A re-evaluation of the olivine-spinel geothermometer

The Irvine olivine-spinel geothermometer, as formulated by Jackson (1969), appears to yield magmatic temperatures when applied to plutonic rocks such as the Stillwater Complex but Evans and Wright (1972) have demonstrated that it gives temperatures in excess of 2,000 ° C when applied to volcanic assemblages. A re-evaluation of the geothermometer has shown that more realistic temperatures can be obtained for volcanic rocks by using a different free energy value of FeCr₂O₄ in the formulation. The revised geothermometer gives temperatures in the range 1,100–1,300 ° C for samples from Kilauea and 500–800 ° C for basic plutonic rocks from layered intrusions, indicating that Mg and Fe²⁺ have re-equilibrated at subsolidus temperatures in these intrusions as suggested by Irvine (1965). This theory was tested by heating uncrushed natural samples from layered intrusions to magmatic temperatures for periods ranging from two days to four weeks. The result was a marked increase in the Mg/Fe²⁺ ratio in the spinels and a decrease in the Mg/Fe²⁺ ratio in the olivines, confirming that considerable subsolidus re-equilibration had taken place in the unheated samples.     

At home and abroad with cine enthusiasts: Regional amateur filmmaking and visualizing the Mediterranean, ca. 1928–1962.

After the appearance of a portable Kodak cine camera in 1923, home moving making grew steadily in popularity in the years leading up to and following World War II. Cine enthusiasts, particularly in the pre-war period, tended to be male, white and middle class, although exceptions exist, and they tended to travel with their cameras much as earlier generations had documented their experiences in written and artistic form. Despite their amateur status, they were often very professional in their approach to cinematography and they produced material for a range of domestic and public audiences on varied topics and in different genres. Specialist publications and the rapid growth of local amateur film societies fostered the rise of an active non-professional film movement; the result is a highly distinctive although neglected component of film history. With reference to materials held at the North West Film Archives in Manchester, England, this discussion considers the rise of non-professional filmmaking at the regional level during the decades before and after the second world war. Making and showing home movies is placed within various socio-cultural contexts. The imagery discloses much about visual practice, including filmmakers' perceptions and their relationships with different kinds of subject matter. The making of holiday footage, in Mediterranean settings, and its subsequent screening in domestic or public places, connects with broader issues of visualization, social practice and leisure-related consumption. This revised version was published online in August 2006 with corrections to the Cover Date.     

Tidally phased emergence events in a strongly tidal estuary

Acoustic backscatter from an active sonar system over a range of six frequencies between 265 kHz and 3 MHz in the tidally dominated Damariscotta River estuary, Maine, United States, revealed that the major emergence event of the night commenced on the first tidal deceleration after dark (3.5–4 h after local slack), irrespective of flow direction. Emergence traps identified the mysid shrimp,Neomysis americana, as the dominant migrator. Water-column-integrated, acoustically estimated biovolume at our 10-m deep study location increased by a factor of about 6 during these large events, entirely dominating the holoplanktonic contribution and likely being a major component in benthic-pelagic coupling. Application of the same algorithm used to locate this nighttime emergence revealed a parallel but considerably smaller daytime emergence event near the same phase of the tide. Daytime trap samples failed to recover the organisms responsible, but transmissometry rejected the alternative hypothesis that we observed resuspension events. We suspect, but have yet only weak evidence, that animals emerging in daylight are copepods rather than mysids.     

Effect of artificial maturation on carbazole distributions, as revealed by the hydrous pyrolysis of an organic-sulphur-rich source rock (Ghareb Formation, Jordan)

Hydrous pyrolysis experiments were performed on the Ghareb Formation (Upper Cretaceous, Jordan), a carbonate- and organic-rich (TOC 19.6%) source rock, using a temperature range of 200 to 360°C (72 h). The original sediment contains only low amounts of carbazoles, (maximum 2.2 μg/g bitumen for 1-methylcarbazole). With increasing thermal maturation, intense generation begins at temperatures only in excess of 300°C, reaching a maximum at 360°C. Likewise, during natural maturation, generation occurs at later stages of maturity (e.g. for Tithonian source rocks at >0.81% R_r and for Posidonia Shale at >0.88% R_r). Some isomeric changes during hydrous pyrolysis do not resemble those in nature whereas others do. The relative abundances of selected C₁- and C₂-alkylcarbazoles on ternary diagrams reveal differences, whereas the benzo[a]carbazole/benzo[a]carbazole+benzo[c]carbazole ratio is closely similar. The latter result supports the contention that maturation plays a key role in controlling carbazole distributions in source rocks. However, the results for alkylcarbazoles, especially the C₂-carbazoles, are not easy to interpret.     

Stable isotope indicators of movement and residency for brown shrimp (<Emphasis Type="Italic">Farfantepenaeus aztecus</Emphasis>) in coastal Louisiana marshscapes

Brown shrimp (Farfantepenaeus aztecus) are an important commercial aquatic species experiencing loss of inshore marsh nursery habitat in coastal Louisiana. To study inshore brown shrimp movements and identify aspects of essential habitat important for sustaining brown shrimp populations, we collected juvenile brown shrimp in April and May 2000, the time of annual maximum brown shrimp abundance, in a small 1-km² marsh area on the central Louisiana coast. Drop sampling showed average shrimp densities of 1.6–2.4 m⁻² in shallow marsh ponds and seining indicated lower densities of 0.5–0.9 m⁻² in nearby shallow channel and open bay sites. Smaller shrimp (< 50 mm) fed disproportionately on benthic diatoms and small harpacticoid copepods, while large shrimp fed more frequently on larger-bodied amphipods and tanaids. We developed novel chemical approaches to estimate patterns of shrimp residency and movement using carbon and nitrogen stable isotopic determinations. Resident shrimp had isotopic values similar to average foods and showed consistent isotopic spacings between fast and slow turnover tissues. Residency was highest (47–55%) in ponds and shallow channel habitats and much less in open bays and deep channels (4–27%). There was sparse evidence for dietary specialization among individull shrimp. The results support the view that small 10–20 mm postlarval and juvenile brown shrimp arriving in estuaries from offshore waters continue movement through sub-optimal habitats (deep channels and open bays), but exhibit much less movement once an optimal habitat (marsh ponds or shallow channel margins) is reached. This study also indicated that combining estimates of shrimp densities, residency, growth rate, and mortality allows evaluation of the importance of different habitat types for shrimp production. Shallow ponds that in many ways resemble fertile aquaculture ponds appear to be hot spots for brown shrimp production, and coastal preservation and restoration efforts should focus on these areas as important for sustaining shrimp fisheries.     

Simulating a century of soil erosion for agricultural catchment management

Agricultural land management requires strategies to reduce impacts on soil and water resources while maintaining food production. Models that capture the effects of agricultural and conservation practices on soil erosion and sediment delivery can help to address this challenge. Historic records of climatic variability and agricultural change over the last century also offer valuable information for establishing extended baselines against which to evaluate management scenarios. Here, we present an approach that combines centennial‐scale reconstructions of climate and agricultural land cover with modelling across four lake catchments in the UK where radiometric dating provides a record of lake sedimentation. We compare simulations using MMF‐TWI, a catchment‐scale model developed for humid agricultural landscapes that incorporates representation of seasonal variability in vegetation cover, soil water balance, runoff and sediment contributing areas. MMF‐TWI produced mean annual sediment exports within 9–20% of sediment core‐based records without calibration and using guide parameter values to represent vegetation cover. Simulations of land management scenarios compare upland afforestation and lowland field‐scale conservation measures to reconstructed historic baselines. Oak woodland versus conifer afforestation showed similar reductions in mean annual surface runoff (8–16%) compared to current moorland vegetation but a larger reduction in sediment exports (26–46 versus 4–30%). Riparian woodland buffers reduced upland sediment yields by 15–41%, depending on understorey cover levels, but had only minor effect on surface runoff. Planting of winter cover crops in the lowland arable catchment halved historic sediment exports. Permanent grass margins applied to sets of arable fields across 15% or more of the catchment led to further significant reduction in exports. Our findings show the potential for reducing sediment delivery at the catchment scale with land management interventions. We also demonstrate how MMF‐TWI can support hydrologically‐informed decision making to better target conservation measures in humid agricultural environments. Copyright © 2018 John Wiley & Sons, Ltd.     

From drought to flood: A water balance analysis of the Tuolumne River basin during extreme conditions (2015–2017)

The degree to which the hydrologic water balance in a snow-dominated headwater catchment is affected by annual climate variations is difficult to quantify, primarily due to uncertainties in measuring precipitation inputs and evapotranspiration (ET) losses. Over a recent three-year period, the snowpack in California's Sierra Nevada fluctuated from the lightest in recorded history (2015) to historically heaviest (2017), with a relatively average year in between (2016). This large dynamic range in climatic conditions presents a unique opportunity to investigate correlations between annual water availability and runoff in a snow-dominated catchment. Here, we estimate ET using a water balance approach where the water inputs to the system are spatially constrained using a combination of remote sensing, physically based modelling, and in-situ observations. For all 3 years of this study, the NASA Airborne Snow Observatory (ASO) combined periodic high-resolution snow depths from airborne Lidar with snow density estimates from an energy and mass balance model to produce spatial estimates of snow water equivalent over the Tuolumne headwater catchment at 50-m resolution. Using observed reservoir inflow at the basin outlet and the well-quantified snowmelt model results that benefit from periodic ASO snow depth updates, we estimate annual ET, runoff efficiency (RE), and the associated uncertainty across these three dissimilar water years. Throughout the study period, estimated annual ET magnitudes remained steady (222 mm in 2015, 151 mm in 2016, and 299 mm in 2017) relative to the large differences in basin input precipitation (547 mm in 2015, 1,060 mm in 2016, and 2,211 mm in 2017). These values compare well with independent satellite-derived ET estimates and previously published studies in this basin. Results reveal that ET in the Tuolumne does not scale linearly with the amount of available water to the basin, and that RE primarily depends on total annual snowfall proportion of precipitation.