Geochemical constraints on the genesis of the volcanic rocks in the southeast of Isfahan area, Iran

Late Miocene–Pliocene to Quaternary calc-alkaline lava flows and domes are exposed in southeast of Isfahan in the Urumieh Dokhtar magmatic belt in the Central Iran structural zone. These volcanic rocks have compositions ranging from basaltic andesites, andesites to dacites. Geochemical studies show these rocks are a medium to high K calc-alkaline suite and meta-aluminous. Major element variations are typical for calc-alkaline rocks. The volcanic rocks have SiO₂ contents ranging between 53.8% and 65.3%. Harker diagrams clearly show that the dacitic rocks did not form from the basaltic andesites by normal differentiation processes. They show large ion lithophile elements- and light rare earth elements (LREE)-enriched normalized multielement patterns and negative Nb, Ti, Ta, and P. Condrite-normalized REE patterns display a steep decrease from LREE to light rare earth elements without any Eu anomaly. These characteristics are consistent with ratios obtained from subduction-related volcanic rocks and in collision setting. The melting of a heterogeneous source is possible mechanism for their magma genesis, which was enriched in incompatible elements situated at the upper continental lithospheric mantle or lower crust. The geochemical characteristics of these volcanic rocks suggested that these volcanic rocks evolved by contamination of a parental magma derived from metasomatized upper lithospheric mantle and crustal melts.     

Removal of uranium(VI) from aqueous solutions using Eucalyptus citriodora distillation sludge

Adsorption and desorption of uranium(VI) from dilute aqueous solutions by Eucalyptus citriodora distillation sludge was studied in a batch mode. The potential of Eucalyptus citriodora distillation sludge to remove uranium(VI) from aqueous solutions has been investigated at different conditions of solution pH, metal ion concentrations, biosorbent dosage, biosorbent particle size, contact time and temperature. The results indicated that biosorption capacity of Eucalyptus citriodora distillation sludge was strongly affected by the medium pH, the biosorbent dose, metal ion concentrations and medium temperature. Reduction in particle size increased the biosorption capacity. Langmuir and Freundlich isotherm models were applied to biosorption data to determine the biosorption characteristics. An optimum biosorption capacity (57.75 mg/g) was achieved with pH 4.0, particle size 0.255 mm, biosorbent dose 0.5 g/100 mL and initial uranium(VI) concentration of 100 mg/L. Uranium(VI) removal by Eucalyptus citriodora distillation sludge was rapid, the equilibrium was established within 60 min and pseudo-second-order model was found to fit with the experimental data. The biosorption process decreased with an increase in the temperature indicating its exothermic nature. Pretreatments of biomass with different reagents affected its biosorption capacity. A significant increase (34 %) in biosorption capacity (83.25 mg/g) was observed with benzene treatment. Fourier-transform infra-red studies showed the involvement of carbonyl, carboxyl and amide groups in the biosorption process. The results indicated that sulfuric acid had the best effects as an eluent showing 93.24 % desorption capacity.     

Random vibration of nonlinear structures with stiffness and strength deterioration by modified tail equivalent linearization method

In this research the tail equivalent linearization method(TELM) has been extended to study structures with degrading materials. The responses of such structures to excitations are non-stationary, even if the excitations are stationary. Non-stationary behavior of the system cannot be considered by conventional TELM. Applying the conventional TELM, the only distinction in the design point excitation for two stationary excitations with different durations is in the addition of a zero value part at the beginning of the design point of the longer excitation. This means that the failure probability is the same for the non-stationary systems under excitations with different durations. Therefore, this solution cannot be correct. In this study, in using TELM for systems with degrading materials, hysteretic energy is replaced by average hysteretic energy, calculated by averaging the obtained hysteretic energy of the structure subjected to a few random sample load realization. In this way, the degradation parameters under design point coincide with those under sample load realizations. Since the average of the hysteretic energy is converges very fast, the modified TELM only requires about tens to hundreds solutions of the response in addition to the ordinary calculations of conventional TELM.     

Shake table study on an ordinary low‐rise building seismically isolated with SU‐FREIs (stable unbonded‐fiber reinforced elastomeric isolators)

This paper reports on the investigation of novel fiber reinforced elastomeric isolator (FREI) bearings, which do not have thick end plates, and are used in an unbonded application. Owing to the stable lateral load‐displacement response exhibited by the unbonded FREI bearings, the proposed bearings are referred to as stable unbonded (SU)‐FREIs. A shake table test program was conducted on a two‐story test‐structure having well‐defined elastic response characteristics. Compared with the results for the corresponding fixed base (FB) structure, the peak response values, distribution of lateral response throughout the height of the structure, and response time histories of the tested base isolated (BI) structure indicate that significantly improved response can be achieved. This study clearly indicates that SU‐FREI bearings can provide an effective seismic isolation system. Copyright © 2009 John Wiley & Sons, Ltd.     

Peculiar motions of galaxy clusters: correlation function approach

The correlation function theory on the basis of prescribed boundary conditions provides a deeper understanding in studying the dynamical parameters of galaxy clusters. The approach approximates that the moderate dense systems discussed by a two point correlation function is helpful for describing the dynamical nature of galaxy clusters. The projected theory of two point correlation function for point mass and extended mass structures can be used an alternative tool in measuring the average peculiar motion and temperature profile of galaxy clusters.     

绿洲耕地变化趋势及其驱动力——塔里木盆地南部策勒绿洲为例

以多年的野外实地调查资料和统计资料,分析了塔里木盆地南部策勒绿洲50年以来耕地面积变化的总体趋势、空间差异和驱动因子。基于GPS现场定位,应用GIS进行空间分析,通过建立多元回归模型,最终对该绿洲2010年和2020年的耕地数量进行了初步的预测。分析结果表明社会经济发展动态、农业科技进步和水土资源的限制等3大类因素是影响耕地数量的3个主成分,其结果将为进一步研究整个塔里木盆地南部绿洲耕地变化提供借鉴,为合理利用和保护耕地、为干旱区可持续发展提供科学依据。     

Application of spectrum–area fractal model to identify of geochemical anomalies based on soil data in Kahang porphyry-type Cu deposit,Iran

The aim of this study is to identify geochemical anomalies using power spectrum–area (S–A) method based on the grade values of Cu, Mo and Au in 2709 soil samples collected from Kahang porphyry-type Cu deposit, Central Iran. S–A log–log plots indicated that there are three stages of Cu, Mo and Au enrichment. The third enrichment was considered as the main stage for the presence of Cu, Mo and Au at the concentrations above 416 ppm, 23 ppm and 71 ppb, respectively. Elemental anomalies are positively associated with monzo–granite–diorite and breccias units which are in the central and western parts of the deposit. The anomalies are located within the potassic, phyllic and argillic alteration types and also there is the positive correlation between the anomalies and nearing faults in the studied area. The results obtained via fractal model were interpreted accordingly to incorporate the information for the mineralized areas including detailed geological map, structural analysis and alterations. The results show that S–A multifractal modeling is applicable for anomalies delineation based on soil data.     

Vertical geochemical variations and arsenic mobilization in the shallow alluvial aquifers of the Chapai-Nawabganj District, northwestern Bangladesh: implication of siderite precipitation

Core sediments from three disturbed boreholes (JOR, GHAT, and RAJ) and two undisturbed boreholes (DW1 and DW2) were collected in the study area of the Chapai-Nawabganj district of northwestern Bangladesh for geochemical analyses. In the study area, groundwater samples from fourteen As-contained private wells and five nested piezometers at both the DW1 and DW2 boreholes were also collected and analyzed. The groundwater arsenic concentrations in the uppermost aquifer (10–40 m of depth) range from 3 to 315 μg/L (mean 47.73 ± 73.41 μg/L), while the arsenic content in sediments range from 2 to 14 mg/kg (mean 4.36 ± 3.34 mg/kg). An environmental scanning electron microscope (ESEM) with an energy dispersive X-ray spectrometer was used to investigate the presence of major and trace elements in the sediments. Groundwaters in the study area are generally the Ca–HCO₃ type with high concentrations of As, but low levels of Fe, Mn, NO₃ ^? and SO ₄ ^?2 . The concentrations of As, Fe, Mn decrease with depth in the groundwater, showing vertical geochemical variations in the study area. Statistical analysis clearly shows that As is closely associated with Fe and Mn in the sediments of the JOR core (r = 0.87, p < 0.05 for Fe and r = 0.78, p < 0.05 for Mn) and GHAT core (r = 0.95, p < 0.05 for Fe and r = 0.93, p < 0.05 for Mn), while As is not correlated with Fe and Mn in groundwater. The comparatively low Fe and Mn concentrations in some groundwater and the ESEM image revealed that siderite precipitated as a secondary mineral on the surface of the sediment particles. The correlations along with results of sequential extraction experiments indicated that reductive dissolution of FeOOH and MnOOH represents a mechanism for releasing arsenic into the groundwater.     

Generating non-stationary random fields of auto-correlated,normally distributed CPT profile by matrix decomposition method

This paper emphasises the true realisation of Cone Penetration Test (CPT) profiles considering non-stationary nature of the data. Formulation of stationary random field theory has been modified and adapted to non-stationary state in order to take into account the mean and variance variability for soil properties. Multi-variance correlation matrix along with the Cholesky decomposition technique was employed to produce realisations of non-homogenous and non-stationary random fields of CPT profiles. A piecewise and segmental data realisation according to the lithology and site class specifications acquired directly from CPT data is adopted in this study so as to render an accurate data simulation. For validation of proposed method 8 CPT test profiles collected from Urmia Lake site have been introduced and simulated by the stationary and non-stationary algorithms. The mean correlation coefficient between the actual CPT data profiles and related realisations along with some other important statistical parameters and their coefficients of variation strongly demonstrate that non-stationary random field generation technique gives quite better accuracy, by comparison to the conventional stationary random field generation scheme.