Influence of HCl/HF treatment on organic matter in aquifer sediments: A Rock-Eval pyrolysis study

Rock–Eval pyrolysis is increasingly used for the routine characterization of natural organic matter in soils and sediments. In this work the bulk composition of sedimentary organic matter (SOM) in sandy aquifer sediments is studied, as well as purified samples (isolation of SOM) by HCl/HF treatment. This treatment is necessary to avoid detection limit problems for samples with low SOM contents, but the results presented here indicate that this treatment influences the organic geochemistry of the aquifer sediment samples. The FID and CO₂/CO pyrograms show a shift of 10–40 °C of the major peak to a lower temperature. Organic matter alteration or removal of components containing O-bearing groups may explain this. It is also suggested that destruction of the mineral matrix may lead to the reduced retention of the material. For the change of the CO₂/CO pyrograms of the RC fraction only organic matter alteration seems to be likely. Concentrated organic matter samples may also accelerate the release of exothermic energy and influence the pyrograms. Results indicate that the organic matter concentration in the sample influences the measured total organic matter (TOM) content and the T_max of the FID pyrogram, while the sample loading (absolute organic matter amount) up to 80 mg in the Rock–Eval apparatus does not. The FID pyrograms can be deconvoluted into four subpeaks, which allows comparison of samples at various depths. Rock–Eval pyrolysis may only be routinely applied to characterize SOM in aquifer sediments when such systematic and analytical phenomena are taken into account.     

Interaction of free-floating planets with a star–planet pair

The recent discovery of free-floating planets and their theoretical interpretation as celestial bodies, either condensed independently or ejected from parent stars in tight clusters, introduced an intriguing possibility. Namely, that some exoplanets are not condensed from the protoplanetary disk of their parent star. In this novel scenario a free-floating planet interacts with an already existing planetary system, created in a tight cluster, and is captured as a new planet. In the present work we study this interaction process by integrating trajectories of planet-sized bodies, which encounter a binary system consisting of a Jupiter-sized planet revolving around a Sun-like star. To simplify the problem we assume coplanar orbits for the bound and the free-floating planet and an initially parabolic orbit for the free-floating planet. By calculating the uncertainty exponent, a quantity that measures the dependence of the final state of the system on small changes of the initial conditions, we show that the interaction process is a fractal classical scattering. The uncertainty exponent is in the range (0.2–0.3) and is a decreasing function of time. In this way we see that the statistical approach we follow to tackle the problem is justified. The possible final outcomes of this interaction are only four, namely flyby, planet exchange, capture or disruption. We give the probability of each outcome as a function of the incoming planet’s mass. We find that the probability of exchange or capture (in prograde as well as retrograde orbits and for very long times) is non-negligible, a fact that might explain the possible future observations of planetary systems with orbits that are either retrograde (see e.g. Queloz et?al. Astron. Astrophys. 417, L1, 2010) or tight and highly eccentric.     

Extreme Dynamic Metamorphism and Earthquakes

<正>For 50+years after the discovery of deep earthquakes in the 1920s,their causal mechanism was one of the major unsolved problems of geophysics.It was clear that the physics that explains shallow earthquakes could not apply to deep ones because the pressure is too high at≥~50km to     

Response of a mid‐latitude cirque glacier to climate over the last two decades: Mangaehuehu Glacier,Mt Ruapehu

The recent loss of mountain glaciers in response to climate warming has been reported across a range of latitudes globally, but the processes involved are not always straightforward. In southern Pacific mid‐latitudes, twentieth‐century glacier fluctuations are thought to reflect the strength of westerly atmospheric circulation, which brings increased precipitation, leading to mass gains. We present a study of the response of Mangaehuehu Glacier, a cirque glacier on Mt Ruapehu, to climate over the last two decades. Glacier surface area fluctuated in size over this period, corresponding closely with mean end‐of‐summer snowlines in the Southern Alps. The key control on glacier extent appears to be ablation season temperature, itself controlled by regional atmospheric circulation, including El Niño‐Southern Oscillation, Interdecadal Pacific Oscillation (IPO), and to a lesser extent, Southern Annular Mode (SAM). Copyright © 2011 John Wiley & Sons, Ltd.     

Use of oxygen isotope ratios in correlation of tuffs,East Rudolf Basin,northern Kenya

Oxygen isotope determinations were made using CoF₃ to extract oxygen from 27 volcanic glass samples from the East Rudolf Basin, northern Kenya. Results show that the older tuffs are progressively enriched in¹⁸O and that this index can be used in the correlation of volcanic ash units. This method could not distinguish individual samples from the youngest units studied because their ranges of δ¹⁸O overlap. The δ¹⁸O values for the shards in the Tulu Bor Tuff, the KBS Tuff, the Koobi Fora Tuff and the Chari Tuff range from 14.5 to 16.4, from 8.9 to 9.5, from 6.6 to 7.0 and from 7.0 to 7.2, respectively, in decreasing age. Determinations from pumice cobbles are consistently higher than the above values.     

Modification of the deep salinity-maximum in the Southern Ocean by circulation in the Antarctic Circumpolar Current and the Weddell Gyre

The evolution of the deep salinity-maximum associated with the Lower Circumpolar Deep Water (LCDW) is assessed using a set of 37 hydrographic sections collected over a 20-year period in the Southern Ocean as part of the WOCE/CLIVAR programme. A circumpolar decrease in the value of the salinity-maximum is observed eastwards from the North Atlantic Deep Water (NADW) in the Atlantic sector of the Southern Ocean through the Indian and Pacific sectors to Drake Passage. Isopycnal mixing processes are limited by circumpolar fronts, and in the Atlantic sector, this acts to limit the direct poleward propagation of the salinity signal. Limited entrainment occurs into the Weddell Gyre, with LCDW entering primarily through the eddy-dominated eastern limb. A vertical mixing coefficient, κ_V of (2.86 ± 1.06) × 10^?4 m² s^?1 and an isopycnal mixing coefficient, κ_I of (8.97 ± 1.67) × 10² m² s^?1 are calculated for the eastern Indian and Pacific sectors of the Antarctic Circumpolar Current (ACC). A κ_V of (2.39 ± 2.83) × 10^?5 m² s^?1, an order of magnitude smaller, and a κ_I of (2.47 ± 0.63) × 10² m² s^?1, three times smaller, are calculated for the southern and eastern Weddell Gyre reflecting a more turbulent regime in the ACC and a less turbulent regime in the Weddell Gyre. In agreement with other studies, we conclude that the ACC acts as a barrier to direct meridional transport and mixing in the Atlantic sector evidenced by the eastward propagation of the deep salinity-maximum signal, insulating the Weddell Gyre from short-term changes in NADW characteristics.     

Temporal stability of soil water content as affected by climate and soil hydraulic properties: a simulation study

Temporal stability of soil water content (TS SWC) is an often‐observed phenomenon, which characterization finds multiple applications. Climate and variability in soil properties are usually mentioned as factors of TS SWC, but their effects are far from clear. The objective of this work was to use SWC modeling to evaluate the effects of climate and soil hydraulic properties on the TS of soil water at different measurement schedules. We selected four representative climates found in USA and simulated the multiyear SWC dynamics for sandy loam, loam, and silty clay loam soils, all having the lognormal spatial distribution of the saturated hydraulic conductivity. The CLIMGEN and the HYDRUS6 codes were used to generate weather patterns and to simulate SWC, respectively. Four different methods were applied to select the representative location (RL). The low probability of having the same variability of mean relative differences of soil water under different climates was found in most of the cases. The probability that the variance of mean relative differences depended on sampling frequency was generally higher than 91% for the three soils. The interannual difference in mean relative differences variation from short and intensive summer campaigns was highly probable for all climates and soils. The RLs changed as climate and measurement scheduling changed, and they were less pronounced for coarse‐textured soils. The RL selection methods based solely on bias provided more consistency as compared with other methods. The TS appears to be the result of the interplay between climate, soil properties, and survey protocols. One implication of this factor interaction effect on TS SWC is that a simulation study can be useful to decide on the feasibility of including a search for TS‐based RLs for a specific site. Copyright © 2013 John Wiley & Sons, Ltd.     

Synergy between Virtual Local Air Pollutants and Greenhouse Gases Emissions Embodied in China’s International Trade

Increasing pressure from the international community to reduce carbon emissions, coupled with the need to reduce domestic air pollutants, is forcing China to deal with both sources of emissions. Air pollutants and greenhouse gases are closely linked via their common source, fossil fuels. As a result of globalization, large portions of these emissions are associated with trade. This study uses data from the World Input-Output Database (WIOD), including 27 EU countries and 13 major countries, covering the period from 2000 to 2009, and applies MRIO (Multiregional input-output) to estimate emissions embodied in China’s international trade. We focus on the synergy between LAPs (local air pollutants) and GHG consumption-based emissions, and the relationship between virtual LAPs and virtual GHGs associated with China’s international trade from 2000 to 2009. The results indicate that a strong synergistic relationship exists and that air pollutant control can serve as an endogenous mechanism to mitigating greenhouse gases. Thanks to domestic actions to control air pollutants, every ton reduction of LAP emissions related to export can save 27.1 tons of GHG emissions in 2005 over emissions efficiency levels, and can save 32.4 tons of GHG emissions in 2009 over 2005. Mitigation actions taken to reduce air pollutants could also reduce GHG emissions.