Remediation of NAPL source zones: lessons learned from field studies at Hill and Dover AFB

Innovative remediation studies were conducted between 1994 and 2004 at sites contaminated by nonaqueous phase liquids (NAPLs) at Hill and Dover AFB, and included technologies that mobilize, solubilize, and volatilize NAPL: air sparging (AS), surfactant flushing, cosolvent flooding, and flushing with a complexing-sugar solution. The experiments proved that aggressive remedial efforts tailored to the contaminant can remove more than 90% of the NAPL-phase contaminant mass. Site-characterization methods were tested as part of these field efforts, including partitioning tracer tests, biotracer tests, and mass-flux measurements. A significant reduction in the groundwater contaminant mass flux was achieved despite incomplete removal of the source. The effectiveness of soil, groundwater, and tracer based characterization methods may be site and technology specific. Employing multiple methods can improve characterization. The studies elucidated the importance of small-scale heterogeneities on remediation effectiveness, and fomented research on enhanced-delivery methods. Most contaminant removal occurs in hydraulically accessible zones, and complete removal is limited by contaminant mass stored in inaccessible zones. These studies illustrated the importance of understanding the fluid dynamics and interfacial behavior of injected fluids on remediation design and implementation. The importance of understanding the dynamics of NAPL-mixture dissolution and removal was highlighted. The results from these studies helped researchers better understand what processes and scales are most important to include in mathematical models used for design and data analysis. Finally, the work at these sites emphasized the importance and feasibility of recycling and reusing chemical agents, and enabled the implementation and success of follow-on full-scale efforts.     

五大连池火山群喷气锥成因机制探讨

五大连池火山群1537个喷气锥中,多数分布在火烧山熔岩流中,在水量充足的五池到四池之间的熔岩台地上,喷气锥数量集中、个体较大、发育良好。通过对五大连池火山群喷气锥的形态结构和集中分布特点进行分析,认为水蒸气在混合气体形成喷气锥中起主导作用,重力也在喷气锥形态塑造上有一定意义。含挥发分的基性岩浆溢流到在靠近水域的地区时表层冷凝固结,内部熔岩仍温度高、粘度低,与地下水作用形成火山气体和水蒸气构成的混合气体,气体冲破表层间歇溢出时,带动熔岩外掀堆叠在喷气孔周围形成喷气锥,中央保留气体多次逸出的通道形成中空结构。当气体压力不足以使熔岩从喷口溢出,喷气锥的生长停止。     

晋北地区中元古代岩墙群的地球化学特征和大地构造背景

晋北地区发育大规模的中元古代北北西向岩墙群，未变形和未变质，是华北克拉通前寒武纪构造演化研究的最显著标志，根据本区岩墙群的岩石学和地球化学研究，这些岩墙群的岩石属于板内大陆裂谷玄武岩系列，形成于大陆裂谷拉张的构造环境，与东侧的燕辽－中条拗拉槽内的火山岩岩石化学对比分析，本区岩墙群的基性岩浆可能来自拗拉槽深部，这些基性岩浆从拗拉槽的深部向北西方向侵位于晋北地区先存的构造裂隙中形成了基性岩墙群。     

Use of general circulation model output in the creation of climate change scenarios for impact analysis

Many scientific studies warn of a rapid global climate change during the next century. These changes are understood with much less certainty on a regional scale than on a global scale, but effects on ecosystems and society will occur at local and regional scales. Consequently, in order to study the true impacts of climate change, regional scenarios of future climate are needed. One of the most important sources of information for creating scenarios is the output from general circulation models (GCMs) of the climate system. However, current state-of-the-art GCMs are unable to simulate accurately even the current seasonal cycle of climate on a regional basis. Thus the simple technique of adding the difference between 2 × CO₂ and 1 × CO₂ GCM simulations to current climatic time series cannot produce scenarios with appropriate spatial and temporal details without corrections for model deficiencies. In this study a technique is developed to allow the information from GCM simulations to be used, while accommodating for the deficiencies. GCM output is combined with knowledge of the regional climate to produce scenarios of the equilibrium climate response to a doubling of the atmospheric CO₂ concentration for three case study regions, China, Sub-Saharan Africa and Venezuela, for use in biological effects models. By combining the general climate change calculated with several GCMs with the observed patterns of interannual climate variability, reasonable scenarios of temperature and precipitation variations can be created. Generalizations of this procedure to other regions of the world are discussed.     

Seed bank patterns in Chesapeake Bay eelgrass (Zostera marina L.): A bay-wide perspective

The decline of eelgrass (Zostera marina) in Chesapeake Bay in the 1960s and 1970s has been studied in the context of changes in water quality and habitat suitability; little effort has focused on the importance of reproductive ecology in understanding current and potential recovery of these populations. The spatial variability of seed-bank characteristics ofZ. marina in Chesapeake Bay was explored by a reproductive shoot and seed-bank sampling effort. Seed banks were sampled from 105 beds of submerged aquatic vegetation among 12 zones throughout the lower and middle Chesapeake Bay. Number of viable seeds was highly variable among and within zones, with seeds found in all but one zone and also found in cores not containing anyZ. marina shoots. Number of reproductive shoots was also highly variable among and within zones, with differences probably driven by different local environmental conditions. Bay-wide, viable seeds were found in more monospecificZ. marina cores than in mixed species or monospecificRuppia maritima cores suggesting local biological and environmental control on sexual reproduction. Lower densities of viable seeds in the middle Chesapeake Bay region reflect the lower abundance ofZ. marina in these regions and provide context for discussion of historical changes inZ. marina in Chesapeake Bay. While this study focused on a snap shot of the seed bank immediately after establishment, we highlight critical questions for future study that may be important for their conservation and restoration.     

西秦岭凤太矿集区丝毛岭金矿床地质地球化学特征

西秦岭凤太矿集区丝毛岭金矿床位于八卦庙造山型金矿床西侧5km左右,是一个新探明的剪切带型金矿。其成矿作用过程可分为早期石英-绢云母-硫化物阶段、中期多金属-硫化物阶段和晚期碳酸盐阶段。对早、中期的石英流体包裹体测试结果表明,丝毛岭金矿床成矿流体以富CO2、中温、低盐度为特征,总体上属于中温低盐度CO2-H2O体系,流体包裹体类型的多样性是流体不混溶性的产物。从早阶段到主成矿阶段成矿流体的温度、压力和盐度均有降低,硫逸度增高,有利于金的沉淀富集。H、O、S、C同位素研究结果,以及与八卦庙金矿床的对比分析表明,二者的成矿流体具有相似性和同源性,都是以深部来源为主的多源流体。由于丝毛岭金矿床产出的层位高于八卦庙金矿床,其成矿环境相对开放。     

塔北隆起二叠纪岩浆岩产状的地震解释及其侵位模式

塔北隆起西部发育大面积岩浆岩,岩浆岩发育产状的研究不仅对岩浆岩油气藏勘探具有重要意义,而且对塔北隆起碳酸盐岩油气藏研究具有重要意义。本文利用钻井和地震资料,提出塔北隆起二叠纪岩浆岩岩性主要为玄武岩、流纹岩、辉绿岩、正长岩、花岗岩和凝灰岩。岩浆岩发育模式与构造作用密切相关,在英买力低凸起北部地区,主要发育一条逆冲断层,地层受构造作用扰动较少,岩浆岩主要为玄武岩,通过近于垂直的通道到达地表; 英买2地区,构造挤压作用在盐上形成大量的构造裂缝,岩浆岩侵入其中,形成辉绿岩侵入体; 哈拉哈塘地区构造变形微弱,岩浆岩通过垂直的火山通道到达地表,在地表形成了一层平行分布的喷发岩; 而在塔北隆起的中部,由于受拉张作用的影响,地壳发育一定的减压熔融,形成中酸性岩浆,岩浆侵位产生了大量的中酸性侵入体和喷出岩。     

准噶尔盆地新生代构造应力对石炭纪火山岩构造裂缝发育的控制

构造裂缝的发育对改善储层的储渗条件有着重要的作用,特别是火山岩这种非传统储层,构造裂缝的发育是其成为有效储层的必要条件。本文主要借助构造应力场有限元数值模拟这一成熟的方法对准噶尔盆地石炭纪火山岩构造裂缝的发育状况进行预测。其两个主要的步骤是首先对区域构造应力场进行模拟计算,然后结合岩石的强度指标判断构造裂缝的发育状况。通过对准噶尔盆地地质背景和构造演化的分析,明确了新生代构造应力场的的决定性作用和石炭纪火山岩的分布区域(划分出六个区域),建立了数值模拟的计算模型、确定了边界条件与载荷。通过二维有限元数值模拟(应用Ansys软件)得到了新生代盆地应力场的分布特征和应力值。结合岩石强度指标,对火山岩构造裂缝(张裂缝和剪裂缝)的发育进行了预测并圈出相应的区域,主要为盆地西北缘、中央坳陷中部、滴西1东部,彩参2周缘、大井-将军庙等地区,对石炭纪火山岩的油气勘探战略选区, 优化勘探部署具有重要指导意义。