The thermal signature of volcanic eruptions on Io and Earth

We investigate a spectrum-based technique to identify the style of active volcanic eruptions on Jupiter's moon Io. Thermal remote sensing of Io has had to rely primarily on low-spatial-resolution data, similar to low-spatial-resolution satellite data applied to detecting and charting the temporal evolution of terrestrial hot spots. These terrestrial analyses use data from sensors designed to monitor the weather and sea surface temperature. On Io, such low-spatial-resolution data are used to classify eruption styles (modes of emplacement) by means of several criteria related to the temporal evolution of the infrared spectrum associated with the eruptive activity at each hot spot, which we term “thermal signature.” We find that the ratio of the emission at 2 and 5 µm, and how this ratio changes with time, is often diagnostic of eruption style, even in low-spatial-resolution data. Tests using thermal data for terrestrial “ground truth” cases show that our classification system is valid on Earth. The results of our analysis can be used to aid in the design of future space-based instruments that can be used for volcano monitoring on Io, as well as Earth.     

An investigation of periglacial slope stability in relation to soil properties based on physical modelling in the geotechnical centrifuge

Results are presented from eight scaled centrifuge modelling experiments designed to investigate mass movement processes on thawing ice-rich slopes. Four pairs of simple planar slope models were constructed, one in each pair being of sufficient gradient to promote slope failure during soil thaw and the second having a gradient below the threshold for instability. Four frost susceptible soils were used, three were normally consolidated and had different clay contents (2%, 12% and 20%) and the fourth comprised the 20% clay soil, but was over consolidated prior to model testing. Modelling protocols included freezing from the surface downwards under an open hydraulic system, and thawing from the surface downwards under an enhanced gravitational field within the geotechnical centrifuge, thereby utilising scaling laws to simulate correct prototype self weight stresses during thaw. Slopes below the stability threshold gradient were subjected to between 2 and 4 cycles of freezing and thawing, simulating annual cycles. Those above the stability threshold were subjected to only one cycle, since they failed during the first thaw phase. Thermal conditions, pore water pressures, surface movements, and profiles of displacement are reported. Measured pore pressures are used in slope stability analyses based on a simple planar infinite slope model. Profiles of solifluction shear strain and mechanisms of slope failure are both shown to be sensitive to small changes in soil properties, particularly clay content and stress history. In all cases, pore pressures rose rapidly immediately following thaw, remained below the threshold for failure in low gradient models, but exceeding the threshold to trigger landslides on steeper slopes. Upward seepage of melt water away from the thaw front contributed to loss of shear strength. Mechanisms of slope failure differed between test soils, ranging from mudflow in non-cohesive silt to active layer detachment sliding in over consolidated silt–clay. During solifluction, shear strain was greatest at the surface in non-cohesive silt and decreased rapidly with depth, but in test soils containing clay, the zone of maximum shear strain was located lower in the displacement profiles.     

Diagenetic transformations and silcrete–calcrete intergrade duricrust formation in palaeo‐estuary sediments

The Boteti palaeo‐estuary in northern Botswana is located where the endoreic Boteti river, an overflow from the regional Okavango river system, enters the Makgadikgadi pans. The present work considers diagenetic silica and calcium carbonate dominated transformations. The aims are to help identify precursor conditions for the origin of microcrystalline silcrete–calcrete intergrade deposits while developing insight into pene‐contemporaneous silica and calcite matrix formation. General precursor conditions require the presence of cyclical endoreic freshwater inflow into a saline pan. The pan should be deep enough to sustain a permanent watertable under climatic conditions sufficient to cause carbonate fractionation within the groundwater. Freshwater inflow into a saline pan drives the geochemistry of the system (from freshwater to saline, from neutral to high pH). The geochemistry is controlled by the periodicity of inflow relative to salinity levels of phreatic groundwater in the receptor saline pan. The source of most silica and localized CaCO₃ is derived from the dissolution and precipitation of micro‐fossils, while more general CaCO₃ enrichment stems from saline pan based carbonate fractionation. Diagenetic change leads to colloidal then more consolidated bSiO₂/CaO aggregate formation (amorphous silica) followed by transformations into opaline silica over time. Irregular zones of siliceous sediment forming in otherwise calcareous deposits may relate to the irregular occurrence of biogenic silica in the source sediments, inferring a source for local silica mobilization in intergrade deposits. The distribution of calcareous micro‐fossils may have a similar converse effect. Diagenetic evidence from an intergrade deposit with a low SiO₂/CaO ratio suggests that transformation occurred more into the pan, while an intergrade deposit with a high SiO₂/CaO ratio more likely formed closer to a land margin and was frequently inundated by freshwater. Pene‐contemporaneous silcrete–calcrete intergrade formation under the above conditions may take place where dissolved silica crystallizes out in the vicinity of calcite crystals due to local decreases in pH. The continuing consolidation of bSiO₂/CaO aggregates may be facilitated by the presence of increasing amounts of calcite. It appears that CaCO₃ may act as a catalyst leading to pene‐contemporaneous bSiO₂/CaO aggregate formation. However the processes involved require further work. Copyright © 2013 John Wiley & Sons, Ltd.     

Quantification of the Mass Flux of H2O Gas (Steam) at Three Active Volcanoes Using Thermal Infrared Imagery

We apply a measurement technique that utilizes thermal video of vapor-dominated volcanic plumes to estimate the H₂O gas flux at three degassing volcanoes. Results are compared with H₂O flux measurements obtained using other methods to verify the thermal camera-derived values. Our estimation of the H₂O emission rate is based on the mass and energy conservation equations. H₂O flux is quantified by extracting the temperature and width of the gas plume from the thermal images, calculating the transit velocity of the gas plume from the thermal video, and combining these results with atmospheric parameters measured on-site. These data are then input into the equations for conservation of mass and energy. Selected volcanoes for this study were Villarrica in Chile, Stromboli in Italy, and Santa Ana in El Salvador. H₂O fluxes estimated from the thermal imagery were 38–250?kg?s^?1 at Villarrica, 4.5–14?kg?s^?1 for Stromboli’s Central Crater, and 168–219?kg?s^?1 at Santa Ana. These compare with H₂O flux values estimated by other methods of 73–220, 3–70 and 266?kg?s^?1, at the three volcanoes, respectively. The good agreement between thermal image-derived results and those estimated by other methods seem to validate this method.     

Climatic change in Western North America during the last 15,000 years: The role of changes in the relative strengths of air masses in producing the changing climates

In the Cordillera of western North America, the influence of the Pacific Interdecadal Oscillation only affects coastal areas west of the Coast Range and the lowlands of western and southern Alaska. The rest of the area is subject to a climate controlled by the relative strengths of three distinct air masses, viz., the cold cA/cP air that is dominant in winter, the mP air bringing cool moist air over the mountains throughout the year, and the dry hot cT air from the deserts of the southwestern United States. The Arctic Front marks the boundary between the cA/cP air mass and the other two. Changes in the relative strengths of these air masses appear to explain the climatic changes documented throughout the region. Thus, in the last 30 years, the average position of the Arctic Front has moved north from about 53°N to 58°N, causing the warming in northern British Columbia and cooling south of Calgary, Alberta. This concept of changing positions of the air masses also appears to explain the mechanism behind the past climatic changes in this region. During the last Neoglacial event （c.1400-1900 A.D.）, it appears that the cA/cP air mass had strengthened enough to push the Arctic Front south of the 49th parallel. Incursions of mP air increased with localized areas of short-term heavy snowfalls resulting in small-scale advances of glaciers in these regions. This accounts for the variability in timing and extent of these glacial advances, while the resulting increased Chinook activity produced the development of a sand sea between Medicine Hat and Regina on the southern Prairies. The cT air mass was relatively weak, permitting these changes. During the maximum of the Altithermal/Hysithermal warm event （6,000 years B.P.）, the Arctic Front had retreated into the southern Yukon Territory as the cT air mass became stronger. The mP air could not move inland as easily, resulting in drier climates across the region. Prairie plants mi- grated into the southern Yukon Territory, and land snails from the eastern United States were able to migrate up the Saskatchewan River system as far as Lake Louise, Alberta. On the southern Prairies, the many small sloughs and lakes dried up. During the maximum of the Late Wisconsin Glacial event （15,000 years B.P.）, the Arctic Front had moved south to the vicinity of 30°N, while there had been a southward movement of the Zone of Intertropical Convergence from the equator to about 10°S. The mP air was also very strong and dumped enormous quantities of snow in the glaciated Canadian Cordillera, but it does not appear to have moved south any distance into the northern United States, witness the limited glaciation and widespread permafrost that developed there. Instead, there is evidence for buffering of the climatic changes in the closed basins in the northern Cordillera of the contiguous United States. The source of the cT air mass had moved south into the northern part of South America, permitting an exchange of savannah biota between the two continents. An extensive area of white dune sands inundated both savannah and forest along the inland hills in Guyana. This parallels the massive changes in African climatology during the last Ice Age （Fairbridge, 1964）. If these changes occurred each time there was a major glaciation in the Northern Hemisphere, this would explain the movement of biota from all terrestrial environments between the two American continents in the last 2 million years. A similar northward movement of climatic belts occurred in South America, with the cA air from Antarctica expanding northwards into southern Argentina and Chili. However paucity of data and the potential effects of El Ni o and the Southern Oscillation make it difficult toprovide details of the changes there in the present state of knowledge. This technique of studying the mechanisms of present-day climatic changes and applying the results to past climatic events has considerable potential for elucidating past climatic changes elsewhere in continental regions. This may prove particularly valuable in studying the Siberian anticyclone that is the main cause of the distribution of permafrost, but this will need international cooperation to be successful.     

The stratigraphy,structure and regional significance of the Moine Rocks of Mull,Argyllshire, W. Scotland

Two right-way-up Moine lithostratigraphic units—the Shiaba (older) and Assapol (younger) Groups—are distinguished in the Ross of Mull. These were intruded in the west by the post-tectonic, Ross-of-Mull granite complex at 414 ± 3 Ma. Apparently undisturbed inclusions of Moine metasediments within the granite permit the boundary between the lithostratigraphic units to be followed westward almost to the supposed trace of the Moine thrust in the Sound of Iona. The Shiaba and Assapol Groups which have a transitional, albeit attenuated, stratigraphic contact are correlated with the Morar and Glenfinnan Divisions of Inverness-shire, the Sgurr Beag ductile thrust (slide) normally found at the Morar/Glenfinnan Division boundary being absent. This implies that the stratigraphic relationship between these two divisions, which is elsewhere obscured by the thrust, is uniquely preserved on Mull. Within a local, D1-D4 sequence, D2 and D3 structures are dominant. Originally subhorizontal D2 folds are intensely curvilinear on all scales about an originally flat-lying, NNW-SSE trending stretching lineation (L2). In sections parallel to L2, D2 minor folds display a constant sense of vergence throughout the Ross-of-Mull Moine Rocks, overturning generally NW-NNW. The present day structure is dominated by the almost upright, SSW-plunging D3 Assapol synform which overprints all earlier structures. Tentative correlation of the deformation sequence with that of Inverness-shire, suggests that the D1-D2 structures of Mull, with accompanying moderate-to-high-grade metamorphism, may be Precambrian, while the D3 Assapol synform may be Caledonian. The presence of migmatites of kyanite grade means that metamorphic grade, established during MS1-MP2, is anomalously high for Moine rocks lying close to the supposed Caldonian front. This suggests that they may lie within one of the higher Caledonian thrust nappes of the North Highland Moine—possibly the Knoydart nappe, where metamorphic grade is comparable. The greenschist facies metamorphism and single phase of deformation affecting the ‘Torridonian’ rocks of Iona presents a significant contrast to the Moine rocks of the Ross of Mull. A major fault in the Sound of Iona is implied, but the Moine thrust itself probably does not outcrop.     

Hapke mixture modeling applied to VNIR spectra of mafic mineral mixtures and shergottites: Implications for quantitative analysis of satellite data

The mineralogy of Mars is well understood on a qualitative level at a global scale due to satellite data. Quantitative analysis of visible and near-infrared (VNIR) satellite data is a desirable but nontrivial task, due partly to the nonlinearity of VNIR reflectance spectra from the mineral mixtures of the Martian surface. In this study, we investigated the use of the Hapke radiative transfer model to generate linearly mixed single scattering albedo data from nonlinearly mixed VNIR reflectance data and then quantitatively analyzed them using the linear spectral mixture model. Simplifications to the Hapke equation were tested accounting for variables that would be unknown when using satellite data. Mineral mixture spectra from the RELAB spectral library were degraded to test the robustness of the unmixing technique in the face of data that mimic some of the complexities of satellite spectral data collected at Mars. A final test was performed on spectra from shergottite meteorites to assess the technique against real Martian mineral mixtures. The simplified Hapke routine produced robust abundance estimates within 5–10% accuracy when applied to laboratory standard spectra from the synthetic mixtures of igneous minerals in agreement with previous studies. The results of tests involving degraded data to mimic the low spectral contrast of the Martian surface and the lack of a priori knowledge of the constituent mineral spectral endmembers, however, were less encouraging, with errors in abundance estimation greater than 25%. These results cast doubt on the utility of Hapke unmixing for the quantitative analysis of VNIR data of the surface of Mars.     

Burial-dominated cementation in non-tropical carbonates of the Oligocene Te Kuiti Group, New Zealand

Cementation of bryozoan-echinoid-benthic foraminiferal temperate shelf carbonates of the Oligocene Te Kuiti Group, North Island, New Zealand, occurred mainly during subsurface burial. The calcite cements in the limestones are dominated by equant and syntaxial rim spar which typically becomes ferroan (given an iron supply) and, compared to the skeletal material with normal marine δ¹⁸O values from +2 to −1‰, more depleted in ¹⁸O with depth of burial, the δ¹⁸O composition of bulk cement samples ranging from −1 to −7‰. These trends reflect the establishment in pore waters during sediment burial of reducing conditions and gradually increasing temperatures (20–50°C), respectively. The δ¹³C values (0 to +3‰) of the cements remain the same as the host marine shells, suggesting the source of carbon in the cements was simply redistributed marine carbonate derived from shell dissolution.

Two gradational burial diagenetic environments influenced by marine-derived porewaters are arbitrarily distinguished: shallow burial phase and moderate burial phase. During the shallow burial phase, down to 500–600 m sub-bottom depth, the carbonates lost at least 25% of their original porosity by mechanical compaction and were selectively cemented by non-ferroan or usually ferroan, variably luminescent, slightly ¹⁸O-depleted sparry calcite cement (δ¹⁸O −2 to −4‰), mainly as syntaxial rims about echinoid grains. These shallow-burial cements form less than about 10% of total cement in the majority of the limestones and their source was probably mainly mild intergranular dissolution of calcitic skeletal fragments accompanying the onset of chemical compaction. During the moderate burial phase, between about 600 and 1100 m sub-bottom depth, porosity loss continued (typically to about 70% of its original value) as a result of pressure-solution of calcitic bioclasts associated with more advanced stages of chemical compaction. This involved development of a wide variety of non-sutured and microstylolitic solution seams, including both single and composite, wispy or continuous, bedding-parallel types and non-parallel reticulate forms. The released carbonate was precipitated as ferroan (or non-ferroan where iron supply was negligible), dull luminescent, strongly ¹⁸O-depleted (δ¹⁸O −4 to −7‰), mainly equant calcite spar cement, occluding available pore space in the limestones.