O-Sr isotopic variations in Miocene granitoids from the Aegean: evidence for an origin by combined assimilation and fractional crystallization

Sr, O, and D/H isotopic compositions have been analyzed in Miocene metaluminous to slightly peraluminous (I-type) granitoids of the central Aegean. Individual plutonic complexes display significant variations in their ¹⁸O and initial⁸⁷Sr/⁸⁶Sr compositions.D and ¹⁸O compositions of minerals and whole-rocks are mostly in the magmatic range. Some samples from Naxos and Mykonos/Delos show low D and ¹⁸O values characteristic of meteoric-water-hydrothermal interaction, but as a whole the changes in ¹⁸O and Sr isotopic compositions as a result of hydrothermal alteration were slight, even in instances where marked alteration is petrographically observable. Consequently, the bulk-rock variations of ¹⁸O from 8.1 to 12.0 and of⁸⁷Sr/⁸⁶Sr from 0.70438 to 0.71450 may be regarded as primary and indicative of the conditions of their evolution. Heterogeneous isotopic compositions observed in the individual plutons of Serifos, Ikaria, Samos and Kos may be caused by the multiple intrusion of chemically and isotopically distinct magma pulses, with high viscosities and relatively rapid consolidation in most cases preventing complete homogenization. The granitoids of Serifos, Ikaria and Kos display weak correlations between the initial⁸⁷Sr/⁸⁶Sr and ¹⁸O and 1/Sr. The granitoid province shows a positive correlation between⁸⁷Sr/⁸⁶Sr and ¹⁸O and a non-linear relationship between⁸⁷Sr/⁸⁶Sr and 1/Sr, whereby 1/Sr increases more rapidly than the isotopic ratio as the degree of fractionation of the rocks increases. It is argued that assimilation of older continental material by mantle-derived arc magmas with combined fractionation (AFC) is the most plausible model to explain the chemical and isotopic characteristics of the granitoids and the geological situation in which rock-types trend from granodiorites in the (south)west, near the inferred Oligocene-Miocene suture, to granites in the center and monzonites in the (north)east of the province.     

A study of wind speed modification and internal boundary-layer heights in a coastal region

Wind profile data within the first two kilometres of a coast have been used to study the wind field modification downstream of this surface discontinuity. The land area is generally very flat, having an overall roughness length of 0.04 m. A wind model, suitable for practical applications and inexpensive to run, has been tested against the data and was found to give satisfactory results. Knowing the climatological statistics of wind and stratification, e.g., at the coast, the model may thus be used to estimate, on a climatological basis, how the wind field is modified with distance inland, at least in areas with only minor topography. This type of information is of great importance when locating wind turbines. It is in these cases also important to know the statistics of the internal boundary-layer (IBL) height, as the turbulence intensity may be quite different in and above the IBL, which in turn may influence load and fatigue calculations. Using the wind profile data, the IBL height was clearly discernible in the majority of cases. Having very unstable stratification over land, the IBL height could, however, not be determined from the wind profiles, as the wind in these cases did not decrease inland. This result was also obtained using the wind model. A simple model of the type z _IBL = a · x ^b, was instead tested, and was shown to give reasonable results.     

Reduction of geomagnetic measurements at sea in the vicinity of the geomagnetic equator

Summary On the dayside of the Earth, a huge current system, the so-called equatorial electrojet, flows along the magnetic dip equator in the ionosphere, mainly in easterly direction. At the surface of the Earth it generates strong variations of the geomagnetic field which severely impair marine geomagnetic measurements. Independent of its changing intensity, the position of the current system is remarkably constant.For marine geomagnetic measurements in the South China Sea and the Sulu Sea the latitude dependence of the variations was determined from the data themselves, using an appropriate functional relation. By a digital filter it was taken into consideration that the slowly changing parts are less latitude-dependent. Thus, with one recording station, it was possible to reduce the variations to only 15% of their original size for distances up to 500 km.Using the comprehensive data set of two research cruises into the Dangerous Grounds area of the South China Sea, it is shown which statements on the structure of the crust are possible with the corrected data.

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Die Reduktion erdmagnetischer Messungen auf See in der Nähe des magnetischen Äquators

Zusammenfassung Entlang des magnetischen Inklinations-Äquators fließt auf der Tagseite der Erde in der Ionosphäre ein riesiges Stromsystem, der sogenannte Äquatoriale Elektroje. Es erzeugt an der Erdoberfläche starke zeitliche Veränderungen des erdmagnetischen Feldes, die seemagnetische Vermessungen erheblich beeinträchtigen. Die Lage des Stromsystems ist auch bei wechselnden Stromstärken bemerkenswert konstant. Für seemagnetische Messungen im Südchinesischen Meer wurde die Breitenabhängigkeit der Variationen unter Benutzung eines geeigneten Funktionsansatzes aus den Daten selbst bestimmt. Durch eine Filterung wurde berücksichtigt, daß langsam veränderliche Anteile weniger stark breitenabhängig sind. Dadurch gelang es, die Variationen unter Benutzung einer einzigen Registrierstation in Entfernungen bis 500 km auf nur 15% zu reduzieren.An Hand des umfangreichen Meßdatensatzes zweier Forschungsfahrten in das Gebiet der Dangerous Grounds im Südchinesischen Meer wird gezeigt, welche geowissenschaftlichen Aussagen über den Aufbau der Erdkruste nach der Verbesserung möglich werden.

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Réduction des mesures de magnétisme à la mer effectuées au voisinage de l'équateur géomagnétique

Résumé Du côté jour de la terre, un flux plasmatique puissant appelé électrojet équatorial s'écoule le long de l'équateur magnétique (champ total et composante horizontale identiques) dans l'ionosphère, principalement en direction de l'Est. Ce flux engendre à la surface du globe de fortes variations du champ géomagnétique, qui ont pour effet de perturber sévèrement les mesures de magnétisme à la mer. La position de ce courant est d'une constance remarquable, et indépendante de ses variations d'intensité.Pour les mesures de magnétisme effectuées dans les mers de Chine Sud et de Sulu, les variations en fonction de la latitude ont été déterminées à partir des données elles-mêmes, au moyen de relations fonctionelles appropriées. L'emploi d'un filtre digital a permis de tenir compte du fait que les éléments variables lentement sont moins dépendants de la latitude. C'est ainsi qu'avec une station d'enregistrement, il a été possible de réduire les variations à 15% seulement de leur valeur originale jusqu'à des distances de 500 km.En s'appuyant sur la collection très complète de données recueillies au cours de deux campagnes de recherche effectuées dans la zone des Hauts-fonds dangereux, au Sud de la mer de Chine, on montre les hypothèses qu'il est possible de formuler quant à la structure de la croûte, à partir des données corrigées.

     

Factors governing the growth rate of roachRutilus rutilus (L.) in pre-alpine Lake Sarnen

Most of the mesotrophic to eutrophic lakes in central Europe have been showing signs of oligotrophication during recent years. The question as to how the fish populations would react to this new situation was investigated looking at the growth rate of roachRutilus rutilus (L.) of Lake Sarnen, central Switzerland. The water temperature sum as day-degrees over 12 to 13°C for the months of June to October was found to be the predominant factor governing the marked year-to-year fluctuations of the growth rate. Contrary to expectation, the decreasing trophic state of the lake has not yet manifested itself noticeably in the growth rate.     

Ellenbergerite,a new high-pressure Mg-Al-(Ti,Zr)-silicate with a novel structure based on face-sharing octahedra

Ellenbergerite occurs as purple millimetre-size grains associated with talc, kyanite, clinochlore, rutile, and zircon in composite inclusions within decimetre-large pyrope crystals (90–98 mole percent end-member) in the quartzite layer of the Dora Maira massif, Western Alps, from which coesite has been recently reported (Chopin 1984). It is hexagonal, a=12.255(8), c=4.932(4) Å, Z=1, space group P6₃. Mohs hardness 6.5; D_mes 3.15, D_cal 3.10; no cleavage. Uniaxial negative and vividly pleochroic, colourless, colourless to deep lilac with colour zoning. The intensely coloured variety has 1.6789(5), 1.670(1); microprobe analysis yields SiO₂ 39.1, P₂O₅ 0.45, Al₂O₃ 25.1, TiO₂ 4.0, MgO 22.2, FeO 0.20, sum 99.05 wt.% including H₂O 8.0 (coulometrically). The formula calculated on a O₂₈(OH)₁₀ basis (implying 7.5 wt.% H₂O) is Mg_6.71 Fe_0.03 Ti_0.61 Al_6.00 Si_7.92 P_0.08 O₂₈(OH)₁₀ The colour zoning is due to nearly complete TiZr substitution. In addition ellenbergerite may contain more than 8 wt.% P₂O₅ with strictly correlated changes of Si, Mg, Al and Ti+Zr contents, over 80% of which represent the SiAlPMg substitution.The structure has been determined from 1049 observed independent reflections and refined to R=0.034, R_w=0.031, including six of ten protons. It consists of single chains of face-sharing octahedra with one third vacancies extending along the six-fold screw axes, and of pairs of fully occupied face-sharing octahedra linked by edge-sharing to form octahedral double chains parallel to the twofold screw axes, all interconnected by SiO₄ tetrahedra. It may be compared with the dumortierite polymorph with space group P6₃mc derived hypothetically by Moore and Araki (1978). The structural formula is (Mg,Ti,Zr,)₂ Mg₆(Al,Mg)₆ (Si,P)₂ Si₆ O₂₈(OH)₁₀ Face-sharing octahedra are an unusual feature in silicates which results in a dense structure and reflects, considering the common bulk composition, the uncommon high-pressure formation conditions (about 25–30 kbar, 700–800° C). Ti⁴⁺-Fe²⁺ charge transfer between face-sharing octahedra on the six-fold screw axes most likely accounts for the absorption scheme.     

Residence of silver in mineral deposits of the Thunder Mountain caldera complex,Central Idaho,U.S.A.

Summary Silver is an accessory element in gold, antimony, and tungsten deposits of the caldera complex. Most of the deposits are economically of low grade and genetically of xenothermal or epithermal character. Their gold- and silver-bearing minerals are usually disseminated, fine grained, and difficult to study. Sparsely disseminated pyrite and arsenoprite are common associates.Identified silver minerals are: native silver and electrum; the sulfides acanthite, argentite (the latter always inverted to acanthite), and members of the Silberkies group; the sulfosalts matildite, miargyrite, pyrargyrite, argentian tetrahedrite, and unnamed Ag-Sb-S and Ag-Fe-Sb-S minerals; the telluride hessite and the selenide naumannite; halides of the cerargyrite group; and the antimonate stetefeldtite. Suspected silver minerals include the sulfide uytenbogaardtite and the sulfosalts andorite, diaphorite, and polybasite. Electrum, acanthite, and argentian tetrahedrite are common, though nowhere abundant. The other silver minerals are rare.Silver is present as a minor element in the structure of some varieties of other minerals. These include arsenopyrite, chalcopyrite, chalcostibite, covelline, digenite, galena, sphalerite, and stibnite. The search for adventitious Ag in most of these minerals has been cursory. The results merely indicate that elemental silver is not confined to discrete silver minerals and is, therefore, an additional complication for the recovery of silver-bearing material from some deposits.Silver occurs cryptically in some plants of the region. At Red Mountain, for example, the ashed sapwood of Douglas-fir (Pseudotsuga menziesii) contains 2 to 300 ppm Ag. Silver in the ashed wood is roughly 100 times as abundant as it is in soil. The phenomenon, useful in biogeochemical exploration, deserves the attention of mineralogists.

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Das Vorkommen von Silber in den Erzlagerstätten des Thunder-Mountain-Caldera-Komplexes, Idaho, U.S.A.

Zusammenfassung Silber ist in den Gold-, Antimon- und Wolframlagerstätten des Caldera-Komplexes ein akzessorisches Element. Die Lagerstätten sind wirtschaftlich geringhaltig und genetisch als xeno- oder epithermal zu deuten. Gold- und silberführende Minerale sind meist feinkörnig und treten akzessorisch auf. Im einzelnen wurden folgende Minerale beobachtet: Gediegen Silber und Elektrum; die Sulfide Akanthit und Argentit (immer zu Akanthit umgewandelt) sowie Silberkiese; die Sulfosalze Matildit, Miargyrit, Pyrargyrit, silberhaltiger Tetraedrit und nicht näher identifizierte Ag-Sb-S- und Ag-FeSb-S-Verbindungen; das Tellurid Hessit und das Selenid Naumannit; Halogenide der Kerargyritgruppe; und das Antimonat Stetefeldit. Mögliche weitere Ag-Minerale schließen das Sulfid Uytenbogaardtit und die Sulfosalze Andorit, Diaphorit und Polybasit ein. Von diesen Mineralen kommen Elektrum, Akanthit und silberhaltiger Tetraedrit am häufigsten vor, während alle anderen selten sind. Die gewöhnlichen Nebengemengteile sind Pyrit und Arsenkies.Darüber hinaus wird vermutet, daß Spuren von Silber im Kristallgitter anderer Minerale eingebaut vorliegen; insbesondere in den Gittern von Arsenkies, Kupferkies, Chalcostibit, Covellin, Digenit, Bleiglanz, Zinkblende und Antimonit. Hierzu liegen noch keine umfassenden Untersuchungen vor, jedoch kann vermutet werden, daß Silber nicht ausschließlich auf Ag-Minerale sensu stricto beschränkt ist.Einige Pflanzen des Lagerstättenbezirkes enthalten beachtliche Mengen an Silber, so zum Beispiel die Asche der Douglas-FichtePseudotsuga menziesii. Der Silbergehalt beträgt 2 bis 300 g/t und ist damit gegenüber dem Boden etwa 100fach erhöht. Dieses Phänomen ist von Nutzen in der biogeochemischen Exploration und verdient das Interesse der Mineralogen.

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With 10 Figures

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Contribution to the Ore Mineralogy Symposium (IMA/COM) at the 14th General Meeting of the International Mineralogical Association, at Stanford, California, in July, 1986.     

Medium-scale maps after survey from space—The “Metric-Camera”—Experiment

Airphotos have been used for topographic survey since the Twenties. The “European Space Agency” (ESA), the “Deutsche Forschungs- und Versuchsanstalt für Luft- und Raumfahrt” (DFVLR) and “Carl Zeiss” have modified this successful technique for spacecraft and recently have tested the system over four continents. Each of these satellite photos covers a region of 189×189 km to the scale of 1∶800000 and may be enlarged to 1∶250000 or 1∶100000. Between the altitudes of 200 and 300 km, mapmaking or-revision seems to be economic in zones or in countries, where existing maps are of minor quality or outdated. In this paper, examples from deserts and semideserts in the Sudan are presented.     

Riyadh and its development

After World War II Saudi Arabia has experienced spectacular changes. Based on huge oil and gas revenues a particularly rapid growth of population and a spectacular urbanization took place. One of the most booming cities in the desert environment of the arabian peninsula is the Kingdoms capital city of Riyadh. With a built-up area of 3.5 km² only before 1950 the city's present-day expansion reaches more than 500 km². During the same period of time the population of Riyadh grew from less than 50,000 in 1945 to more than 1.4 Mio. in 1985. Such an explosive development can be documented best by a satellite image. In this paper the process of urbanization of Riyadh is presented by the interpretation of a MOMS image taken in 1984, documenting the geographic situation, urban structures, and the city's development.     

Turbulent exchange above a pine forest,I: Fluxes and gradients

Measurements of gradients of wind, temperature and humidity and of the corresponding turbulent fluxes have been carried out over a sparse pine forest at Jädra»s in Sweden. In order to ascertain that correct gradient estimates were obtained, two independent measuring systems were employed: one system with sensors at 10 fixed levels on a 51 m tower and another with reversing sensors for temperature and humidity, covering the height interval 23 to 32 m. Turbulent fluxes were measured at three levels simultaneously. Data from three field campaigns: in June 1985, June 1987 and September 1987 have been analyzed. The momentum flux is found on the average to be virtually constant from tree top level, at 20 to 50 m. The average fluxes of sensible and latent heat are not so well behaved. The ratio of the non-dimensional gradients of wind and temperature to their corresponding values under ideal conditions (low vegetation) are both found to be small immediately above the canopy (about 0.3 for temperature and 0.4 for wind). With increasing height, the ratios increase, but the values vary substantially with wind direction. The ratios are not found to vary systematically with stability (unstable stratification only studied). The ratio of the non-dimensional humidity gradient to the corresponding non-dimensional potential temperature gradient (equivalent to k _h /k _w ) is found to be unity for (z – d)/L _v less than about –0.1 and about 1.4 for near neutral stratification, but the scatter of the data is very large.     

Content of radio caesium in the water of the Northern North Atlantic during the year 1985

The relative great number of data of the radio caesium activity concentrations in the water of the northern North Atlantic gained in 1985 from a station network between 60°N to 80°N and 16°W to 22°E provides a good basis for a fairly realistic calculation of the inventory of radio caesium in this region. In the area taken into account for the calculation, between 60°N to 80°N and 20°W to 22°E, an inventory of about 11000 TB_q (including background activity from fallout) has been found. That corresponds to about 40% of the caesium 137 released by the Scllafield Works between 1958 and 1980 and La Hague between 1966 and 1980, decay corrected to 1985.