Cell-zonal textures of tinguaites from the Kola Peninsula

Textures of tinguaite dykes cutting the alkaline Khibiny massif in the Kola Peninsula, Russia, are described. They are characterized by a combination of a fractal microfracture network dividing rock into pencil-like cells and of a concentric rhythmical zonation in almost all of them. The latter is formed by interchange of volatile-enriched and volatile-depleted mineral zones. The location of the textures only where dykes contact host khibinites appears to point out the contraction nature of the microfracture network. The cooling time calculated agrees well with this hypothesis. The zonation appears to have arisen through autometamorphic processes with two main competing factors, namely (a) overall cooling of the system and (b) periodic depletion of it in some elements, mainly Na and K. Another mechanism which may be applied to explain the zonation is the known Marangoni Instability effect at the early stage of evolution of the volatile-saturated phonolite melt. Thus, tinguaite textures are caused by nonspecific influences external to the system and may be regarded as an example of self-organization in nature.     

Comparison of source rock geochemistry of selected rocks from the Schei Point group and Ringnes formation, Sverdrup basin, arctic Canada

Organic-rich from the Schei Point group (middle to late Triassic in age) and the Ringnes formation (late Jurassic) from the Sverdrup basin of the Canadian arctic archipelago have been geochemically evaluated for source rock characterization. Most samples from the Schei Point group are organic-rich (> 2% TOC and are considered as immature to mature oil-prone source rocks [kerogen types I, I–II (IIA) and II (IIA)]. These kerogen types contain abundant AOM1, AOM2 and alginite (Tasmanales, Nostocopsis, Leiosphaeridia, acritarch and dinoflagellate) with variable amounts of vitrinite, inertinite and exinite. Samples from the Ringnes formation contain dominant vitrinite and inertinite with partially oxidized AOM2, alginite and exinite forming mostly immature to mature condensate- and gas-prone source rocks [kerogen type II–III (IIB), III and a few II (IIA)]. Schei Point samples contain higher bitumen extract, saturate hydrocarbons and saturate/ aromatic ratio than the Ringnes samples. Triterpane and sterane (dominant C₃₀) distribution patterns and stable carbon isotope of bitumen and kerogen suggest that the analyzed samples from the Schei Point group are at the onset of oil generation and contain a mixture of sapropelic (algal) and minor terrestrial humic organic matter. Sterane carbon number distributions in the Ringnes formation also suggest a mixed algal and terrestrial organic matter type. There are some variations in hopane carbon number distributions, but these are apparently a function of thermal maturity rather than significant genetic differences among samples. Pyrolysis-gas chromatography/mass spectrometry of the two samples with similar maturity shows that the Schei Point sample generates three times more pyrolyzate than the Ringnes sample. Both samples have a dominant aliphatic character, although the Ringnes sample contains phenol and an aromaticity that is higher than that of the Schei Point sample.     

200 years of mining activities at La Paz/San Luis Potosí/Mexico - Consequences for environment and geochemical exploration

The Ag---Pb---Zn---Cu---Au mining district of Santa María de La Paz has been extensively exploited for approximately 200 years. Consequences of these activities are several deposits of tailings with high As and heavy metal concentrations, which are completely unstable. The climate is semiarid and as the dumps have no protective cover, material from the dumps is dispersed by strong winds. It is also washed out during seasonally heavy rainfalls. By these processes approximately 100 km² of surrounding have been contaminated by dump material. The As and heavy metal content of the soils was determined as well as their level in crops (Zea Maize) from agricultural lands in the vicinity of the dumps. In the direction of prevailing winds concentrations up to 1000 ppm Zn, 400 ppm Pb, 16 ppm Cd, 550 ppm Cu and 300 As have been detected in top soils. Using fuzzy cluster analysis the different contamination sources could be identified. Grains of corn from contaminated sites showed no critical concentrations, but leaves which are also used tor fodder, have As-concentrations up to 20 ppm.     

High-pressure metallization and electronic-magnetic propertiesof hexagonal cubanite (CuFe2S3)

^?57Fe Mössbauer studies at room temperature and temperature-dependent resistance studies have been performed on a natural specimen of cubanite (CuFe₂S₃) in a diamond-anvil cell at pressures up to ～10 GPa. An insulator-metal phase transition occurs in the range 3.4–5.8 GPa coinciding with a previously observed structural transition from an orthorhombic to a hexagonal NiAs (B8) structure. The room temperature data shows that the metallization process concurs with a gradual transition from a magnetically ordered phase at low pressure to a nonmagnetic or paramagnetic phase at high-pressure. The change in magnetic behaviour at the structural transition may be attributed to a reduction of the Fe-S-Fe superexchange angle formed by edge-sharing octahedra occurring in the high-pressure phase. The non-magnetic or paramagnetic metallic phase at high pressure is retained upon decompression to ambient pressure-temperature conditions, indicative of substantial hysteresis associated with the pressure driven orthorhombic→hexagonal structural transition. The pressure evolution of both the ⁵⁷Fe Mössbauer hyperfine interaction parameters and resistance behaviour is consistent with the transition from mixed-valence character in the low pressure orthorhombic structure to that of extended-electron delocalization in the hexagonal phase at high-pressure.     

Past imperfect, future tense: Archaeology and development

Archaeological sites are valuable nonrenewable resources and they are being destroyed rapidly by modern development projects of all kinds, worldwide. The contextual information in these sites could tell surprising and valuable stories of human behavior over an enormous sweep of time and might contribute to a better future. Archaeologists’ experience of site destruction and their recent efforts to work with local communities toward alternatives to site destruction may offer examples for others concerned with the treatment of nonrenewable resources     

A record of accelerated erosion in the recent sediments of Blelham Tarn in the English Lake district

Two frozen cores from Blelham Tarn were subsampled and measured using mineral magnetic, loss-on-ignition (LOI), radiometric, granulometric and diatom analyses. A detailed chronology was established using varves, radioisotopes and diatoms. This has enabled an accurately dated reconstruction of sedimentation over the past forty years. Despite a large increase in lake productivity, evidence suggests that the observed exponential increase in sedimentation rates can be attributed to erosion within the catchment. The predominant sediment source has been identified as surface soil. A comparison between the trend of accelerated sedimentation and the record of increased sheep stocking density for the area within which the most of the catchment lies, as well as observations of contemporary surface processes within the catchment, both suggest that much of the recent erosion is a direct response to increased pressure from sheep grazing.     

Neural dynamic modelling on earthquake magnitude series

Earthquake magnitude prediction is of vital importance for human safety. The earthquake is a very complicated and non-linear dynamic process. It cannot be described adequately by any deterministic models. In this paper a neural dynamic modelling for earthquake magnitude prediction is reported. Historical records of earthquake magnitude series are used to construct the optimal non-linear dynamic model, and the consequent outcome of the earthquake behaviour is then predicted by this model. In turn, the latest recorded data set can be fed back to improve the accuracy of the neural dynamic model. The modelling of experiments of three earthquake magnitude series in China and Japan and their extrapolated predictions are included in this paper. The values predicted by extrapolation are in good agreement with the historical data.     

New palaeogeographic and lake-level reconstructions of Lake Tanganyika: implications for tectonic, climatic and biological evolution in a rift lake

Palaeogeographic and lake-level reconstructions provide powerful tools for evaluating competing scenarios of biotic, climatic and geological evolution within a lake basin. Here we present new reconstructions for the northern Lake Tanganyika subbasins, based on reflection seismic, core and outcrop data. Reflection seismic radiocarbon method (RSRM) age estimates provide a chronological model for these reconstructions, against which yet to be obtained age dates based on core samples can be compared. A complex history of hydrological connections and changes in shoreline configuration in northern Lake Tanganyika has resulted from a combination of volcanic doming, border fault evolution and climatically induced lake-level fluctuations. The stratigraphic expression of lake-level highstands and lowstands in Lake Tanganyika is predictable and cyclic (referred to here as Capart Cycles), but in a pattern that differs profoundly from the classic Van Houten cycles of some Newark Supergroup rift basins. This difference results from the extraordinary topographic relief of the Western Rift lakes, coupled with the rapidity of large-scale lake-level fluctuations. Major unconformity surfaces associated with Lake Tanganyika lowstands may have corresponded with high-latitude glacial maxima throughout much of the mid- to late Pleistocene.
Rocky shorelines along the eastern side of the present-day Ubwari Peninsula (Zaire) appear to have had a much more continuous existence as littoral rock habitats than similar areas along the north-western coastline of the lake (adjacent to the Uvira Border Fault System), which in turn are older than the rocky shorelines of the north-east coast of Burundi. This model of palaeogeographic history will be of great help to biologists trying to clarify the evolution of endemic invertebrates and fish in the northern basin of Lake Tanganyika.