小秦岭金矿中黄铁矿微量元素原位LA-ICPMS分析及其对矿床成因的指示意义

位于河南和陕西交界的小秦岭金矿集区是我国仅次于胶东金矿的第二大黄金产地,大地构造位置上位于华北地台的南部边缘,属于秦岭造山带的边缘组成部分,近东西向展布.该地区金矿类型主要是石英脉型,少量蚀变岩型.     

Assessing the Effect of Data Imports on the Completeness of OpenStreetMap – A United States Case Study

The assessment of OpenStreetMap (OSM) data quality has become an interdisciplinary research area over the recent years. The question of whether the OSM road network should be updated through periodic data imports from public domain data, or whether the currency of OSM data should rather rely on more traditional data collection efforts by active contributors, has led to perpetual debates within the OSM community. A US Census TIGER/Line 2005 import into OSM was accomplished in early 2008, which generated a road network foundation for the active community members in the US. In this study we perform a longitudinal analysis of road data for the US by comparing the development of OSM and TIGER/Line data since the initial TIGER/Line import. The analysis is performed for the 50 US states and the District of Columbia, and 70 Urbanized Areas. In almost all tested states and Urbanized Areas, OSM misses roads for motorized traffic when compared with TIGER/Line street data, while significant contributions could be observed in pedestrian related network data in OSM compared with corresponding TIGER/Line data. We conclude that the quality of OSM road data could be improved through new OSM editor tools allowing contributors to trace current TIGER/Line data.     

New constraints on the auriferous Witwatersrand sediment provenance from combined detrital zircon U–Pb and Lu–Hf isotope data for the Eldorado Reef (Central Rand Group,South Africa)

Combined U–Pb and Lu–Hf isotope analyses of detrital zircon grains from the auriferous Eldorado Reef conglomerate, upper Central Rand Group, reveal new insights into the provenance of the sediments and thus, by implication, possibly also into that of the gold. Most of the detrital zircon grains, which are of magmatic origin, yielded Mesoarchaean ages clustering around 2.94 and 3.06 Ga. A subordinate zircon population gave ages with maxima at 3.28 and 3.44 Ga. The Mesoarchaean zircon grains mostly show super-chondritic ?Hf_t of up to +5.2, whereas the Palaeoarchaean zircon grains have nearly chondritic composition with ?Hf_t between −1.3 and +2.0. The new dataset of the Mesoarchaean zircon populations provides the first unambiguous evidence of the formation of juvenile crust not only at 3.06 but also at 2.94 Ga. As the analysed zircon grains are from the ruditic fraction, they must be derived from a comparatively proximal source in close vicinity to the Central Rand Basin. Based on currently available data, this source was most likely a magmatic arc that existed at the northern edge of the Witwatersrand Block at 3.06 Ga. An additional source might be the 2.94 Ga magmatic rocks of the Kraaipan Greenstone Belt that occurs to the west of the Witwatersrand Block. The minor fraction of Palaeoarchaean zircon grains in the Eldorado Reef perhaps stem from sources that are isotopically similar to the Barberton Greenstone Belt and the Limpopo Belt but were more proximal to the Central Rand Basin.     

Watson: A new link in the HE iron chain

Abstract— Watson, which was found in 1972 in South Australia, contains the largest single silicate rock mass seen in any known iron meteorite. A comprehensive study has been completed on this unusual meteorite: petrography, metallography, analyses of the silicate inclusion (whole rock chemical analysis, INAA, RNAA, noble gases, and oxygen isotope analysis) and mineral compositions (by electron microprobe and ion microprobe). The whole rock has a composition of an H-chondrite minus the normal H-group metal and troilite content. The oxygen isotope composition is that of the silicates in the HE iron meteorites and lies along an oxygen isotope fractionation line with the H-group chondrites. Trace elements in the metal confirm Watson is a new HE iron. Whole rock Watson silicate shows an enrichment in K and P (each ～2X H-chondrites). The silicate inclusion has a highly equilibrated igneous (peridotite-like) texture with olivine largely poikilitic within low-Ca pyroxene: olivine (Fa₂₀), opx (Fs₁₇Wo₃), capx (Fs₉Wo₄₁) (with very fine exsolution lamellae), antiperthite feldspar (An_1–Or₅) with <1 μm exsolution lamellae (An_1–3Or_>40), shocked feldspar with altered stoichiometry, minor whitlockite (also a poorly characterized interstitial phosphate-rich phase) and chromite, and only traces of metal and troilite. The individual silicate minerals have normal chondritic REE patterns, but whitlockite has a remarkable REE pattern. It is very enriched in light REE (La is 720X C1, and Lu is 90X C1, as opposed to usual chonditic values of ～300X and 100–150X, respectively) with a negative Eu anomaly. The enrichment of whole rock K is expressed both in an unusually high mean modal Or content of the feldspar, Or₁₃, and in the presence of antiperthite. Whole rock trace element data for the silicate mass support the petrography. Watson silicate was an H-chondrite engulfed by metal and melted at > 1550 °C. A flat refractory lithophile and flat REE pattern (at ～1x average H-chondrites) indicate that melting took place in a relatively closed system. Immiscible metal and sulfide were occluded into the surrounding metal host. Below 1100 °C, the average cooling rate is estimated to have been ～1000 °C/Ma; Widmanstätten structure formed, any igneous zoning in the silicates was equilibrated, and feldspar and pyroxene exsolution took place. Cooling to below 300 °C was completed by 3.5 Ga B. P. At 8 Ma, a shock event took place causing some severe metal deformation and forming local melt pockets of schreibersite/metal. This event likely caused the release of Watson into interplanetary space. The time of this event, 8Ma, corresponds to the peak frequency of exposure ages of the H-chondrites. This further confirms the link between HE irons and the H-chondrites, a relationship already indicated by their common oxygen isotope source. Watson metal structures are very similar to those in Kodaikanal. Watson, Kodaikanal and Netschaëvo form the young group of HE meteorites (ages 3.7 ± 0.2 Ga). They appear to represent steps in a chain of events that must have taken place repeatedly on the HE parent body or bodies from which they came: chondrite engulfed in metal (Netschaëvo); chondrite melted within metal (Watson); and finally melted silicate undergoing strong fractionation with the fractionated material emplaced as globules within metal (Kodaikanal). Watson fills an important gap in understanding the sequence of events that took place in the evolution of the IIE-H parent body(ies). This association of H-chondrite with HE metal suggests a surface, or near surface process-a suggestion made by several other researchers.     

Interference Testing for Atmospheric HOx Measurements by Laser-induced Fluorescence

Accurate OH and HO₂ (collectively called HO_x) measurements by laser-induced fluorescence (LIF) may be contaminated by spurious signals from interfering atmospheric chemicals or from the instrument itself. Interference tests must be conducted to ensure that observed OH signal originates solely from ambient OH and is not due to instrument artifacts. Several tests were performed on the Penn State LIF HO_x instrument, both in the laboratory and in the field. Theseincluded measurements of the instrument's zero signal by using either zero air or perfluoropropylene to remove OH, examination of spectral interferences from naphthalene, sulfur dioxide, and formaldehyde, and tests of interferences by addition of suspected interfering atmospheric chemicals, including ozone, hydrogen peroxide, nitrous acid, formaldehyde, nitric acid, acetone, and organic peroxy radicals (RO₂). All tests lacked evidence ofsignificant interferences for measurements in the atmosphere, including highly polluted urban environments.     

Integrating Cavity Absorption Meter measurements of dissolved substances and suspended particles in ocean water

We have developed a new device to measure the separate contributions to the spectral absorption coefficient due to a pure liquid, due to the particles suspended in it, and due to the substances dissolved in it. This device, the Integrating Cavity Absorption Meter (ICAM), is essentially independent of scattering effects in the sample. In April 1993, a prototype of the ICAM was field tested on board the research vessel USNS Bartlett. A major part of the cruise track included criss-crossing the area where the Mississippi flows into the Gulf of Mexico at various ranges from the mouth of the river; thus samples were collected from areas of blue, green, and brown/black water. We evaluated 35 seawater samples collected with 5-l Niskin bottles from 22 locations to determine absorption spectra (380–700 nm) of suspended particles and dissolved substances (gelbstoff). Results validate the ICAM as a viable tool for marine optical absorption research. Gelbstoff absorption at 432.5 nm ranged from 0.024 to 0.603 m⁻¹. Over the spectral region 380→560 nm, gelbstoff absorption by each of the samples could be accurately fit to a decaying exponential. The particle absorption spectra are generally characteristic of those of phytoplankton and exhibit a local maximum at 430–440 nm. Absorption values at 432.5 nm ranged from zero to 1.0 m⁻¹. Some samples with moderate particulate absorption, however, did not show the characteristic local maximum of phytoplankton in the blue and instead resembled the characteristic decaying exponential of detritus with a shape similar to that observed in the gelbstoff. The ratio of gelbstoff to particulate absorption at 432.5 nm ranged from 0.46 to 152.     

Using Volunteered Geographic Information to measure name changes of artificial geographical features as a result of political changes: a Libya case study

Over the past few years, political systems have changed in several countries of the Middle East as a result of citizen revolutions on the ruling regimes. These geopolitical changes have had effects on the names of artificial geographical features, such as roads and schools. Many of the names, especially those that were associated with previous regimes, were changed to become associated with the revolutions, their dates, their leaders, or their martyrs. The recent change in the paradigm of Web use towards data sharing and crowd-sourcing in the Web 2.0 provides new opportunities to get insight into a local community’s perception of political events. Crowd-sourced spatial data, often referred to as Volunteered Geographic Information (VGI), can be contributed and accessed through various websites and data repositories. These data can supplement traditional data sources, such as road maps hosted by governmental offices. Libya’s governmental maps of urban infrastructure are scarce and incomplete. This provides an incentive for citizens and grassroots groups to collect and generate spatial data on their own and to express changed realities of feature names by the means of crowd-sourced mapping. Using two districts in Libya this study evaluates for five Web 2.0 platforms (OpenStreetMap, Wikimapia, Google Map Maker, Panoramio, and Flickr) to which extent VGI reflects name changes of geographical features as a result of the revolution in 2011. Other data sources, such as school directories posted by teachers on Facebook, serve as additional information for feature name change detection. Results show that the extent to which VGI reflects name changes based on the 2011 revolution in Libya varies strongly between VGI data sources. VGI provides a useful supplement to limited governmental resources to better understand how names of artificial geographical features are affected by changes in political systems.