Quenching of phosphorus fixation with organic wastes in a bauxite mine overburden

Capabilities of two phosphate-rich organic wastes to quench phosphorus (P) fixation in a stored high-phosphorus-fixing tropical bauxite overburden were examined in a field experiment. Prior grinding and ensiling of shrimp shell waste facilitated increased solubility and hence phosphorus fixation quenching in the soil. Normal plant-available P concentrations were exhibited by the overburden for up to 4 months after application despite the cultivation and harvesting of plants in the treated beds. Ten-year-old, stored overburden treated with ensiled shrimp shell silage, or chicken manure exhibited P levels of 1.0 and 1.1%, respectively, 4 months after treatment application. This represents a small excess over normal concentrations of free P in the overburdens. These P levels dropped to 0.055 and 0.060%, respectively, after 8 months. The capacity of the soil to fix phosphorus was thus rapidly “filled” with an excess of P in the overburden. However, increased P fixation in the second 4-month period was attributed to the inherently high levels of Ca²⁺ in the ground. Therefore, amelioration based on quarterly applications promises a long-term corrective for P-fixing in stored bauxite overburdens.     

Perceptions and costs of seal impacts on Atlantic salmon fisheries in the Moray Firth,Scotland: Implications for the adaptive co-management of seal-fishery conflict

The Moray Firth Seal Management Plan (MFSMP) was introduced in Scotland in 2005 as a pilot for resolving conflict between Atlantic salmon fisheries and conservation imperatives for protected harbour and grey seals. This adaptive co-management model is now being applied nationally through the Marine (Scotland) Act (2010). However, no information exists on salmon fishery stakeholders’ perceptions of seal predation impacts and related costs, which could influence the success of the MFSMP and other similar initiatives. In 2006 a questionnaire survey of the 95 salmon rod fisheries in seven major Moray Firth rivers was undertaken, and all 20 active salmon netting stations in the Firth. Forty-five fishery owners, 39 ghillies, 120 anglers and 11 netsmen (representing 17 netting stations) responded. The majority (81%) believed that seals had a significant or moderate impact on stocks and catches, 77% believed that all seals were responsible and 47% supported seal culling. Seals were sighted by 38% of rod fisheries, and 18% lost angler days from seal interference. Overall, 0.2% of total reported angler days were lost annually. The estimated direct cost of seal interference for responding rod fisheries was £14,960 annum⁻¹, and losses of catches and damage to nets was £16,500 annum⁻¹ for responding netsmen. Stakeholders’ perceptions were largely inconsistent with their low direct costs and the aims of the MFSMP. Possible reasons for this are discussed, and implications for the governance of future adaptive co-management initiatives for seal-fishery conflict.     

Plankton community diversity from bacteria to copepods in bloom and non-bloom conditions in the Celtic Sea in spring

The plankton community composition comprising heterotrophic bacteria, pro-/eukaryotes, heterotrophic nanoflagellates, microzooplankton and mesozooplankton was assessed during the spring bloom and at non-bloom stations in the English Channel and Celtic Sea between 6 and 12 April 2002. Non-bloom sites were characterised by a dominance of pro-/eukaryotic phytoplankton <20 μm, higher abundance of heterotrophic nanoflagellates, microzooplankton standing stocks ranging between 60 and 380 mg C m⁻², lower mesozooplankton diversity and copepod abundance of between 760 and 2600 ind m⁻³. Within the bloom, the phytoplankton community was typically dominated by larger cells with low abundance of pro-/eukaryotes. Heterotrophic nanoflagellate cell bio-volume decreased leading to a reduction in biomass whereas microzooplankton biomass increased (360–1500 mg C m⁻²) due to an increase in cell bio-volume and copepod abundance ranged between 1400 and 3800 ind m⁻³. Mesozooplankton diversity increased with an increase in productivity. Relationships between the plankton community and environmental data were examined using multivariate statistics and these highlighted significant differences in the abiotic variables, the pro-/eukaryotic phytoplankton communities, heterotrophic nanoflagellate, microzooplankton and total zooplankton communities between the bloom and non-bloom sites. The variables which best described variation in the microzooplankton community were temperature and silicate. The spatial variation in zooplankton diversity was best explained by temperature. This study provides an insight into the changes that occur between trophic levels within the plankton in response to the spring bloom in this area.     

Spectral observations for near-Earth objects including potential target 4660 Nereus : Results from Meudon remote observations at the NASA Infrared Telescope Facility (IRTF)

We present visible and near-infrared spectral measurements for the highly accessible spacecraft target 4660 Nereus and three additional near-Earth objects displaying diverse color characteristics. All near-infrared measurements were carried out during the first remote observing operations between the Observatoire de Paris at Meudon and Mauna Kea, Hawaii. From Meudon, we had fine pointing and guiding control of the NASA Infrared Telescope Facility 3.0-m telescope and the near-infrared spectrograph “SpeX” to measure asteroid spectra in the range 0.8-. The efficiency of the observation was virtually the same as if the observers had been on location. We combine our near-infrared results with complementary 0.4- spectral measurements. Nereus is found to be a rare Xe-type asteroid with a composition that may be analogous to very high albedo enstatite achondrite (aubrite) meteorites, leading to a diameter estimate of less than . 1685 Toro displays a classic S-type spectrum while a steeper visible wavelength slope and a less pronounced absorption feature for 1943 Anteros places it in the L-class. Also unusual is the apparent olivine-rich spectrum for 4142 Dersu-Uzala, which is classified as an A-type.     

SHRIMP baddeleyite age for the Fraser Dyke Swarm,southeast Yilgarn Craton,Western Australia

Recent high‐resolution aeromagnetic data have delineated an extensive swarm of undeformed northeast‐trending dolerite dykes in the southeastern Yilgarn Craton, known previously only from isolated exposures in surface mining operations. Owing to parallelism of the dykes to the Fraser Mobile Belt, the eastern segment of the Albany‐Fraser Orogen, the swarm is referred to here as the Fraser Dyke Swarm. Ion‐microprobe dating of baddeleyite from a granophyric segregation in the centre of one dyke yields a mean ²⁰⁷Pb/²⁰⁶Pb age of 1212 ± 10 Ma (95% confidence limits). The location of the Fraser Dyke Swarm, adjacent and parallel to the Fraser Mobile Belt, suggests that the dykes may have been emplaced into lines of weakness that originated during tectonic loading and downwards flexure of the craton margin. This is the first evidence of ca 1210 Ma mafic dykes and associated crustal‐scale extension in the southeast Yilgarn Craton, although the age is similar to those reported recently for dolerite and quartz diorite dykes in the central and southern part of the craton, suggesting that a genetic relationship may exist between intrusions in the two areas.     

Radio-colouration of diamond: a spectroscopic study

We have undertaken a study of the common green or orange-brown spots at the surface of rough diamond specimens, which are caused by alpha particles emanating from radioactive sources outside the diamond. Richly coloured haloes represent elevated levels of structural damage, indicated by strong broadening of the main Raman band of diamond, intense strain birefringence, and up-doming of spots due to their extensive volume expansion. Green radio-colouration was analogously generated through the irradiation of diamond with 8.8 MeV helium ions. The generation of readily visible radio-colouration was observed after irradiating diamond with ≥10¹⁵ He ions per cm². The accumulation of such a high number of alpha particles requires irradiation of the diamond from a radioactive source over long periods of time, presumably hundreds of millions of years in many cases. In the samples irradiated with He ions, amorphisation was observed in volume areas where the defect density exceeded 5 × 10^?3 Å^?3 (or 0.03 dpa; displacements per target atom). In contrast, graphitisation as a direct result of the ion irradiation was not observed. The green colouration transformed to brown at moderate annealing temperatures (here 450 °C). The colour transformation is associated with only partial recovery of the radiation damage. The colour change is mainly due to the destruction of the GR1 centre, explained by trapping of vacancies at A defects to form the H3 centre. An activation energy of ~2.4 ± 0.2 eV was determined for the GR1 reduction. The H3 centre, in turn, causes intense yellowish-green photoluminescence under ultraviolet illumination. Radio-colouration and associated H3 photoluminescence are due to point defects created by the ions irradiated, whereas lattice ionisation is of minor importance. This is concluded from the depth distribution of the colouration and the photoluminescence intensity (which corresponds to the defect density but not the ionisation distribution pattern). The effect of the implanted He ions themselves on the colour and photoluminescence seems to be negligible, as radio-colouration and H3 emission were analogously produced through irradiation of diamond with C ions. The photoluminescence emission becomes observable at extremely low defect densities on the order of 10^?6 Å^?3 (or 0.000006 dpa) and is suppressed at moderate defect densities of ~5 × 10^?4 Å^?3 (or ~0.003 dpa). Intensely brown-coloured diamond hence does not show the H3 emission anymore. Anneals up to 1,600 °C has reduced considerably irradiation damage and radio-colouration, but the structural reconstitution of the diamond (and its de-colouration) was still incomplete.     

The relationship between fire behaviour measures and community loss: an exploratory analysis for developing a bushfire severity scale

Current fire danger scales do not adequately reflect the potential destructive force of a bushfire in Australia and, therefore, do not provide fire prone communities with an adequate warning for the potential loss of human life and property. To determine options for developing a bushfire severity scale based on community impact and whether a link exists between the energy release rate (power) of a fire and community loss, this paper reviewed observations of 79 wildfires (from 1939 to 2009) across Victoria and other southern states of Australia. A methodology for estimating fire power based on fuel loading, fire size and progression rate is presented. McArthur??s existing fire danger indices (FDIs) as well as fuel- and slope-adjusted FDIs were calculated using fire weather data. Analysis of possible relationships between fire power, FDIs, rate of spread and Byram??s fireline intensity and community loss was performed using exposure as a covariate. Preliminary results showed that a stronger relationship exists between community loss and the power of the fire than between loss and FDI, although fuel-adjusted FDI was also a good predictor of loss. The database developed for this study and the relationships established are essential for undertaking future studies that require observations of past fire behaviour and losses and also to form the basis of developing a new severity scale.     

Magmatic evolution of the Cadamosto Seamount,Cape Verde: beyond the spatial extent of EM1

The Cadamosto Seamount is an unusual volcanic centre from Cape Verde, characterised by dominantly evolved volcanics, in contrast to the typically mafic volcanic centres at Cape Verde that exhibit only minor volumes of evolved volcanics. The magmatic evolution of Cadamosto Seamount is investigated to quantify the role of magma-crust interaction and thus provide a perspective on evolved end-member volcanism of Cape Verde. The preservation of mantle source signatures by Nd–Pb isotopes despite extensive magmatic differentiation provides new insights into the spatial distribution of mantle heterogeneity in the Cape Verde archipelago. Magmatic differentiation from nephelinite to phonolite involves fractional crystallisation of clinopyroxene, titanite, apatite, biotite and feldspathoids, with extensive feldspathoid accumulation being recorded in some evolved samples. Clinopyroxene crystallisation pressures of 0.38–0.17 GPa for the nephelinites constrain this extensive fractional crystallisation to the oceanic lithosphere, where no crustal assimilants or rafts of subcontinental lithospheric mantle are available. In turn, magma-crust interaction has influenced the Sr, O and S isotopes of the groundmass and late crystallising feldspathoids, which formed at shallow crustal depths reflecting the availability of oceanic sediments and anhydrite precipitated in the ocean crust. The Nd–Pb isotopes have not been affected by these processes of magma-crust interaction and hence preserve the mantle source signature. The Cadamosto Seamount samples have high ²⁰⁶Pb/²⁰⁴Pb (>19.5), high εNd (+6 to +7) and negative Δ8/4Pb, showing affinity with the northern Cape Verde islands as opposed to the adjacent southern islands. Hence, the Cadamosto Seamount in the west is located spatially beyond the EM1-like component found further east. This heterogeneity is not encountered in the oceanic lithosphere beneath the Cadamosto Seamount despite greater extents of fractional crystallisation at oceanic lithospheric depths than the islands of Fogo and Santiago. Our data provide new evidence for the complex geometry of the chemically zoned Cape Verde mantle source.