Photosynthetic responses to Cu2+ exposure are independent of light acclimation and uncoupled from growth inhibition in Fucus serratus (Phaeophyceae)

We have studied the effect of light acclimation on photosynthetic responses and growth during Cu²⁺ exposure (0–0.84 μM) in the brown seaweed Fucus serratus. Measurements of chlorophyll fluorescence parameters showed that Cu²⁺ exposure amplified ETR, reduced the chlorophyll content at the cellular level and that there was no effect of light adaptation on the Cu²⁺ resistance of the algae. In contrast to the inhibitory effects of Cu²⁺ on chlorophyll fluorescence, O₂ evolution and the total content of chlorophyll and carotenoid of the algae was unaffected by Cu²⁺. We conclude that photoinhibition and perhaps pigment degradation in the meristoderm was compensated for by cells deeper in the thallus with the result that the overall photosynthetic fitness of the algae was maintained. The pronounced inhibitory effects of Cu²⁺ on algae growth was not a consequence of photoinhibition and could be attributed to direct inhibitory effects on the growth process.     

Fast transformation of iron oxyhydroxides by the catalytic action of aqueous Fe(II)

Iron oxides may undergo structural transformations when entering an anoxic environment. These transformations were investigated using the isotopic exchange between aqueous Fe(II) and iron oxides in experiments with ⁵⁵Fe-labelled iron oxides. ⁵⁵Fe was incorporated congruently into a ferrihydrite, two lepidocrocites (#1 and #2), synthesised at 10°C and 25°C, respectively, a goethite and a hematite. The iron oxides were then submerged in Fe²⁺ solutions (0-1.0 mM) with a pH of 6.5. In the presence of aqueous Fe²⁺, an immediate and very rapid release of ⁵⁵Fe was observed from ferrihydrite, the two lepidocrocites and goethite, whereas in the absence of Fe²⁺ no release was observed. ⁵⁵Fe was not released from hematite, even at the higher Fe²⁺ concentration. The release rate is mainly controlled by characteristics of the iron oxides, whereas the concentration of Fe²⁺ only has minor influence. Ferrihydrite and 5-nm-sized lepidocrocite crystals attained complete isotopic equilibration with aqueous Fe(II) within days. Within this timeframe ferrihydrite transformed completely into new and more stable phases such as lepidocrocite and goethite. Lepidocrocite #2 and goethite, having larger particles, did not reach isotopic equilibrium within the timeframe of the experiment; however, the continuous slow release of ⁵⁵Fe suggests that isotopic equilibrium will ultimately be attained.Our results imply a recrystallization of solid Fe(III) phases induced by the catalytic action of aqueous Fe(II). Accordingly, iron oxides should properly be considered as dynamic phases that change composition when exposed to variable redox conditions. These results necessitate a reevaluation of current models for the release of trace metals under reducing conditions, the sequestration of heavy metals by iron oxides, and the significance of stable iron isotope signatures.     

All about water and land? Resource-related conflicts in East and West Africa revisited

Recent years have seen an upsurge in the numbers of studies investigating the potential link between climate variability and conflict—and particularly so quantitative studies of this relationship—without reaching any consensus on causal pathways or main findings. This study sets out to explore what the main causes of conflict between resource-user groups in arid and semi-arid areas in Sub-Saharan Africa are, with a particular focus on renewable-resource scarcity. We conduct a comparative analysis of eleven high-quality case studies of the escalation into violence of disputes between pastoralists and farmers or pastoralists in the Western Sahel and East Africa. This enables us to identify the mechanisms underpinning the actors’ motivations. Our analysis shows that the nature of these conflicts is complex. They cannot be reduced to a stimulus (resource scarcity)–response (violence) relationship. We find that drought is a contributing factor in four of the conflicts, and that a poor rainy season plays a role in a fifth one. However, resource scarcity is never the most important cause and it does not explain well the differences in conflict intensity. The most important contributor to explaining different levels of intensity is when local autochthonous and exclusionary claims are coupled with national-level political processes.     

Water and solute movement in a coarse-textured water-repellent field soil

Unstable water flow in water-repellent unsaturated soils can significantly affect the processes of infiltration and soil water redistribution. A field experiment was carried out to study the effect of water-repellency on water and bromide movement in a coarse-textured soil in the southwestern part of The Netherlands. The field data were analyzed using a relatively simple numerical model based on the standard Richards' equation for unsaturated water flow and the Fickian-based convection-dispersion equation for solute transport. Water-repellency was accounted for by multiplying the water content and the unsaturated hydraulic conductivity of the soil with F, a factor equal to the volumetric fraction of soil occupied by preferential flow paths resulting from the unstable flow process. The good comparison of simulated and measured bromide concentrations suggests that the model provides a viable method for simulating unstable water flow in water-repellent soils.     

Arctic rockwall retreat rates estimated using laboratory‐calibrated ERT measurements of talus cones in Longyeardalen,Svalbard

Holocene rockwall retreat rates quantify integral values of rock slope erosion and talus cone evolution. Here we investigate Holocene rockwall retreat of exposed arctic sandstone cliffs in Longyeardalen, central Svalbard and apply laboratory‐calibrated electrical resistivity tomography (ERT) to determine talus sediment thickness. Temperature–resistivity functions of two sandstone samples are measured in the laboratory and compared with borehole temperatures from the talus slope. The resistivity of the higher and lower‐porosity sandstone at relevant borehole permafrost temperatures defines a threshold range that accounts for the lithological variability of the dominant bedrock and debris material. This helps to estimate the depth of the transition from higher resistivities of ice‐rich debris to lower resistivities of frozen bedrock in the six ERT transects. The depth of the debris–bedrock transition in ERT profiles is confirmed by a pronounced apparent resistivity gradient in the raw data plotted versus depth of investigation. High‐resolution LiDAR‐scanning and ERT subsurface information were collated in a GIS to interpolate the bedrock surface and to calculate the sediment volume of the talus cones. The resulting volumes were referenced to source areas to calculate rockwall retreat rates. The rock mass strength was estimated for the source areas. The integral rockwall retreat rates range from 0.33 to 1.96 mm yr^–1, and are among the highest rockwall retreat rates measured in arctic environments, presumably modulated by harsh environmental forcing on a porous sandstone rock cliff with a comparatively low rock mass strength. Here, we show the potential of laboratory‐calibrated ERT to provide accurate estimates of rockwall retreat rates even in ice‐rich permafrost talus slopes. Copyright © 2012 John Wiley & Sons, Ltd.     

Comparison of geomorphological field mapping and 2D‐InSAR mapping of periglacial landscape activity at Nordnesfjellet,northern Norway

The ability to continuously monitor the dynamic response of periglacial landforms in a climate change context is of increasing scientific interest. Satellite radar interferometry provides information on surface displacement that can be related to periglacial processes. Here we present a comparison of two‐dimensional (2D) surface displacement rates and geomorphological mapping at periglacial landform and sediment scale from the mountain Nordnesfjellet in northern Norway. Hence, 2D Interferometric Synthetic Aperture Radar (InSAR) results stem from a 2009–2014 TerraSAR‐X dataset from ascending and descending orbits, decomposed into horizontal displacement vectors along an east–west plane, vertical displacement vectors and combined displacement velocity. Geomorphological mapping was carried out on aerial imagery and validated in the field. This detailed landform and sediment type mapping revealed an altitudinal distribution dominated by, weathered bedrock blockfields, surrounded primarily by slightly, to non‐vegetated solifluction landforms at the mountain tops. Below, an active rockslide and associated rockfall deposits are located on the steep east‐facing side of the study area, whereas glacial sediments dominate on the gentler western side. We show that 2D InSAR correctly depicts displacement rates that can be associated with typical deformation patterns for flat‐lying or inclined landforms, within and below the regional permafrost limit, for both wet and dry areas. A net lowering of the entire landscape caused by general denudation of the periglacial landforms and sediments is here quantified for the first time using radar remote sensing. Copyright © 2018 John Wiley & Sons, Ltd.     

Nivation forms and processes in unconsolidated sediments,NE Greenland

In the periglacial unconsolidated sediment landscape of Zackenberg in High Arctic NE Greenland, perennial and seasonal snowpatches dominate the geomorphological development in large areas and control the distribution of the vegetation. The existence and distribution of snowpatches and their associated landforms are mainly controlled by the dominating winter wind direction and the amount of snow precipitation, with aspect exerting much less influence. This makes them an important source of information on past environmental change, and knowledge of the combination of geomorphological processes and forms that result from their existence is thus essential. The main nivation processes are backwall failure, sliding and flow, niveo-aeolian sediment transport, supra- and ennival sediment flows, niveo-fluvial erosion, development of pronival stone pavements, accumulation of alluvial fans and basins, and pronival solifluction. The importance of failure, sliding and flow in the continuous retrogressive extension of nivation hollows and niches is emphasized under the term backwall failure. A morphological assemblage of landforms clearly demonstrates the direct nival sediment transfer link between the eroded nivation hollows, their associated meltwater eroded channels and the pronival alluvial fans or basins. All landform elements and their formative processes are integrated into a comprehensive model. © 1998 John Wiley & Sons, Ltd.     

Impact of warming climate on water management for the Ariège River basin (France)

Abstract

The French national project IMAGINE2030 aims to assess future water availability in the Garonne River basin (southwest France) by taking account of changes in both climate and water management in the 2030s. Within this project, two mountainous drainage basins located in the Pyrenees were examined to assess the specific impact of climate change on reservoir management. The Salat River basin at Roquefort, is considered as a proxy (representative of a natural basin), whereas the Ariège River at Foix is influenced by hydropower production in winter and by water releases to sustain low flows in summer. The Cequeau rainfall–runoff model, combined with a simplified model of reservoir management operations, was calibrated on present-day conditions and forced with climate projections derived from the IPCC AR4 report. The results show that a warming climate over the basins induces a decrease in mean annual runoff, a shift to earlier snow melting in mountainous areas and more severe low-flow conditions. The simulations show a decrease in electricity generation. Under two water management scenarios (one “business-as-usual” and the other incorporating an increased downstream water demand in compliance with requirements for increased minimum flow), simulations for the Ariège River basin suggest an earlier filling of the reservoir is necessary in winter to anticipate the increased release from reservoirs in summer to support minimum flow farther downstream.

Editor Z.W. Kundzewicz; Associate editor D. Hughes

Citation Hendrickx, F. and Sauquet, E., 2013. Impact of warming climate on water management for the Ariège River basin (France). Hydrological Sciences Journal, 58 (5), 976–993.     

Release of arsenic associated with the reduction and transformation of iron oxides

The behaviour of trace amounts of arsenate coprecipitated with ferrihydrite, lepidocrocite and goethite was studied during reductive dissolution and phase transformation of the iron oxides using [⁵⁵Fe]- and [⁷³As]-labelled iron oxides. The As/Fe molar ratio ranged from 0 to 0.005 for ferrihydrite and lepidocrocite and from 0 to 0.001 for goethite. For ferrihydrite and lepidocrocite, all the arsenate remained associated with the surface, whereas for goethite only 30% of the arsenate was desorbable. The rate of reductive dissolution in 10 mM ascorbic acid was unaffected by the presence of arsenate for any of the iron oxides and the arsenate was not reduced to arsenite by ascorbic acid. During reductive dissolution of the iron oxides, arsenate was released incongruently with Fe²⁺ for all the iron oxides. For ferrihydrite and goethite, the arsenate remained adsorbed to the surface and was not released until the surface area became too small to adsorb all the arsenate. In contrast, arsenate preferentially desorbs from the surface of lepidocrocite. During Fe²⁺ catalysed transformation of ferrihydrite and lepidocrocite, arsenate became bound more strongly to the product phases. X-ray diffractograms showed that ferrihydrite was transformed into lepidocrocite, goethite and magnetite whereas lepidocrocite either remained untransformed or was transformed into magnetite. The rate of recrystallization of ferrihydrite was not affected by the presence of arsenate. The results presented here imply that during reductive dissolution of iron oxides in natural sediments there will be no simple correlation between the release of arsenate and Fe²⁺. Recrystallization of the more reactive iron oxides into more crystalline phases, induced by the appearance of Fe²⁺ in anoxic aquifers, may be an important trapping mechanism for arsenic.     

Large Aperture Scintillometer Intercomparison Study

Two field studies with six large aperture scintillometers (LASs) were performed using horizontal and slant paths. The accuracy of this novel and increasingly popular technique for measuring sensible heat fluxes was quantified by comparing measurements from different instruments over nearly identical transects. Random errors in LAS measurements were small, since correlation coefficients between adjacent measurements were greater than 0.995. However, for an ideal set-up differences in linear regression slopes of up to 21% were observed with typical inter-instrument differences of 6%. Differences of 10% are typical in more realistic measurement scenarios over homogeneous natural vegetation and different transect heights and locations. Inaccuracies in the optics, which affect the effective aperture diameter, are the most likely explanation for the observed differences.