An interlaboratory comparison of source rock data

Organic matter in eight rock samples has been analyzed by nineteen laboratories and the results show that source rock data from any one laboratory cannot be directly compared to data from any other laboratory. A high degree of variability exists among the data reported by the nineteen participating laboratories, most of which can be explained by differences in the sample preparation steps and analytical procedures used in these laboratories. Differences also exist in the definition of basic units of measurement being reported. In order to make the data more comparable, standard rock samples and analytical methods should be developed and used by all laboratories. Until then, extreme caution must be used when comparing source rock data from different laboratories.     

Seismic resistance of precast concrete shear walls

The earthquake resistance of stacked precast concrete simple shear walls found typically in Large Panel buildings of the cross-wall type is studied. Physical model testing on a small shaking table facility and analytical techniques are compared. Results of the testing of four models to failure portrayed the non-linear effects of rocking and shear slip that were assumed in several analytical studies but were never before measured experimentally. The physical model studies are supplemented with an independent mathematical analysis using a modified version of the dynamic, non-linear computer code Drain 2–D. Correlation of the analytical and experimental results show that the computer study can be used to predict the overall shear wall response. Results of the small scale model and the mathematical model studies indicate that the simple shear wall behaves in a non-linear manner, even for low magnitudes of base acceleration. Non-linear effects, usually concentrated in only one or two joints, reduced force levels and increased displacements. The four small scale models that were tested withstood high magnitudes of base acceleration without collapse.     

Effects of Bunker C oil on Juvenile horseshoe crabs (Limulus polyphemus)

Newly hatched horsehoe crabs (Limulus polyphemus) were exposed to autoclaved Bunker C oil for 8 weeks. Autoclaving served to prevent bacterial degradation of stored oil and to drive off the volatile fraction of the oil. The oil was introduced in the form of a whole oil suspension. Minimum lethal dose was shown to be 2.25 mg per 1. Concentrations greater than 0.25 mg per 1 caused a delay in molting.     

Application of a wind-driven hydrodynamic model for the quantification of transport in an open boundary canal-lakes system in sw Friesland,The Netherlands

The south western lake district is a part of the boezem, a system of interconnected lakes and canals in the province of Friesland. The lake district has open boundaries with the other part of the boezem system. However, discharges in the boundary canals are unknown. These discharges are needed for modelling the phosphorus dynamics in the study area. Incidental water flow measurements gave a good indication of the complex water transport in the study area, but continuous water flow recording was not possible. Consequently, discharges could not be measured directly. In order to quantify the discharges, the water transport in the area was modelled by the application of a detailed wind-driven hydrodynamic model. In the model hourly mean values of wind data and water levels at the boundary locations were used as forcing functions. Model tuning was done by comparing observed and computed water levels of three stations within the system. This approach is new in surface water systems in The Netherlands. Therefore, a sensitivity analysis was done and it was verified whether the model results were reliable.The sensitivity analysis showed that the sensitivity was low for modifications of the wind exponent value and rather high for the bottom roughness coefficient. Simulations with daily or weekly mean wind and water level data resulted in an undesirable loss of detail. The sensitivity for noise at the imposed water levels at the boundary locations was moderate. The calculated discharges were used as forcing functions for a chloride mass balance model. Calculated chloride concentrations coincided with measured concentrations in three lakes, during three periods. From this it was concluded that the discharges were reliable. The simulations also lead to the quantification of the water balance and water residence times in the lakes.     

Sulfate reduction in deep coastal marine sediments

Sulfate reduction rates in sediments of four deep stations in the Saguenay Fjord and the Laurentian Trough, Gulf of St. Lawrence, are among the lowest reported for the coastal environment. Maximum rates were 0.4–7.0 nmol cm⁻³ day⁻¹. The low rates are due to relatively low sedimentation rates and continuously low temperatures. Regional differences in both integrated and maximum sulfate reduction rates in the sediment correlate with sediment trap measurements of sedimentation rate and organic carbon flux.Sulfate reduction accounts for the degradation of 5–26% of the estimated downward flux of organic matter to these sediments. Unlike the absolute rate of sulfate reduction, the relative proportion of the carbon flux that is degraded via sulfate reduction is not directly correlated with the sedimentation rate but is a function of organic matter composition, intensity of bioturbation, and the abundance of sub-oxic electron acceptors. Thus, the lowest proportion of carbon degradation via sulfate reduction occurred at a Gulf site, where a combination of low sedimentation and bioturbation rates allowed a long residence time for organic matter near the sediment surface and, in consequence, a low flux of labile carbon into the sulfate reduction zone. The highest proportion was observed at a station with a similar organic carbon flux but with higher rates of sedimentation and bioturbation. At a third site, with the highest rates of sulfate reduction as well as the highest rates of sedimentation and bioturbation, the contribution of sulfate reduction to organic matter degradation was only intermediate. This is attributable to the exhaustion of the supply of porewater sulfate. In deep coastal environments the proportion of organic matter degraded via sulfate reduction can be highly variable both spatially and temporally.