Activation of zinc sulphide with CuII,CdII and PbII: I. Activation in weakly acidic media

During the activation of zinc sulphide with the heavy metal ions Cu^II, Cd^II and Pb^II, metal-ion uptake follows a logarithmic dependence on time. A reaction mechanism is proposed which is consistent with experimental observations. Incident radiation has a strong influence on the activation reaction, an effect which is interpreted in terms of semiconductor theory.     

Activation of zinc sulphide with CuII,CdII and PbII: III. The mass-spectrometric determination of elemental sulphur

A new mass-spectrometric technique, capable of the quantitative detection of very low levels of elemental sulphur on sulphide mineral surfaces has been developed. It is shown that elemental sulphur is formed, under certain conditions, on zinc sulphide surfaces activated by Cu^II, Cd^II and Pb^II. The findings are interpreted in terms of semiconductor theory.     

A normative calculation technique for determining opal in deep-sea sediments

The opal content of deep-sea sediment can be estimated by subtracting non-biogenic silica, calculated from the aluminum and magnesium concentrations in the sediment, from the total silica content of the samples. Unlike most previously described methods, this calculation is capable of yielding reliable estimates of opal in pre-Pleistocene sediments because it is unaffected by structural changes that take place in opal as it ages.     

Persistent organic pollutants and stable isotopes in biopsy samples (2004/2006) from Southern Resident killer whales

“Southern Resident” killer whales include three “pods” (J, K and L) that reside primarily in Puget Sound/Georgia Basin during the spring, summer and fall. This population was listed as “endangered” in the US and Canada following a 20% decline between 1996 and 2001. The current study, using blubber/epidermis biopsy samples, contributes contemporary information about potential factors (i.e., levels of pollutants or changes in diet) that could adversely affect Southern Residents. Carbon and nitrogen stable isotopes indicated J- and L-pod consumed prey from similar trophic levels in 2004/2006 and also showed no evidence for a large shift in the trophic level of prey consumed by L-pod between 1996 and 2004/2006. ∑PCBs decreased for Southern Residents biopsied in 2004/2006 compared to 1993–1995. Surprisingly, however, a three-year-old male whale (J39) had the highest concentrations of ∑PBDEs, ∑HCHs and HCB. POP ratio differences between J- and L-pod suggested that they occupy different ranges in winter.     

Climatic Trends and Temporal Patterns of Phytoplankton Composition, Abundance, and Succession in the Indian River Lagoon, Florida, USA

This paper describes the results of 10 years of water quality monitoring in the Indian River Lagoon Florida, with special emphasis on the relationships between trends in climatic conditions and the distribution, composition, and abundance of the phytoplankton community. The Indian River Lagoon, which spans 220 km of Florida’s east coast, is a region of particular concern because of the rapid rate of human development throughout the region and the hydrologically restricted character of the lagoon, which heightens the potential for algal bloom. Water sampling was carried out on a monthly to twice-monthly basis at six sites located in the northern and central lagoon. The 10-year study included both extended periods of below and above average rainfall. A number of ecologically distinct regions exist within the lagoon, which differ considerably in water exchange properties and watershed inputs. The northern lagoon is characterized by longer water residence times, lower phosphorus concentrations, higher nitrogen concentrations, and more stable salinity conditions than the central lagoon. Mean phytoplankton biovolumes were substantially higher at the sites in the northern lagoon than at the sites in the central lagoon, and algal blooms were more common and intense in the former region. Inter-annual patterns of phytoplankton biovolume were also different in the northern and central lagoon. In the northern lagoon, phytoplankton biovolumes were lowest during the drought period, from the autumn of 1998 to the spring of 2001. By contrast, algal bloom events in the central lagoon were not only less frequent but were not tied to periods of high rainfall. The most widespread and common bloom formers were the potentially toxic dinoflagellate Pyrodinium bahamense var. bahamense and two centric diatoms, Dactyliosolen fragilissimus and Cerataulina pelagica. Many of the biovolume peaks observed over the study period were attributable to these three species. The results of time series modeling of phytoplankton dynamics further highlighted the disparities between the two regions of the lagoon in terms of the suite of parameters that best predict the observed trends in the biomass of phytoplankton. Overall, the outcome of this initial modeling effort in the Indian River Lagoon suggests that time series approaches can help define the factors that influence phytoplankton dynamics.     

Warm‐temperate,marine, carbonate sedimentation in an Early Miocene,tide‐influenced,incised valley; Provence,south‐east France

The Saumane‐Venasque compound palaeovalley succession accumulated in a strongly tide‐influenced embayment or estuary. Warm‐temperate normal marine to brackish conditions led to deposition of extensive cross‐bedded biofragmental calcarenites. Echinoids, bryozoans, coralline algae, barnacles and benthic foraminifera were produced in seagrass meadows, on rocky substrates colonized by macroalgae and within subaqueous dune fields. There are two sequences, S1 and S2, the first of which contains three high‐frequency sequences (S1a, S1b and S1c). Sequence 1 is largely confined to the palaeovalley with its upper part covering interfluves. Each of these has a similar upward succession of deposits that includes: (i) a basal erosional surface that is bored and glauconitized; (ii) a discontinuous lagoonal lime mudstone or wackestone; (iii) a thin conglomerate generated by tidal ravinement; (iv) a transgressive systems tract series of cross‐bedded calcarenites; (v) a maximum flooding interval of argillaceous, muddy quartzose, open‐marine limestones; and (vi) a thin highstand systems tract of fine‐grained calcarenite. Tidal currents during stages S1a, S1b and S1c were accentuated by the constricted valley topography, whereas basin‐scale factors enhanced tidal currents during the deposition of S2. The upper part of the succession in all but S1c has been removed by later erosion. There is an overall upward temporal change with quartz, barnacles, encrusting corallines and epifaunal echinoids decreasing but bryozoans, articulated corallines and infaunal echinoids increasing. This trend is interpreted to be the result of changing oceanographic conditions as the valley was filled, bathymetric relief was reduced, rocky substrates were replaced as carbonate factories by seagrass meadows and subaqueous dunes, and the setting became progressively less confined and more open marine. These limestones are characteristic of a suite of similar cool‐water calcareous sand bodies in environments with little siliciclastic or fresh water input during times of high‐amplitude sea‐level change wherein complex inboard antecedent topography was flooded by a rising ocean.     

Further finds of the Derrick Peak meteorite,Transantarctic Mountains,and implications for terrestrial age

Abstract— Nine additional iron meteorite fragments weighing a total of 72 kg were recovered from the Derrick Peak area by a Canterbury Museum geological party in late 1988. One iron was located in the Onnum Valley, 6 km south of the previous finds. Geochemical analysis indicates that all irons belong to a single meteorite shower, greatly increasing the known extent of the fall zone. Kamp and Lowe (1982) have previously estimated the terrestrial age of the meteorite from glacial geological evidence. The location of the 1988 finds supports Kamp and Lowe's interpretation that the meteorites lie in situ, but recent revisions of the chronology of Cenozoic glacial history of the region reduce the interpreted terrestrial age. An age of between Oxygen Isotope stages 6 and 2 is probable (190–125 to 35–12 ka BP). This conflicts with a terrestrial age estimate of 1.0 ± 0.1 Ma BP from cosmogenic radionuclides.     

Classification of Streaky Bay,Mangalo, Ethiudna and Crockers Well: Stony meteorites from South Australia

Abstract— Four meteorites from South Australia are described and classified. Streaky Bay (L4b) and Mangalo (L6e) were received by the South Australian Museum in December, 1989. Ethiudna (L4a) and Crockers Well (LL7) were previously thought to be paired and were previously described only as chondrites.