Water quality assessment at Jinhae Bay and Gwangyang Bay,South Korea

A new water quality index for evaluating the water quality of Jinhae Bay and Gwangyang Bay was developed. Four water quality parameters were selected as water quality indicators for the water quality index: dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorus (DIP), chlorophyll-a (Chl-a), and dissolved oxygen (DO). Reference levels of DIN, DIP, and Chl-a were determined as 6.22 μmol L^?1, 0.38 μmol L^?1, and 2.32 μmol L^?1, respectively, on the basis of a long-term dataset that was collected monthly in the Korea Strait over a period of seven years (2006–2012). The water quality index established for Jinhae Bay and Gwangyang Bay is (bottom DO grade × 0.33) + (surface Chl-a grade × 0.33) + (surface DIN grade × 0.17) + (surface DIP grade × 0.17). On the basis of a three-year observation, the water quality of Jinhae Bay was classified as “good” in winter and spring, “poor” in summer, and “fair” in autumn and exhibited large spatial variation, with the lowest-quality water observed in Masan Bay. The water quality of Gwangyang Bay was classified as “good” in winter, “fair” in spring, “poor” in summer, and “fair” in autumn. Unlike Jinhae Bay, the water quality of Gwangyang Bay exhibited minimal spatial variation. In both bays, water quality among the four seasons was worse during summer. It is essential that a survey for water quality evaluation be conducted during summer.     

High-resolution numerical simulation of the Pacific Ocean

The present study developed Pacific Ocean models from the Research Institute for Applied Mechanics Ocean Model (RIAMOM) with very high horizontal (1/6° and 1/12°) and vertical (70 levels) resolutions. The hydrographic features of the simulations show good agreement with observed climatological features. Solution differences between the 1/6° and 1/12° models are small for general features of various physical components, but large for eddy fields and the strengths of western boundary currents and their extensions. However, the two high-resolution models show realistic climatological features of Pacific Ocean circulation patterns. Volume transports through major straits in the northwestern Pacific Ocean were also simulated and compared with previous observational results.     

New insights into the crustal structure of the North German Basin from reprocessing of seismic reflection data using the Common Reflection Surface stack

The influence of deep crustal processes on basin formation and evolution and its relation to current morphology is not well understood yet. A key feature to unravel these issues is a detailed seismic image of the crust. A part of the data recorded by the hydrocarbon industry in the late 1970s and 1980s in the North German Basin were released to the public recently. The seismic reflection data were recorded down to 15 s two-way travel time. The mean Common Midpoint fold of about 20 is relatively low compared to contemporary seismic acquisitions. The processing of the 1980s focussed on the sedimentary structures to explore the hydrocarbon potential of this area. We applied the Common Reflection Surface stack technique to the data sets, which is well suited for low-fold data. The reprocessing was focussed on the imaging of the subsedimentary crustal range. The reprocessed images show enhanced reflections, especially in the mid and lower crustal part. Also, the image of the salt structures in the graben area was improved. Furthermore, the reprocessed images indicate an almost flat Moho topography in the area of the Glückstadt Graben and an additional lower crustal structure, which can be correlated with a high-density body found in recent gravity modeling studies.     

Detection of mean-field bias of the radar rain rate using rain gauges available within a small portion of radar umbrella: a case study of the Donghae (East Sea) radar in Korea

Observation of a storm approaching from the ocean to the in-land area is very important for the flood forecasting. Radar is generally used for this purpose. However, as rain gauges are mostly located within the in-land area, detection of the mean-field bias of radar rain rate cannot be easily made. This problem is obviously different from that with evenly-spaced rain gauges over the radar umbrella. This study investigated the detection problem of mean-field bias of radar rain rate when rain gauges are available within a small portion of radar umbrella. To exactly determine the mean-field bias, i.e. the difference between the radar rain rate and the rain gauge rain rate, the variance of the difference between two observations must be small; thus, a sufficient number of observations are indispensable. Therefore, the problem becomes determining the number of rain gauges that will satisfy the given accuracy, that being the variance of the difference between two observations. The dimensionless error variance derived by dividing the expected value of the error variance by the variance of the areal average rain rate was introduced as a criteria to effectively detect the mean field bias. Here, the variance of the areal average rain rate was assumed to be the climatological one and the expectation for the error variance could be changed depending one the sampling characteristics. As an example, this study evaluated the rainfall observation over the East Sea by the Donghae radar. About 6.8 % of the entire radar umbrella covered in-land areas, where the rain gauges were available. It was found that, to limit the dimensionless error variance to 2 %, a total of 26 rain gauges are required for the entire radar umbrella; whereas, a total of 24 rain gauges would be required within the in-land area with available for the rain gauge data.     

Seasonal characteristics of the Tsushima Current in the Tsushima/Korea Strait obtained by a fine-resolution numerical model

The horizontal distribution of the Tsushima Current in the Tsushima/Korea Strait is assessed by a fine-resolution numerical experiment. The comparison of the model results with the observations along a section crossing the strait shows that the model represents relatively well, the general tendency of what was observed, such as the separation of the Tsushima Current into the western and eastern streams by the Tsushima Island. In summer, strong and relatively uniformly distributed surface currents enhance the formation of the wake downstream of the Tsushima Island. The axis of the countercurrent, embedded in the wake, is closer to the western stream. Anti-cyclonic eddies are shed near the downstream tip of the Tsushima Island and propagate along the boundary between the western stream and the wake. The exchange of water between the western stream and the wake takes place through the intermediation of these eddies. There is a net water supply from the western stream to the wake, which is then carried to the eastern stream by the countercurrent via the eastern coast of the Tsushima Island. In winter, currents, strongly barotropic, tend to have banded structures, especially in the region downstream of the western channel where isobaths converge in the downstream direction. The eddies found in this region in winter appear to be fundamentally different from those associated with the Tsushima Island wake. The necessary condition for barotropic instability is satisfied for the monthly mean currents in this region, suggesting that the currents are barotropically unstable in this region in winter.     

An estimation of discharge using mean velocity derived through Chiu’s velocity equation

To estimate discharge through the year (dry season and flood season), a stage–discharge curve derived through monitoring discharge in about 20 rivers or channels every year has been generally used. As revealed in many studies, however, the stage–discharge curve is inevitably affected by their hydraulic characteristics. This suggests that the use of a stage–discharge curve derived without considering hydraulic characteristics unique to a river or channel may produce significant errors in estimating discharge at not only low stage (during dry seasons) but also high stage (during flood seasons). In this study, the authors proposed a method to calculate the mean velocity and to estimate the discharge considering the hydraulic characteristics of a river or channel (e.g. the bed slope, wetted perimeter, width, kinematic viscosity, etc.); the method was developed using Chiu’s velocity equation. With the proposed method, it is possible to calculate a maximum velocity that is difficult to measure in an open channel, derive an entropy function representing the equilibrium of the channel, and thereby, estimate reliable discharge even in a flood season. To comparatively verify the utility of the proposed method, relations between the results of analysis using Manning’s and Chezy’s mean velocity equations and the values of measured discharge were addressed together. The results of analysis using lab data sets and measured data sets revealed that the proposed method was significantly more accurate in estimating discharge, even in flood seasons, when compared with the conventional method.     

Adsorption of organic matter at mineral/water interfaces: I. ATR-FTIR spectroscopic and quantum chemical study of oxalate adsorbed at boehmite/water and corundum/water interfaces

The types and structures of adsorption complexes formed by oxalate at boehmite (γ-AlOOH)/water and corundum (α-Al₂O₃)/water interfaces were determined using in situ attenuated total reflectance fourier transform infrared (ATR-FTIR) spectroscopy and quantum chemical simulation methods. At pH 5.1, at least four different oxalate species were found at or near the boehmite/water interface for oxalate surface coverages (Γ_ox) ranging from 0.25 to 16.44 μmol/m². At relatively low coverages (Γ_ox < 2.47), strongly adsorbed inner-sphere oxalate species (IR peaks at 1286, 1418, 1700, and 1720 cm⁻¹) replace weakly adsorbed carbonate species, and a small proportion of oxalate anions are adsorbed in an outer-sphere mode (IR peaks at 1314 and 1591 cm⁻¹). IR peaks indicative of inner-sphere adsorbed oxalate are also observed for oxalate at the corundum/water interface at Γ_ox = 1.4 μmol/m². With increasing oxalate concentration (Γ_ox > 2.47 μmol/m²), the boehmite surface binding sites for inner-sphere adsorbed oxalate become saturated, and excess oxalate ions are present dominantly as aqueous species (IR peaks at 1309 and 1571 cm⁻¹). In addition to these adsorption processes, oxalate-promoted dissolution of boehmite following inner-sphere oxalate adsorption becomes increasingly pronounced with increasing Γ_ox and results in an aqueous Al(III)-oxalate species, as indicated by shifted IR peaks (1286 → 1297 cm⁻¹ and 1418 → 1408 cm⁻¹). At pH 2.5, no outer-sphere adsorbed oxalate or aqueous oxalate species were observed. The similarity of adsorbed oxalate spectral features at pH 2.5 and 5.1 implies that the adsorption mechanism of aqueous HOx⁻ species involves loss of protons from this species during the ligand-exchange reaction. As a consequence, adsorbed inner-sphere oxalate and aqueous Al(III)-oxalate complexes formed at pH 2.5 have coordination geometries very similar to those formed at pH 5.1.The coordination geometry of inner-sphere adsorbed oxalate species was also predicted using quantum chemical geometry optimization and IR vibrational frequency calculations. Geometry-optimized Al₈O₁₂ and Al₁₄O₂₂ clusters with the reactive surface Al site coordinated by three oxygens were used as model substrates for corundum and boehmite surfaces. Among the models considered, calculated IR frequencies based on a bidentate side-on structure with a 5-membered ring agree best with the observed frequencies for boehmite/oxalate/water samples at Γ_ox = 0.25 to 16.44 μmol/m² and pH 2.5 and 5.1, and for a corundum/oxalate/water sample at Γ_ox = 1.4 μmol/m² and pH 5.1. Based on these results, we suggest that oxalate bonding on boehmite and corundum surfaces results in 5-coordinated rather than 4- or 6-coordinated Al surface sites.     

Behavior of warm water flowing into a cold ocean

Behavior of warm water flowing into a model ocean with flat bottom filled with cold water is investigated numerically with a three-dimensional level model in a rotating system.The warm water which flows through the southern opening into the ocean is found to progress in two directions. The east front of the warm water progresses along the east coast and reaches the northern opening. And an eastern boundary current associated with this density structure is formed. The west front progresses along the west coast with the speed much less than that of the eastside front. However, the progression of the west front slows down remarkably half way between the southern and northern boundaries due to-effect, and a baroclinic western boundary current system is formed. Unstable waves whose scales are 200–400 km are found in the region of the eastern boundary current and propagate toward the west. These waves seem to be caused by the baroclinic instability.The boundary currents obtained in the present model are considered to represent some characteristics of the Tsushima Current system in the Japan Sea.     

Family strategies in a neoliberal world: Korean immigrants in Winnipeg

South Korean immigration to Canada has increased since the East Asian economic crisis of the late 1990s. Korean immigrants in Winnipeg chose the city for many reasons: the introduction of the Provincial Nominee Program, structural changes in the home country, and individual family strategies to provide better educational opportunities for their children. This article examines how changes in the current wave of globalization, at both global and local scale, have affected the migration of Koreans to Winnipeg, Canada and how individual households chose their immigration destination. This study contributes to understanding of the less popular immigrant destinations of Canada using a multiscalar analysis that includes household level. In addition to economic purposes and children’s education, changes of life style can be an important reason for immigrant location choice. Overall, the neoliberal economy in South Korea has pushed many Koreans to move to other countries, and the globalization of the Canadian economy has pulled nomadic middle-class members from other countries.     

Above-ground biomass estimation of tuberous bulrush (<Emphasis Type="Italic">Bolboschoenus planiculmis</Emphasis>) in mudflats using remotely sensed multispectral image

We present a multivariate regression approach for mapping the spatial distribution of above-ground biomass (AGB) of B. planiculmis using field data and coincident moderate spatial resolution satellite imagery. A total of 232 ground sample plots were used to estimate the biomass distribution in the Nakdong River estuary. Field data were overlain and correlated with digital values from an atmospherically corrected multispectral image (Landsat 8). The AGB distribution was derived using empirical models trained with field-measured AGB data. The final regression model for AGB estimation was composed using the OLI3, OLI4, and OLI7 spectral bands. The Pearson correlation between the observed and predicted biomass was significant (R = 0.84, p < 0.0001). OLI3 made the largest contribution to the final model (relative coefficient value: 53.4%) and revealed a negative relationship with the AGB biomass. The total distribution area of B. planiculmis was 1,922,979 m². Based on the model estimation, the total AGB had a dry weight (DW) of approximately 298.2 tons. The distribution of high biomass stands (> 200 kg DW/900 m²) constituted approximately 23.91% of the total vegetated area. Our findings suggest the expandability of remotely sensed products to understand the distribution pattern of estuarine plant productivity at the landscape level.