Multiple fluid components of salt diapirs and salt dome cap rocks, Gulf Coast, U.S.A.

Salt diapirs contain a few percent of anhydrite that accumulated as residue to form anhydrite cap rocks during salt dissolutions. Reported ⁸⁷Sr/⁸⁶Sr ratios of these salt-hosted and cap rock anhydrites in the Gulf Coast, U.S.A., indicate their derivation from Middle Jurassic seawater. However, a much wider range of ⁸⁷Sr/⁸⁶Sr ratios, incorporating a highly radiogenic component in addition to the Middle Jurassic component, has been found in several Gulf Coast salt domes. This wide range of ⁸⁷Sr/⁸⁶Sr ratios of anhydrite within the salt stocks records Sr contributions from both marine water and formation water that has equilibrated with siliciclastics. During cap rock formation this anhydrite either recrystallized in the presence of, or was cemented by, a low-Sr fluid with a Late Cretaceous seawter-type Sr isotope ratio or simply lost Sr during recrystallization. Later, the cap rock was invaded by warm saline brines with high Sr isotope ratios from which barite and metal sulfides were precipitated. Subsequently, low-salinity water hydrated part of the anhydrite bringing to six the total number of fluids that interacted througout the history of salt dome and cap rock growth. The progenitor of these salt diapirs, the Louann Formation, is generally thought to have formed from marine water evaporated to halite and, rarely, higher evaporite facies. Salt domes in the East Texas, North Louisiana, and Mississippi Salt Basins have ⁸⁷Sr/⁸⁶Sr and δ³⁴S values that corroborate a Mid-Jurassic age for the mother salt. However, salt domes in the Houston and Rio Grande Embayments of the Gulf Coast Basin have ⁸⁷Sr/⁸⁶Sr ration ranging to values higher than both Middle Jurassic seawater and all Rb-free marine Phanerozoic rocks. These anomalous ⁸⁷Sr/⁸⁶Sr ratios are probably derived from radiogenic Sr-bearing fluids that equilibrated with siliciclastic rocks and invaded the salt either prior to, or during, diapirism. Potential sources of the radiogenic ⁸⁷Sr component include clay and/or feldspar (located either in older units beneath the Louann Formation or younger units flanking the salt diapirs) and K-salts within the Louann evaporites. Because partial Sr exchange in anhydrite had to take place in a fluid medium, admittance of radiogenic ⁸⁷Sr-bearing fluids into the salt may have led to diapirism by lowering the shear strength of the crystalline salt. The slight number of anomalous ⁸⁷Sr/⁸⁶Sr values in the interior basins indicates that anomalous values are related to areally discrete structural or stratigraphic controls that affected only the Gulf Coast Basin.     

Petrology and origin of the shergottite meteorites

Shergottites contain cumulus pigeonite and augite, probably without cumulus plagioclase and crystallized under relatively oxidizing conditions. Shergotty and Zagami may differ in the relative proportions of cumulus pyroxenes and crystallized intercumulus liquid, but the compositions of pyroxenes and liquid are similar in both meteorites. Absence of olivine in melting experiments suggests that the shergottites crystallized from fractionated derivatives of primary liquids. Low-Ca pyroxene and augite apparently began to crystallize from these primary liquids prior to plagioclase. Shergottites can be readily distinguished from other achondrite groups by their mineralogies, crystallization sequences and inferred source region compositions. However, the source regions of the shergottites may be related to those of other achondrite types by addition or loss of volatile components.The bulk composition of the Earth's upper mantle overlaps that of permissible shergottite source regions. Shergottites and terrestrial basalts display similarities in oxidation state and concentrations of trace and minor elements with a wide range of cosmochemical and geochemical affinities. Accretion of similar materials to produce the terrestrial upper mantle and the shergottite parent body or accretion of the Earth's upper mantle from planetesimals similar to the shergottite parent body may account for many of their similarities. Models of the origin of the Earth's upper mantle which attribute its oxidation state, its siderophile element abundances and its volatile element abundances to uniquely terrestrial processes or conditions, or to factors unique to the origin and differentiation of large bodies, are unattractive in light of the similarities between shergottites and terrestrial basalts.     

A petrogenetic model of the relationships among achondritic meteorites

The basaltic achondrite, shergottite, nakhlite, and chassignite meteorites appear to define a petrological and geochemical sequence. Assuming that they developed from basaltic liquids produced by low pressure partial melting of plagioclase peridotites, their petrological and chemical distinctions can be understood in terms of the compositional differences between their source periodites. The source regions of basaltic achondrite magmas were alkali-poor, metal-bearing peridotites in which pigeonite and/or orthopyroxene was the only pyroxene. By simultaneously increasing the ratio of high-Ca pyroxene to low-Ca pyroxene, the alkali content of the feldspar, the oxidation state, and the overall volatile content of the basaltic achondrite source peridotite, peridotites capable of yielding the parent liquids of the shergottites can be produced. Further increases can produce peridotites capable of yielding the parent liquids of the nakhlites and chassignites.Addition of a volatile-rich component to the volatile-poor type of peridotite required for the source regions of the eucrites appears to be capable of producing the required series of peridotites. Alternatively, progressive volatile-loss from a volatile-rich material, possibly of roughly cosmic composition, could have produced this sequence of peridotites. A simple two-component model of planetary compositions is, to a first approximation, consistent with the petrology and chemistry of these igneous meteorite groups.     

Petrogenetic relationship between Allan Hills 77005 and other achondrites

Allan Hills (ALHA) 77005 is a newly discovered, unique achondrite from Antarctica. Petrologic similarities with the shergottites in terms of mineralogy, oxidation state, inferred source region composition, shock metamorphic effects and shock ages suggest a genetic relationship. Volatile to involatile element ratios (e.g. K/U, Rb/U, Cs/U, Tl/U) and abundances of other trace elements support this hypothesis. ALHA 77005 may be a cumulate that crystallized from a liquid parental to those from which the shergottites crystallized; alternatively it may be a sample of the type of source peridotite from which shergottite parent liquids were derived by partial melting. Chemical similarities with terrestrial ultramafic rocks suggest that this unique meteorite provides an additional sample of the only other solar system body known to have basalt source regions chemically similar to the upper mantle of the Earth.     

An innovative hydrogeologic setting for disposal of low-level radioactive wastes

A natural unique hydrogeological setting favorable for safe and economical disposal of low-level radioactive wastes occurs in the flat hinterland of southeastern North Carolina. The uniqueness results partly from the absence of vertical and horizontal groundwater gradients, representing a nonflow, or null, zone. The null setting is localized to key horizons 30 to 75 feet below land surface and to areas where glauconitic sandy clays of the Peedee Formation lie under less than 25 feet of surficial sandy clays; the Peedee contains nearly stagnant brackish groundwater slightly below the proposed disposal zone.Issues to overcome include: (1) demonstrating better combined safety and economical features over conventional and prescribed settings, (2) dewatering the low-permeability disposal zone for the 20-year operational period, and (3) changing rules to allow disposal slightly below the zone in which the normal water table occurs.Favorable site characteristics of the key setting are: (1) no major aquifer to contaminate, (2) no surface streams or lakes to contaminate, (3) optimal ion exchange and sorptive capacity (clay and glauconite pellets), (4) no appreciable or distinctive vertical and horizontal gradients, (5) no elongated contaminated plume to develop, (6) no surface erosion, (7) a capable setting for injection of potential contaminated water into deep brackish water wells, if needed and allowed, (8) minimum problems of the overfilled bathtub effect, (9) no apparent long-term harmful environmental impact (normal water table would be restored after the 20-year period), (10) relatively inexpensive disposal (engineered barriers not needed and desired), (11) simple and relatively inexpensive monitoring, (12) large tracts of land likely available, and (13) sparse population.In spite of legal and political obstacles to shallow land burial, the null setting described is a capable hydrogeological host to contain low-level radioactive wastes. The setting may have safety and economic advantages over selected sites in eastern North America and over innovative technological experiences in Europe.     

Dynamics of a confined lava flow on Kilauea volcano,Hawaii

This paper presents a new method of analysing lava flow deposits which allows the velocity, discharge rate and rheological properties of channelled moving lavas to be calculated. The theory is applied to a lava flow which was erupted on Kilauea in July 1974. This flow came from a line of fissures on the edge of the caldera and was confined to a pre-existing gully within 50 m of leaving the vent. The lava drained onto the floor of the caldera when the activity stopped, but left wall and floor deposits which showed that the lava banked up as it flowed around each of the bends. Field surveys established the radius of curvature of each bend and the associated lava levels, and these data, together with related field and laboratory measurements, are used to study the rheology of the lava. The results show the flow to have been fast moving but still laminar, with a mean velocity of just over 8 m s^–1; the lava had a low or negligible yield strength and viscosities in the range 85–140 Pa s. An extension of the basic method is considered, and the possibility of supercritical flow discussed.     

The composition of carbonaceous chondrite matrix

Matrix compositions of 32 carbonaceous chondrites have been analyzed by an electron microprobe defocussed-beam technique. Except in those chondrites that show evidence of metamorphism, matrices are compositionally similar and have correlation coefficients of +0.96 or greater. Weight per cent Mg/Si in matrices is constant (0.82 ± 0.05) but less than ratios derived from bulk analyses. Matrices in metamorphosed meteorites are Mg-depleted relative to those of other chondrites. Al Rais and Renazzo (anomalous by any classification scheme) have Mg-enriched matrices. Average matrix compositions cluster into chemical subgroups similar to those based on bulk chemical and petrographie criteria [C1, C2, C3(0), C3(V)]. C1 matrices are particularly variable in composition from point to point within the same meteorite, but points within individual breccia clasts appear to be more compositionally uniform. Cl matrices are depleted in Na, S, and Ca relative to solar and C2 matrix values, probably as a result of leaching. Matrix Ca/A1 ratios are highly variable and generally fall below the accepted meteoritic value. The only strong interelement correlation is for Fe, Ni, and S in C2 matrices, suggesting mixing of variable proportions of two components: Mg-rich phyllosilicate and a Ni-bearing chalcophile phase. The amount of magnetite associated with C2 matrix appears to vary systematically with matrix composition. Isotopic, chemical, and mineralogical constraints suggest that matrix, although appreciably altered in some meteorites, is chiefly a solar system condensation product which contains an admixture of unprocessed interstellar dust.     

Petrographic variations among carbonaceous chondrites of the Vigarano type

The Vigarano subtype is a petrographically complex class of meteorites. Oxidized and reduced groups can be distinguished on the basis of metal vs magnetite abundances and Ni contents of sulfide minerals. These meteorites also differ in the proportions of matrix and chondrules and in polymict character. Slight bulk chemical differences correlate with the recognized petrologic groupings. It is likely that the Vigarano subtype includes several previously unrecognized subgroups. Metamorphism has affected Coolidge, Mulga (West) and, to a lesser extent, Allende, as evidenced by ferromagnesian mineral equilibration, Fe-enrichment of fine-grained inclusions, and loss of some volatile gases. Because of the metamorphic effects in the Allende chondrite (the only meteorite of the group that has been intensively studied) and the petrographie differences among all meteorites of the Vigarano subtype, it is suggested that Allende alone may not adequately reflect the wide spectrum of properties in this important class of meteorites.