The eddy-covariance method is the state-of-the-art tool to measure mass and energy fluxes, though many measuring systems (particularly
closed-path systems) show strong spectral attenuation that causes significant underestimates of actual mass fluxes. The standard
way to correct these underestimates is to use theoretically derived transfer functions. Practical implementation has shown
that the attenuation, especially of closed-path systems, is underestimated by this method, even when the additional tube damping
is considered. This paper introduces and tests three alternative site-specific and hardware specific correction methods based
on spectral analysis, which typically enhance—additionally to the classical correction—the calculated mass fluxes based on
closed-path analysers, as their inevitable tubing and the filters used cause additional flow attenuation. Two of the three
methods are based on a site-specific and hardware specific transfer functions, the third uses direct comparison of cospectra.
Primarily the methods based on transfer functions proved to be easy-to-handle once established for the specific set-up and
measurement site. They represent practical and robust methods to correct for spectral attenuation. 相似文献
In the last years more and more often detections of antimicrobially active compounds (“antibiotics”) in surface waters have been reported. As a possible input pathway in most cases municipal sewage has been discussed. But as an input from the realm of agriculture is conceivable as well, in this study it should be investigated if an input can occur via the pathway application of liquid manure on fields with the subsequent mechanisms surface run‐off/interflow, leaching, and drift. For this purpose a series of surface waters, soils, and liquid manures from North Rhine‐Westphalia (Northwestern Germany) were sampled and analyzed for up to 29 compounds by HPLC‐MS/MS. In each of the surface waters antibiotics could be detected. The highest concentrations were found in samples from spring (300 ng/L of erythromycin). Some of the substances detected (e.g., tylosin), as well as characteristics in the landscape suggest an input from agriculture in some particular cases. In the investigation of different liquid manure samples by a fast immunoassay method sulfadimidine could be detected in the range of 1…2 mg/kg. Soil that had been fertilized with this liquid manure showed a content of sulfadimidine extractable by accelerated solvent extraction (ASE) of 15 μg/kg dry weight even 7 months after the application. This indicates the high stability of some antibiotics in manure and soil. 相似文献
The transfer of fatty acids (FAs) in the food web of a Mediterranean lagoon was studied using FA compositional patterns across several trophic levels. The structure of the food web was inferred from C and N stable isotopes values and an isotope mixing model was used in order to estimate the relative contribution of the different potential food sources to the biomass of consumers. Bidimensional plots of FA composition of food web components against their δ15N values indicated a general trend of increasing proportions of highly unsaturated fatty acids (HUFAs) with increasing trophic levels while the proportions of saturated fatty acids (SAFAs) and 18-carbon polyunsaturated fatty acids (PUFAs) decreased. Using the relative contributions of food sources to consumers and their FA compositions, a model was built in order to estimate the PUFA composition of consumer mixed diets which was compared to consumer PUFA profiles. The latter allowed the identification of the PUFAs which were mostly enriched/retained in consumer lipids. There was a surprisingly high retention of arachidonic acid (ARA), a trend which challenges the idea of low ARA needs in marine fish and suggests the important physiological role of this essential FA for fish in estuarine environments. 相似文献
Hf‐isotope data of >1100 detrital zircon grains from the Palaeozoic, south‐central Andean Gondwana margin record the complete crustal evolution of South America, which was the predominant source. The oldest grains, with crustal residence ages of 3.8–4.0 Ga, are consistent with complete recycling of existing continental crust around 4 Ga. We confirm three major Archaean, Palaeoproterozoic (Transamazonian) and late Mesoproterozoic to early Neoproterozoic crust‐addition phases as well as six igneous phases during Proterozoic to Palaeozoic time involving mixing of juvenile and crustally reworked material. A late Mesoproterozoic to early Neoproterozoic, Grenville‐age igneous belt can be postulated along the palaeo‐margin of South America. This belt was the basement for later magmatic arcs and accreted allochthonous microcontinents as recorded by similar crustal residence ages. Crustal reworking likely dominated over juvenile addition during the Palaeozoic era, and Proterozoic and Archaean zircon was mainly crustally reworked from the eroding, thickened Ordovician Famatinian arc. 相似文献
Throughout the last 1.1 million years repeated glaciations have modified the southern Fennoscandian landscape and the neighbouring continental shelf into their present form. The glacigenic erosion products derived from the Fennoscandian landmasses were transported to the northern North Sea and the SE Nordic Seas continental margin. The prominent sub‐marine Norwegian Channel trough, along the south coast of Norway, was the main transport route for the erosion products between 1.1 and 0.0 Ma. Most of these erosion products were deposited in the North Sea Fan, which reaches a maximum thickness of 1500 m and has nearly 40 000 km3 of sediments. About 90% of the North Sea Fan sediments have been deposited during the last 500 000 years, in a time period when fast‐moving ice streams occupied the Norwegian Channel during each glacial stage. Back‐stripping the sediment volumes in the northern North Sea and SE Nordic Seas sink areas, including the North Sea Fan, to their assumed Fennoscandian source area gives an average vertical erosion of 164 m for the 1.1–0.0 Ma time period. The average 1.1–0.0 Ma erosion rate in the Fennoscandian source area is estimated to be 0.15 mm a?1. We suggest, however, that large variations in erosion rates have existed through time and that the most intense Fennoscandian landscape denudation occurred during the time period of repeated shelf edge ice advances, namely from Marine Isotope Stage 12 (c. 0.5 Ma) onwards. 相似文献
Long-term exploitation schemes in many regions are often based solely on hydrodynamic factors, while the agricultural use of groundwater undergoes significant changes over time. The Bouhefna-Haffouz aquifer system in central Tunisia is one of those cases where an aquifer exploitation scheme was well designed hydrodynamically to address the political needs at the time. Fifty years later, a numerical groundwater model has been conducted to assess the sustainability of the scheme. Results show that the scheme aimed to lower the groundwater level to reduce overflow to Merguellil Wadi and maintain it at a level that benefits agricultural profitability. This caused loss of the Merguellil baseflow, forcing farmers to switch from traditional irrigation canals to deep wells and motor pumps, thereby disrupting the hydrological budget even further. The numerical model indicates that the flow to the wadi reached zero in 1978, the average flow by vertical leakage decreased from 8 hm3 in 1970 to 2 hm3 in 2020, and the horizontal percolation between the regional aquifer units increased from 1 hm3 in 1970 to 6 hm3 in 2020. Although the groundwater exploitation scheme was not previously considered a factor in local hydrological changes, the results of this study demonstrate the significant impact of societal behavior following the scheme’s implementation on the hydrological budget of Merguellil Wadi.
On February 15, 2013, after the observation of a brilliant fireball and a spectacular airburst over the southern Ural region (Russia), thousands of stones fell and were rapidly recovered, bringing some extremely fresh material for scientific investigations. We undertook a multidisciplinary study of a dozen stones of the Chelyabinsk meteorite, including petrographic and microprobe investigations to unravel intrinsic characteristics of this meteorite. We also study the short and long‐lived cosmogenic radionuclides to characterize the initial meteoroid size and exposure age. Petrographic observations, as well as the mineral compositions obtained by electron microprobe analyses, allow us to confirm the classification of the Chelyabinsk meteorite as an LL5 chondrite. The fragments studied, a few of which are impact melt rocks, contain abundant shock melt veins and melt pockets. It is likely that the catastrophic explosion and fragmentation of the Chelyabinsk meteoroid into thousands of stones was in part determined by the initial state of the meteoroid. The radionuclide results obtained show a wide range of concentrations of 14C, 22Na, 26Al, 54Mn, 57Co, 58Co, and 60Co, which indicate that the pre‐atmospheric object had a radius >5 m, consistent with other size estimates based on the magnitude of the airburst caused by the atmospheric entry and breakup of the Chelyabinsk meteoroid. Considering the observed 26Al activities of the investigated samples, Monte Carlo simulations, and taking into account the 26Al half‐life (0.717 Myr), the cosmic‐ray exposure age of the Chelyabinsk meteorite is estimated to be 1.2 ± 0.2 Myr. In contrast to the other radionuclides, 14C showed a very large range only consistent with most samples having been exposed to anthropogenic sources of 14C, which we associate with radioactive contamination of the Chelyabinsk region by past nuclear accidents and waste disposal, which has also been confirmed by elevated levels of anthropogenic 137Cs and primordial 40K in some of the Chelyabinsk fragments. 相似文献