeper depths as the seismic waves travel through the well-aquifer system. The increase in groundwater levels was caused by pulse of colder, less brackish water flowing into the well because of the earthquake. This behavior reflects an enhancement in rock permeability by removing precipitates and colloidal particles from clogged fractures, which improve the hydraulic connection with a nearby unit with a higher hydraulic head. This study suggests there is value added with a more aggressive monitoring strategy.     

Softening effects of RC nonstructural flat walls on ductile concrete buildings

Nonstructural reinforced concrete flat walls architecturally designed as exterior/partition walls in concrete buildings were severely damaged by the 2011 earthquake off the Pacific coast of Tohoku. This damage was observed in the monolithic nonstructural flat walls of relatively old ductile concrete buildings. Although these flat walls might affect the overall seismic performance and behavior of a building, the nonstructural wall effects have not been clarified because of the complex interactions among the structural components. To understand these effects, this paper conducts an experimental and numerical investigation of the nonstructural wall effects, focusing on a typical residential building damaged by the 2011 earthquake. A single‐story, one‐bay moment‐resisting frame model of the building with a nonstructural flat wall was tested to clarify the fundamental behavior. The results reveal that the wall significantly contributed to the seismic performance of the overall frame until it failed in shear, subsequently losing structural effectiveness. Such experimental wall behavior could be simulated by the isoparametric element model. Moreover, the structural effects of the nonstructural flat walls on the global seismic performance and behavior of the investigated building were discussed through earthquake response analyses using ground motions recorded near the building site and pushover analyses. Consequently, the building damage could be simulated in an analytical case considering the nonstructural flat walls, showing larger inter‐story drifts in the lower stories due to softening of the walls. The analytical results also indicated that the softening of the nonstructural flat walls decreased the building ductility, as defined by ultimate inter‐story drifts. Copyright © 2017 John Wiley & Sons, Ltd.     

Polyp Removal of a Bloom Forming Jellyfish, <Emphasis Type="Italic">Aurelia coerulea</Emphasis>, in Korean Waters and Its Value Evaluation

Aurelia coerulea is a bloom forming jellyfish that first appeared before 1980 in the western and southern Korean seas and which has been blamed for huge economical losses in all fields of marine activities. As a preventive measure to reduce economical losses, polyp removal was undertaken at Lake Shihwa, Lake Saemangeum, and Masan Bay, Korea. In the course of efforts during 2 years to remove polyps, polyps were surveyed, quantified, and removed. In these areas, the initial total polyp abundance was 5.04 × 10⁹ and 46.25% of them were removed; Lake Shihwa the highest rates of removal and Lake Saemangeum the lowest. These efforts to remove polyps prevented the appearance of 1.20 × 10⁹ medusae, corresponding to 78.28 × 10⁶ kg. The cost of polyp removal was evaluated and compared with that of medusae removal. The ratio between the cost of polyp removal and that of medusae removal ranged between 0.78–3.14%, indicating large cost savings for polyp removal undertakings. However, the effect of polyp removal varied from positive to none, and we assumed that the cleared surface for polyp removal, quantity of removed polyp, and existence of polyps’ hotspots in neighboring areas were the causes of the non-effectiveness of polyp removal undertakings.