Removal of heavy metals from paint industry’s wastewater using Leca as an available adsorbent

The ability of light expanded clay aggregate to remove lead and cadmium from paint industry’s effluents was studied at different levels of adsorbent, contact time and pH in April 2008. For this purpose, lead and cadmium removal from paint industry effluents were studied in batch reactors. lead and cadmium measurements have been taken with non-flame atomic absorption techniques and test methods were adapted from 19^th. Ed. of standard methods for the examination of water and wastewater. In this study, different amounts of Leca (1, 2, 3, 4, 5, 6, 7, 8, 9 and 10 g/L) were investigated. The amount of adsorbed lead and cadmium exposure to Leca increased from 1.41 to 3 mg/g and 0.22 to 0.75 mg/g, respectively. The maximum removal efficiency for Pb was 93.75 % at pH = 7 and exposure to 10 g/L of Leca, while for cadmium, it was nearly 89.7 % at the same condition. In this study, adsorption process of lead and cadmium was fitted with Freundlich adsorption isotherm (R² _Pb = 0.97 and R² _Cd = 0.98). The sufficient contact time was deemed 1–2 h for lead and cadmium. According to the results, Leca is recommended as a low cost and available adsorbent to remove lead and cadmium from industrial wastewater.     

Water quality variability and eutrophic state in wet and dry years in wetlands of the semiarid and arid regions

Wetland ecosystems are particularly vulnerable due to flow of nutrients from the surrounding watershed. The study was performed in the Shadegan wetland, a Ramsar-listed wetland located in the south-west of Iran at the head of the Persian Gulf. The wetland plays a significant hydrological and ecological role in the natural functioning of the northern Gulf. The proposed wetland has different water quality characteristics in wet and dry years of study during 1994–2006. To determine the variables, sampling was carried seasonally for each year at six stations. The results indicate that wetland in wet years had high concentrations of nitrate and silicate, leading to oligo–meso eutrophic conditions. Wetland in dry years had high phosphate concentrations, resulting in meso-eutrophic conditions. Forcing functions, such as climatic patterns, water residence time, reduce runoff and increasing density of wastewaters from the surrounding urban, agricultural and industrial area are probably the main variables that explain the observed patterns.     

On the characteristics of ground motion rotational components using Chiba dense array data

An effort is made to examine the properties of rotational (torsional and rocking) ground motions using Chiba dense array data. The Chiba array system, located 30 km east of Tokyo, Japan, is composed of 15 boreholes with separation distances varying from 5 to 320 m. This provides a unique opportunity to examine the characteristics of rotational components. For this purpose, 17 events are considered and rotational ground motions are evaluated using spatial derivatives of translational ones. The effects of seismological parameters and separation distances between stations on properties of rotational motions are examined, showing a sudden increase in rotational motions for the earthquakes with large magnitude or PGA and decrease of these motions with increasing separation distance. While the duration of torsional motion is found to be larger than translational ones, there is no significant difference between durations of rocking and vertical motions. The effects of separation distance and earthquake magnitude on rotational response spectra are also investigated. The normalized rotational response spectra are found to be strongly affected by separation distance. The spectral ratios of rotational and translational motions are not linearly proportional to period as suggested by the previous studies. Finally, the torsional motion is predicted from translation ones for different separation distances at the site. The comparison of the predicted and the calculated torsional motions reveals a weak estimation in close separation distances (<30m) and satisfactory predictions in other cases. Copyright © 2007 John Wiley & Sons, Ltd.     

Spatiotemporal reference evapotranspiration changes in humid and semi-arid regions of Iran: past trends and future projections

Theoretical and Applied Climatology - This study was undertaken to investigate the reference evapotranspiration (ET0) changes in semi-arid and humid regions of Iran during the past...     

Environmental management of coastal regions in the Caspian Sea

Considering rapid population growth and migration, higher accumulation of communities is noticed in coastal areas. This is especially true with the coastal areas of the Caspian Sea. In the present investigation coastal areas between Jouybar to Behshahr region is selected for their special geographical and ecological locations. Further, adverse impacts of human, agriculture and industrial activities was examined along side the above mentioned coasts. It should be pointed out that protected Miankaleh Wildlife zone which is an internationally recognized wetland, falls within area of study. In the present study strengths, weaknesses, opportunities and threats method is used for the evaluation of environmental management status. In this regard, internal and external factors gained 2.28 and 2.58 scores. This is indicative of the abundance of weaknesses over strengths and it also shows that opportunities are more than threats. Subsequently 27 strategies were developed and quantitative strategic planning matrix method was also used to score each strategies. The results of quantitative strategic planning matrix method analysis was programmed in strategic position and action evaluation matrix. The present situation falls within “competitive” classification. This is indicative of weakness in coordinating development and environmental strategic plans. The result of present investigation strongly emphasis on compilation of strategic environmental plans for the control of population, pollution emission and land use planning changes. The most important strategies include development of environmental regulations and better supervision on enforcement of laws.     

Socioeconomic Vulnerabilities and Housing Reconstruction in Puerto Rico After Hurricanes Irma and Maria

Natural Hazards - Hurricanes Irma and Maria caused widespread destruction in Puerto Rico in 2017. In the absence of government recovery support and denial of assistance based on ownership, many...     

An iterative scheme for two-dimensional supercavitating flow

In the present research, supercavitating potential flow is studied numerically by the boundary element method (BEM). Using the advantages of BEM, an iterative algorithm has been introduced to capture cavity boundary in two-dimensional symmetric flows. In this algorithm, the cavity length is known and used to find the related cavitation number and cavity profile. In order to obtain finite length cavities, a cusped cavity closure model has been employed. Applying this cavity closure model, it is possible to change the cavity closure profile and its specified length. By comparing the results of the present analysis with previous analytical and numerical solutions as well as the experimental data, it can be concluded that the present iterative numerical algorithm is reliable and can be applied with BEM or other numerical methods to predict the characteristics of a supercavitating flow. Moreover, the feasibility of the cavity capturing in a flow field with low cavitation number is especially attractive.     

Improved Water Quality Prediction with Hybrid Wavelet-Genetic Programming Model and Shannon Entropy

Natural Resources Research - Prediction of biochemical oxygen demand (BOD) as the main pollution indicators of organic pollution in freshwater resources is necessary. In the present work, a hybrid...     

Flocculation of heavy metals during mixing of freshwater with Caspian Sea water

Flocculation of colloidal size fraction for Cu, Zn, Pb, Ni and Mn was investigated on a series of mixtures with water salinities ranging from 1.5 to 9.5‰ during mixing of Haraz River with the Caspian Sea water. The flocculation trend of Zn (85.5%) > Mn (55.2%) > Cu (39.6%) > Pb (33.7%) > Ni (11.3%) indicates that Cu, Zn, Pb and Mn have non-conservative behavior and Ni has relatively conservative behavior during estuarine mixing. Highest flocculation of heavy metals occurs between salinities of 1.5 and 4.5‰. Statistical analysis indicates that the flocculation of Cu, Zn and Ni is governed by pH and total nitrogen.