Devonian to Carboniferous collision in the Greenland Caledonides: U-Pb zircon and Sm-Nd ages of high-pressure and ultrahigh-pressure metamorphism

A variety of eclogites from an east-west transect across the North-East Greenland eclogite province have been studied to establish the timing of high pressure (HP) and ultrahigh-pressure (UHP) metamorphism in this northern segment of the Laurentian margin. Garnet + omphacite ± amphibole + whole rock Sm-Nd isochrons from a quartz eclogite, a garnet + omphacite + rutile eclogite and a partially melted zoisite eclogite in the western HP belt are 401±2, 402±9 and 414±18 Ma, respectively. Corresponding sensitive high-resolution ion microprobe (SHRIMP) ²⁰⁶Pb/²³⁸U ages of metamorphic zircon in the same samples are 401±7, 414±13, and 393 ±10 Ma. Metamorphic zircon domains were identified using morphology, cathodoluminescence (CL) imaging, U, Th, Th/U and trace element contents. Zircon from the quartz eclogite and the garnet + omphacite + rutile eclogite are typical of eclogite facies zircon with rounded to subhedral shapes, patchy to homogenous CL domains, low U, and very low Th and Th/U. The partially melted eclogite contains euhedral zircons with dark, sector-zoned, higher U, Th and Th/U inherited cores. Three cores give a Paleoproterozoic ²⁰⁷Pb/²⁰⁶Pb age of 1,962±27 Ma, interpreted as the age of the leucogabbroic protolith. CL images of the bright overgrowths show faint oscillatory zoning next to homogenous areas that indicate zircon growth in the presence of a HP melt and later recrystallization. Additional evidence that zircon grew during eclogite facies conditions is the lack of a Eu anomaly in the trace element data for all the samples. These results, combined with additional less precise Sm-Nd ages and our earlier work, point to a Devonian age of HP metamorphism in the western and central portions of the eclogite province. An UHP kyanite eclogite from the eastern part of the transect contains equant metamorphic zircon with homogeneous to patchy zoning in CL and HP inclusions of garnet, omphacite and kyanite. These zircons have slightly higher U, Th and Th/U values than the HP ones, no Eu anomaly, and are thus comparable to UHP zircons in the literature. The ²⁰⁶Pb/²³⁸U age of these zircons is 360±5 Ma, much younger than the HP eclogites. The same sample gives a Sm-Nd age of 342±6 Ma. Unlike the HP eclogites, the Sm-Nd age of the UHP rock is ca. 20 Ma younger than the U-Pb zircon age and most likely records slow cooling through the closure temperature, since peak temperatures were in excess of 900°C. Widespread HP metamorphism of both the Laurentian and Baltica continental margins marks the culmination of this continent–continent collision in the Devonian. Carboniferous UHP conditions, though localized in the east, suggest a prolonged collisional history rather than a short-lived Scandian orogeny. The traditional Silurian Scandian orogeny should thus be extended through the Devonian.     

Spatio‐temporal changes in bog pool bottom topography – temperature effect and its influence on pool development: an example from a raised bog in Estonia

Increases in pool water and peat temperature in summer accelerate peat decomposition and production of biogenic gases, which can be trapped in peat pores and cause oscillation of peatland surfaces and the rise of peat from the bottom of bog pools. Associated changes in peat water conductivity, holding capacity and transpiration also affect bog hydrology. Our multi‐year study is the first to show in detail the extent and dynamics of changes in bog pool depth and bottom topography associated with changes in temperature, peat type and other factors. The true seasonal rise of peat from the pool bottom begins once the water temperature at the pool bottom exceeds 13–14 °C, although the speed and extent of the rise depends on peat properties, making the rise more erratic than its subsequent descent. The more rapid descent occurs after the first large drop in the temperature of the pool's surface water at the end of summer, resulting from the combination of reduced methane production and increased gas solubility with less influence by peat properties. Much higher dissolved organic carbon concentrations (216 ± 26 mg l^?1) in the pore water of peat risen from the bottom to the pool surface compared with that in the same type of peat at the pool bottom (62 ± 20 mg l^?1) indicate an acceleration of peat decomposition at the warmer pool surface. We show the extent and character of changes in pool depth and bottom topography and how annual differences relate to temperature. Only a few degrees' increase in pool water temperature could induce the pool bottom to rise faster and more extensively for a longer period and enhance decomposition in the peat at the pool surface. This should be evaluated in greater detail to assess the effects of temperature increase on the carbon budget and hydrology of peatlands. Copyright © 2012 John Wiley & Sons, Ltd.     

The Kelvin–Helmholtz instability at Venus: What is the unstable boundary?

The Kelvin–Helmholtz instability gained scientific attention after observations at Venus by the spacecraft Pioneer Venus Orbiter gave rise to speculations that the instability contributes to the loss of planetary ions through the formation of plasma clouds. Since then, a handful of studies were devoted to the Kelvin–Helmholtz instability at the ionopause and its implications for Venus. The aim of this study is to investigate the stability of the two instability-relevant boundary layers around Venus: the induced magnetopause and the ionopause. We solve the 2D magnetohydrodynamic equations with the total variation diminishing Lax–Friedrichs algorithm and perform simulation runs with different initial conditions representing the situation at the boundary layers around Venus. Our results show that the Kelvin–Helmholtz instability does not seem to be able to reach its nonlinear vortex phase at the ionopause due to the very effective stabilizing effect of a large density jump across this boundary layer. This seems also to be true for the induced magnetopause for low solar activity. During high solar activity, however, there could occur conditions at the induced magnetopause which are in favour of the nonlinear evolution of the instability. For this situation, we estimated roughly a growth rate for planetary oxygen ions of about 7.6 × 10²⁵ s⁻¹, which should be regarded as an upper limit for loss due to the Kelvin–Helmholtz instability.     

Structural investigations of the two polymorphs of synthetic Fe-cordierite and Raman spectroscopy of hexagonal Fe-cordierite

The crystal structures of synthetic hexagonal and orthorhombic Fe-cordierite polymorphs with the space groups P6/mcc and Cccm were refined from single-crystal X-ray diffraction data to R _{1, hex}?=?3.14 % and R _{1, ortho}?=?4.48 %. The substitution of the larger Fe²⁺ for Mg leads to multiple structural changes and an increase of the unit cell volumes, with a, c (hex)?=?9.8801(16) Å, 9.2852(5) Å and a, b, c (ortho)?=?17.2306(2) Å, 9.8239(1) Å, 9.2892(1) Å in the end-members. Furthermore Fe incorporation results in an increase of the volumes of the octahedra, although the diameters of the octahedra in direction of the c-axis decrease in both polymorphs. X-ray powder diffraction analysis indicates a high degree of Al/Si ordering in the orthorhombic polymorph, the Miyashiro distortion index is ~0.24. Estimations of site occupancies based on the determined tetrahedral volumes result in the following values for hexagonal Fe-cordierite: ~73 % Al for T₁ and ~28 % Al for T₂. For the first time Raman spectroscopy was performed on the hexagonal Fe-cordierite polymorph. In the hexagonal Fe-cordierite polymorph most Raman peaks are shifted towards lower wavenumbers when compared with the Mg-end-member.     

Using a Combination of Digital Aerial Photography and Satellite Remote Sensing to Assist Contemporary Restructuring in an Urban Area of South Africa

Abstract

The transition and restructuring process of urban South Africa are currently in the phase of identifying land development objectives. These objectives aim to integrate previously segregated areas through integrated development plans. This research aims firstly to identify and describe the historical development of the spatial form and structure of the secondary city and capital of the Northern Province, Pietersburg and its dispersed peripheral towns. Supervised classification of SPOT HRV multispectral imagery is used to support the theoretical explanation. Images from an airborne digital Kodak DCS 420 camera are used to provide training sites in the pre‐classification stages, and also provide field data to the process of post‐classification accuracy assessment. Secondly, SPOT HRV imagery is applied to identify the stark contrast in urban development between the city of Pietersburg and its surrounding former homeland towns. Both built and natural environmental aspects are investigated. In conclusion benefits and problems of assessing urban morphology and development in a developing country by means of a combination of satellite imagery and digital aerial photography are discussed.     

Calibration/Data Assimilation Approach for Integrating GRACE Data into the WaterGAP Global Hydrology Model (WGHM) Using an Ensemble Kalman Filter: First Results

We introduce a new ensemble-based Kalman filter approach to assimilate GRACE satellite gravity data into the WaterGAP Global Hydrology Model. The approach (1) enables the use of the spatial resolution provided by GRACE by including the satellite observations as a gridded data product, (2) accounts for the complex spatial GRACE error correlation pattern by rigorous error propagation from the monthly GRACE solutions, and (3) allows us to integrate model parameter calibration and data assimilation within a unified framework. We investigate the formal contribution of GRACE observations to the Kalman filter update by analysis of the Kalman gain matrix. We then present first model runs, calibrated via data assimilation, for two different experiments: the first one assimilates GRACE basin averages of total water storage and the second one introduces gridded GRACE data at \(5^\circ\) resolution into the assimilation. We finally validate the assimilated model by running it in free mode (i.e., without adding any further GRACE information) for a period of 3 years following the assimilation phase and comparing the results to the GRACE observations available for this period.     

Setting priorities for land management to mitigate climate change

Background

No consensus has been reached how to measure the effectiveness of climate change mitigation in the land-use sector and how to prioritize land use accordingly. We used the long-term cumulative and average sectorial C stocks in biomass, soil and products, C stock changes, the substitution of fossil energy and of energy-intensive products, and net present value (NPV) as evaluation criteria for the effectiveness of a hectare of productive land to mitigate climate change and produce economic returns. We evaluated land management options using real-life data of Thuringia, a region representative for central-western European conditions, and input from life cycle assessment, with a carbon-tracking model. We focused on solid biomass use for energy production.

Results

In forestry, the traditional timber production was most economically viable and most climate-friendly due to an assumed recycling rate of 80% of wood products for bioenergy. Intensification towards "pure bioenergy production" would reduce the average sectorial C stocks and the C substitution and would turn NPV negative. In the forest conservation (non-use) option, the sectorial C stocks increased by 52% against timber production, which was not compensated by foregone wood products and C substitution. Among the cropland options wheat for food with straw use for energy, whole cereals for energy, and short rotation coppice for bioenergy the latter was most climate-friendly. However, specific subsidies or incentives for perennials would be needed to favour this option.

Conclusions

When using the harvested products as materials prior to energy use there is no climate argument to support intensification by switching from sawn-wood timber production towards energy-wood in forestry systems. A legal framework would be needed to ensure that harvested products are first used for raw materials prior to energy use. Only an effective recycling of biomaterials frees land for long-term sustained C sequestration by conservation. Reuse cascades avoid additional emissions from shifting production or intensification.     

A constitutive law for rock salt based on creep and relaxation tests

Summary The paper deals with uniaxial relaxation tests on rock salt which are the basis for a constitutive equation. Since so far no regard was paid to relaxation behaviour, corresponding test results are not available and hence a special device for performing of uniaxial relaxation tests had to be constructed. Some interesting test results are discussed in the paper. These results are useful for the verification of constitutive equations. A critical analysis of conventional constitutive laws and their fundamentals shows that these material laws have considerable imperfections and are rested on substantial restrictions. Particularly, they are not able to describe relaxation behaviour sufficiently. Consequently, a constitutive law is proposed consisting of a strain hardening approach with separate creep and relaxation functions. By post-calculation of different laboratory tests it could be shown that in comparison to conventional steady-state creep equations this material law describes the viscous behaviour of rock salt more realistically.     

Trace element and isotopic variations in a zoned pluton and associated volcanic rocks,Unalaska Island,Alaska: A model for fractionation in the Aleutian calcalkaline suite

Trace elements, including rare earth elements (REE), exhibit systematic variations in plutonic rocks from the Captains Bay pluton which is zoned from a narrow gabbroic rim to a core of quartz monzodiorite and granodiorite. The chemical variations parallel those in the associated Aleutian calcalkaline volcanic suite. Concentrations of Rb, Y, Zr and Ba increase as Sr and Ti decrease with progressive differentiation. Intermediate plutonic rocks are slightly enriched in light REE (La/Yb=3.45–9.22), and show increasing light REE fractionation and negative Eu anomalies (Eu/Eu^*=1.03–0.584). Two border-zone gabbros have similar REE patterns but are relatively depleted in total REE and have positive Eu anomalies; indicative of their cumulate nature. Initial ⁸⁷Sr/⁸⁶Sr ratios in 8 samples (0.70299 to 0.70377) are comparable to those of volcanic rocks throughout the arc and suggest a mantle source for the magmas. Oxygen isotopic ratios indicate that many of the intermediate plutonic rocks have undergone oxygen isotopic exchange with large volumes of meteoric water during the late stages of crystallization; however no trace element or Sr isotopic alteration is evident.Major and trace element variations are consistent with a model of inward fractional crystallization of a parental high-alumina basaltic magma at low pressures (6 kb). Least-squares approximations and trace element fractionation calculations suggest that differentiation in the plutonic suite was initially controlled by the removal of calcic plagioclase, lesser pyroxene, olivine and Fe-Ti oxides but that with increasing differentiation and water fugacity the removal of sub-equal amounts of sodic plagioclase and hornblende with lesser Fe-Ti oxides effectively drove residual liquids toward dacitic compositions. Major and trace element compositions of aplites which intrude the pluton are not adequately explained by fractional crystallization. They may represent partial melts derived from the island arc crust. Similarities in Sr isotopes, chemical compositions and differentiation trends between the plutonic series and some Aleutian volcanic suites indicates that shallow-level fractional crystallization is a viable mechanism for generating the Aleutian calcalkaline rock series.LDGO Contribution no. 2964