利用MC-ICPMS对水样中硼同位素比值的测定

采用Amberlite IRA-743硼特效树脂进行水溶液中硼的分离,对洗脱液温度、体积以及树脂动态交换容量等进行了实验.它的动态交换容量为4.2 mg/g,在室温条件下,用5 mL 2%HNO3可定量从树脂柱上洗脱被吸附的硼.采用Neptune型MC-ICPMS进行硼同位素组成的测定,1 μg/g浓度的硼标准溶液获得放大的信号强度约为0.7V,硼的化学分离过程有效避免了质量歧视效应.实验结果表明,MC-ICPMS对硼存在严重的记忆效应,通过采用5%HNO3-(1%HNO3 0.1%HF)-H2O-20%NH3H2O-H2O的交替清洗方法,可在约1 h内消除硼的记忆效应.在最佳仪器条件下,对含有250 ng硼的水样,可以快速测定硼的同位素组成,占δ11B测定的绝对偏差为0.4‰-0.5‰(SD).     

南海沉积岩芯的地球化学研究

本文对南海中部陆坡区和海盆区的5个岩芯中的 Si,Al,Fe,Mn,Ca,Mg 和 CaCO_3成分做了分析,并对其分布特征与有关影响因素进行了讨论。受沉积区环境差异的影响,元素的分布具有区域性特征;受海区特定地理位置的影响,元素的分布呈现出过渡性特征(浅海到大洋的过渡);受沉积过程中环境变化的影响,元素的分布展示了周期性变化或旋回性。根据岩芯中元素的分布特征,并参考有关古地磁,氧碳同位素和钙质超微化石的测试分析结果,将本区岩芯划分为14层地球化学层,并将本区划分为两个沉积地球化学区,揭示了早更新世以来本区沉积环境的变化和存在的两种沉积模式。     

A three-dimentional model of the northeast East China Sea, with application to the M2 current field

A simple three-dimensional tidal model is used to examine the M2 tidal current distribution in a northeastern part of the East China Sea, especially the vertical variation of the current in the region. Computed M2 current is compared with observations available and found to be in good agreement.Main features of the calculating method in this study are: (1) Vertical variation of the tidal current is taken as a funetion of the depth-mean velocity: (2) the method is applicable to a variety of the vertical eddy viscosities; (3) it has a fine vertical resolution, especially near the sea bootom. So, this method not only enables us to get a steady state solution easily but also depicts effects of the friction on the vertical variation of the current much better.     

Relationship between biogeochemical features of biogenic elements and flocculation in the Changjiang Estuary

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East-west oscillation of sea temperature in the Equatorial Pacific and its modelling

In this paper, by analyzing the data of sea temperature in the Equatorial Western Pacific (EWP), we found that the sea temperature at sensitive district (WSST) (about at 6° N, depth of 125-150 m) is correlated negatively to the sea temperature in the Equatorial Eastern Pacific (EEP). On the basis of basic characteristics of Equatorial Pacific atmosphere and ocean, we designed a simple air-sea coupled model. Using this model,an ocean circulation was simulated. The east-west oscillation of sea temperature in Equatorial Pacific is related to this ocean circulation.     

台湾海峡西部柱状沉积物粘土矿物的分析

根据台湾海峡西部10个柱102个样品的X 射线衍射等分析,鉴定了该区粘土矿物组合与含量变化,分析了其与沉积环境的关系.结果表明,该区粘土矿物组合大多数站位以伊利石含量占首位,绿泥石和高岭石次之,且含少量蒙脱石;伊利石含量随距岸、水深的增加而递增,高岭石则反之;蒙脱石含量与火山活动密切相关,绿泥石含量呈斑块状分布;775和819号站有典型的陆相层,为早玉木冰期的“台湾陆桥”或“东山陆桥”提供有力证据.     

黄河三角洲沿岸及邻近海区细粒沉积物中的碳酸盐

本文用X-射线衍射法直接计算了来自黄河三角洲沿岸及邻近海区80个沉积样的细粒组分(<2μm)中的碳酸盐含量。计算结果与全样的容量法分析结果基本一致。研究结果表明,本区细粒沉积物中碳酸盐含量变化受沉积物来源、海区水动力作用、海底地貌特征和碳酸盐的地球化学行为等因素所影响。     

贻贝育苗中不同饵料的饲养效果比较

培育双壳类软体动物幼苗所需的饵料，是指池内培育阶段适合于幼虫和幼苗(壳长一般在1mm以下)的饵料。育苗成功的关键问题之一为是否已经选择到这样的饵料。自40年代找到适宜的饵料生物以后，双壳类幼虫的培养才取得较明显的成效。以往利用过的一些饵料生物巳有文献系统记载。我国贻贝人工育苗是在分离与培养出扁藻以后才获得成功的。随着研究工作的深入以及适应各种不同情况的需要，采用的饵料种类越来越多样化。从生产性育苗特别是多茬育苗考虑，必须因地制宜地筛选出一定种数的饵料，以便在不同培养条件下有机动选择的余地。同一时还应找出适宜的投饵数量，以求取得较好的育苗效果。为此目的，我们于1975-1978年结合生产性育苗的需要进行了一些饵料饲养实验。本文根据实验结果以及多年来生产性育苗的实践，对贻贝育苗的饵料问题进行总结，侧重于不同饵料的饲养效果比较。     

某船坞南翼墙基岩水下控制爆破技术

本文介绍的基岩水下爆破属临近重要建筑物的水下控制爆破。当岩石裂隙发育，且岩面有较厚的石碴覆盖层，其技术难度大，采取的诸如搭钢平台钻孔。塑料套管护孔，以及孔间、排间塑料导爆管雷管接力式微差起爆网路等措施，都是成功之经验，值得今后类似工程推广应用。     

Wave-Current Forces on Small Square Cylinders (Part I)

-Based on the extended Morison Equation and model tests, the in-line forces on small square cylinders caused by waves (regular and irregular) and currents are analyzed in detail in this paper. The hydrodynamic coefficient CD and Cu related to KC number and the effect of direction of wave incidence are also given, which can be used in engineering practice.