Quantifying Metabolically Driven pH and Oxygen Fluctuations in US Nearshore Habitats at Diel to Interannual Time Scales

We compiled and examined 15 years (2002–2016) of high-frequency monitoring data from the National Estuarine Research Reserve System (NERRS) to characterize diel to interannual variability of pH and dissolved oxygen (DO, % saturation) across 16 diverse, shallow-water habitats along the US Atlantic, Gulf of Mexico, Caribbean, and Pacific coasts. We asked whether these systems exhibit a common pH/DO relationship, whether there were detectable interannual trends in temperature, pH, and DO within and across systems, and how pH/DO dynamics would relate to measured levels of nutrients and chlorophyll. Our analyses confirmed that large, metabolically driven, and thus concurrent fluctuations of pH and DO are a unifying feature of nearshore habitats. Moreover, we derived well-constrained relationships that predict (i) monthly mean pH or (ii) mean diel pH fluctuations across systems based on habitat mean salinity and (i) mean DO or (ii) mean diel DO fluctuations. This suggests that common metabolic principles drive diel to seasonal pH/DO variations within as well as across a diversity of estuarine environments. Yearly pH and DO anomalies did not show monotonous trends over the study period and differed considerably between sites and regions. However, weekly anomalies of means, diel minima, and diel ranges of pH and DO changed significantly over time and were strongly correlated to temperature anomalies. These general patterns lend strong empirical support to the notion that coastal acidification—in addition to being driven by eutrophication and atmospheric CO₂ increases—is exacerbated simply by warming, likely via increasing community respiration. Nutrient and chlorophyll dynamics were inversely related in these shallow, well-mixed systems, but higher nutrient levels were still associated with lower pH and lower DO levels in most, but not all, systems. Our analyses emphasize the particular dynamics of nearshore habitats and the critical importance of NERRS and its system-wide monitoring program.     

Single-crystal structure and Raman spectroscopy of synthetic titanite analog CaAlSiO<Subscript>4</Subscript>F

Synthetic CaAlSiO₄F, the Al-F analog of titanite, has been investigated using single-crystal synchrotron diffraction experiments at Beamline X06DA (Swiss Light Source, Paul Scherrer Institute, Villigen, Switzerland) and Raman spectroscopy. The presented structural model with 40 parameters was refined against 506 unique reflections to a final R _{o b s} of 0.026 (space group A2/a, a = 6.9120(11), b = 8.5010(10), c = 6.435(2) Å, β = 114.670(11)°, and Z = 4) and exhibits less distorted coordination polyhedra than earlier models from powder data. Vibrational spectra were calculated in harmonic approximation at the Γ point from fully relaxed energy optimisations of the crystal structure, using 3D-periodic density functional theory with Gaussian basis sets and the software CRYSTAL06. The lattice parameters of the fully relaxed structure were in good agreement with the experimental values, with the calculated values 0.8 ± 0.4 % too large; the monoclinic angle was calculated 0.4° too large. The agreement of the calculated Raman frequencies with the observed ones was very good, with standard deviation ±3 cm^?1 and maximum deviations of ±7 cm^?1. Furthermore, a detailed discussion of the atomic displacements associated with each Raman mode is given.     

Climate-change impacts on sagebrush habitat and West Nile virus transmission risk and conservation implications for greater sage-grouse

Greater sage-grouse (Centrocercus urophasianus) are threatened by loss of sagebrush habitat and the spread of West Nile virus throughout much of their range in North America; yet, future impacts of climate change on these potential stressors have not been addressed. Here, we aim to quantify the potential impacts of climate change on the distribution of climatically suitable habitat for sagebrush and on transmission risk for West Nile virus in the eastern portion of the species’ range. We used Maxent to model the current and future climatically suitable habitat for two dominant sagebrush species in the study area, and we used a degree-day model to predict future West Nile virus transmission risk under likely climate-change scenarios. Our models suggest that areas with the highest future suitability for sagebrush habitat will be found in southwestern Wyoming and north-central Montana. The degree-day model suggests that greater sage-grouse in western portions of the study area, which are generally higher in elevation than where West Nile virus currently occurs, will see increasing risk of transmission in the future. We developed a spatially explicit map of suggested management actions based on our predictions that will aid in conservation of the species into the coming decades.     

Intramonthly Indices of the Pacific/North American Teleconnection Pattern and Temperature Regimes over the United States

Summary Previous work has examined relationships between the planetary scale Pacific North American (PNA) teleconnection pattern and regional scale mean temperature over portions of the United States, but analyses have been restricted to monthly values of these two variables. It is not clear if this is the most appropriate scale for relating PNA patterns to temperature. In this study, PNA indices are related to various aspects of temperature over a range of time scales spanning one month. To carry this out, standardized PNA indices are calculated for 6 time intervals ranging from 5 to 30 days over a period of 27 winter seasons. Standardized regional scale temperature anomalies are assessed over various regions of the United States and used to compute mean, maximum, and minimum temperature anomalies over the same 6 time intervals. Correlation matrices are then constructed to provide relationship characteristics between the PNA indices and temperature measures within the intramonthly time scale. Only the southeastern and northwestern regions of the United States display significant relationships between the PNA indices and temperature. Over the Southeast, temperature anomalies on short time scales relate most strongly to PNA indices computed over time intervals of 25 to 30 days; this is especially the case for the minimum temperature anomaly. The strongest relationships, however, are observed between the PNA index and temperature anomalies computed on a 20–25 day time interval. Over the Northwest, the relationships are not as strong and somewhat more varied. Most notably, moderate connections are found between the 30 day PNA index and minimum temperature anomalies computed over a 25 day period. Received August 18, 1997Revised November 28, 1997     

Ergebnisse und Aussichten der Gefügeforschung im pommerschen Diluvium

Zusammenfassung Die Bewegungsrichtungen der diluvialen, nordischen Inlandeismassen können mit ihren Veränderungen des Nachschubes auf Grund ihres Geschiebeinventars in. Norddeutschland festgestellt werden. Derartige Eisstromstriche im großen stehen mit den lokalen Lagerungsverhältnissen diluvialer Schichtpakete des Jungmoränengebietes sehr oft im Widerspruch. Besonders ist das im küstennahen Gebiet Norddeutschlands der Fall. Selten sind genügend große Aufschlüsse vorhanden, die aus der Art der Schichtenlagerung die bis 90^° betragenden Abweichungen von der normalen Bewegungsrichtung des Inlandeises erkennen lassen. Es wird daher das Kleingefüge der Geschiebemergel zum Erkennen dieser Abweichungen benutzt. Im allgemeinen wurden die Geschiebe im Eis als Stromlinienkörper bewegt, so daß für Pommern eine Karte beigegeben ist, die eine Glazialschrammenkarte ersetzt. Sie läßt die stärkeren lokalen Schwankungen im küstennahen Gebiet deutlich erkennen. Weitere Einregelungsstudien in fluvioglazialen Sedimenten führten besonders bei Osern zur Möglichkeit, ehemalige Stromrichtungen und -stärken festzustellen. Als Darstellungsmethode werden Gefügediagramme empfohlen, wie sieSander, Rüger u. a. vorwiegend bei Schmelztektoniten benutzten. Die Urstromtäler und großen radialen Rinnen in Norddeutschland bergen noch Probleme, die voraussichtlich mit Einregelungsstudien zu lösen sind.     

Petrology,geochronology,and geophysical characterization of Mesoproterozoic rocks in central Illinois,USA

The Precambrian basement rocks of the Eastern Granite-Rhyolite Province(EGRP)in central Illinois(midcontinent region of North America)exhibit a complex history of early volcanism,granite emplacement,and intrusion of mafic rocks.A comprehensive suite of dedicated petrographic analyses,geophysical logs,and drill core from four basement-penetrating wells,two-dimensional and three-dimensional seismic reflection data,and U-Pb age data from the Illinois Basin–Decatur Project(IBDP)and Illinois Carbon Capture Storage(ICCS)Project site provide new constraints for interpreting the Precambrian basement of the Illinois Basin.These new data reveal the basement to be compositionally and structurally complex,having typical EGRP felsic volcanic rocks intruded by the first reported gabbro in the Precambrian basement in Illinois.Zircons(n?29)from rhyolite give a U-Pb weighted mean average age of 14679 Ma.Zircons(n?3)from a gabbro dike that intrudes the rhyolite yield a concordia age of 107312 Ma,which corresponds to Grenville-age extension and represents the first Grenville-age rock in Illinois and in the EGRP.A high-resolution three-dimensional seismic reflection volume,coincident with the four wells,provides a context for interpreting the petrological data and implies a high degree of heterogeneity for basement rocks at the IBDP–ICCS site,as also shown by the drill cores.The occurrence of Grenville-age gabbro is related to a prominent bowl-like structure observed on local two-dimensional seismic reflection profiles and the three-dimensional volume that is interpreted as a deep-seated mafic sill complex.Furthermore,heterogeneities such as the brecciated EGRP rhyolite and later gabbro intrusion observed in the basement lithology at the IBDP–ICCS may reflect previously unknown distal elements of the 1.1 Ga Midcontinent Rift in the EGRP and more likely Grenville-age extension.     

Natural convection of compressible and incompressible gases in undeformable porous media under cold climate conditions

A numerical model for convective heat and mass transport of compressible or incompressible gas flows with soil-water phase change is presented. In general, the gaseous phase is considered as compressible and the model accounts for adiabatic processes of compression heating and expansion cooling. The inherently compressible gaseous phase may nevertheless be considered as incompressible by adopting the Oberbeck–Boussinesq approximations. The numerical method used to solve the equations that describe natural convection is based on a Galerkin finite element formulation with adaptive mesh refinement and dynamic time step control. As most existing numerical studies have focused on the behavior of incompressible fluids, model substantiation examines the influence of fluid compressibility on two-widely used benchmarks of steady-state convective heat and mass transport. The relative importance of the effect of pressure-compressibility cooling is shown to increase as the thermal gradient approaches the magnitude of the adiabatic gradient. From these results, it may be concluded that pore-air compressibility cannot be neglected in medium to large-sized enclosures at small temperature differentials. After demonstrating its ability to solve fairly complex transient problems, the model is used to further our understanding of the thermal behavior of the toe drain at the LA2-BSU dam in the province of Quebec, Canada.     

Coupled Reactive Transport Modeling of Redox Processes in a Nitrate-Polluted Sandy Aquifer

The reactive transport modeling of a complicated suite of reactions apparent in the aquifer during the application of N-containing fertilizers is reported. The unconfined sandy aquifer can be subdivided into an oxic zone which contains groundwater with oxygen and nitrate and an anoxic zone characterized by elevated iron and sulfate concentrations in groundwater. Oxygen and nitrate are being reduced by pyrite and organic matter that commonly apparent in the aquifer. The oxidation of pyrite is modeled using the local equilibrium approach, whereas decomposition of organic matter, with the adoption of kinetic approach. The system is buffered by dissolution of aluminum and iron oxides. The modeling process is a two-step procedure. First, the processes are modeled in the one-dimensional (1D) column using PHREEQC code. Subsequently, the calibrated and verified data were copied and used in two-dimensional (2D) PHAST model. Prior to the performance of reactive transport modeling operations with PHAST, a reliable flow model was executed. Finally, predictions are made for the distribution of water chemistry for the year 2008. Model predicts that sulfate derived from the ongoing pyrite oxidation is reduced by the dissolved organic carbon at the higher depth and forms pyrite by the reaction with iron. The results of this study highlight the importance of understanding the interplay between the transport and chemical reactions that occur during the input of nitrate to the aquifer. Reactive transport modeling incorporating the use of a newly developed code PHAST have proved to be a powerful tool for analyzing and quantifying such interactions.