Sensitive Ion‐Flotation Separation of Ag(I) Traces Using 2‐(2‐Methoxyphenyl)benzimidazole before Flame Atomic Absorption Spectrometric Determination in Water

A sensitive, reliable, and environmentally friendly method for simple separation and preconcentration of Ag(I) traces in aqueous samples is presented prior to their flame atomic absorption spectrometric determinations. At pH 7.0, Ag(I) was separated with 2‐(2‐methoxyphenyl)benzimidazole (MPBI) as a new complexing agent and floated after adding sodium dodecyl sulfate (SDS) as a foaming reagent. The floated layer was then dissolved in proper amount of concentrated nitric acid in methanol and introduced to the flame atomic absorption spectrometer (FAAS). The effects of pH, concentration of MPBI, type and amount of surfactant as the floating agent, type and amount of eluting agent, and influence of foreign ions on the recovery of the analyte ion were investigated. Also, using a nonlinear curve fitting method, the formation constant of 1.62 × 10⁶ was obtained for Ag(I)–MPBI complex. The analytical curve was linear in the range of 1.8 × 10^?7–1.7 × 10^?6 mol/L for determination of Ag(I). The relative standard deviation (RSD; N = 10) corresponding to 0.7 × 10^?6 mol/L of Ag(I), the limit of detection (10 blanks), and the enrichment factor were obtained as 1.7%, 2.9 × 10^?8 mol/L, and 43.0, respectively. The proposed procedure was then applied successfully for determination of silver ions in different water samples.     

Comparison of two intelligent models to estimate the instantaneous global solar radiation in semi-arid climate conditions: Application in Iran

Solar radiation incident on the earth’s surface is a fundamental input for many aspects of climatology, hydrology, biology, and architecture. In addition, it is an important parameter in solar energy applications. Due to the high cost of the measuring instruments of solar radiation, many researchers have suggested different empirical methods to estimate this essential parameter. In this study, with the help of fuzzy systems and neural networks, two models have been designed to estimate the instantaneous global solar radiation in Rafsanjan city which has a typical climatic conditions of semi-arid region of middle eastern countries. In fuzzy and neural network model, the inputs are the number of the given day in the year, time, ambient temperature and cloudiness, The comparison between the results of the models and the measurements, shows that the estimated global radiation is similar to the measurement; for fuzzy model, statistical indicators RMSE, MBE and t-test are 103.4367 \((\hbox {w/m}^{2})\), 4.1169 \((\hbox {w/m}^{2})\) and 9.1318, respectively and for ANN, they are 85.46 \((\hbox {w/m}^{2})\), 3.08 \((\hbox {w/m}^{2})\) and 5.41, respectively. As the results indicate, both models are able to estimate the amount of radiation well, while the neural network has a higher accuracy. The output of the modes for six other cities of Iran, with similar climate conditions, also proves the ability of the proposed models.     

Assessing building vulnerability to tsunami using the PTVA-3 model: A case study of Chabahar Bay,Iran

Chabahar Bay, in southeastern Iran, lies at the north of the Gulf of Oman and close to the Makran Subduction Zone, which makes it a region that is susceptible to tsunamis. This bay has an increasingly important role in Iran’s international trade, and therefore the assessment of the regional vulnerability to the effects of a tsunami is vital. Based on both the details of historical events and the results of numerical modeling of the propagation pattern of a tsunami in this region, this study assessed the vulnerability of buildings within the Chabahar Bay region to a tsunami event. The Papathoma Tsunami Vulnerability Assessment (PTVA) model was used to calculate a relative vulnerability index (RVI) for the affected buildings based on their physical and structural characteristics. The results showed that in a postulated worst-case-scenario tsunami event in the Chabahar Bay area, approximately 60 % of the residential buildings would be affected, a level of damage that is categorized as “Average” in the RVI classification. Overall, the economic losses related to the damage of residential buildings due to a tsunami in the Chabahar Bay area are anticipated to be the equivalent of US$ 16.5 million.     

Psychological sequels of flood on residents of southeast Caspian region

Flood is the most common disaster in the world and has acute or chronic health consequences including psychological sequels. Post-traumatic stress disorder (PTSD) is one of the main consequences. This study aimed to explore the psychological impacts (PTSD) in two flooded cities of Mazandaran Province, Neka and Behshahr, in the southeastern Caspian region that experienced flooding in 2012. A cross-sectional community-based study was performed on randomly selected samples of 400 individuals using GIS-based sampling from 139931 residents of the two flooded cities. The PTSS-10 questionnaire was used for data collection. The results showed that the overall stress disorder mean score among the participants was 2.59 out of 6. PTSD prevalence in the affected population was 64%. It was also found that stress scores significantly increased in younger people, male gender, the divorced, the widows or the widowers, and those who lost their properties (p < 0.05). Study findings showed that flood is a considerable stressor which develops PTSD. This finding should be taken into account in all four phases of disaster management cycle, and subsequently, specialized post-disaster mental health services must be provided for the afflicted population.     

Investigation of Various Parameters Effect on Cerchar Abrasivity Index with PFC3D Modeling

The Cerchar test is one of the appropriate and routine tests for determining the rock abrasion; but as for the costs and pin wear measurement errors in laboratory procedures and lack of access to laboratory equipment, using of numerical modeling can lead to use of greater number of samples required during the course of mechanized excavation and reduce the costs and errors in the laboratory test. In this study, the Cerchar abrasivity test was modeled using PFC3D (Particle Flow Code in 3 Dimensions) software. In order to verify the simulation results, Cerchar laboratory test results obtained by Rostami (Rock Mech Rock Eng 47(5):1905–1919, 2014) were compared with the numerical modeling results. In modeling studies, the effects of some parameters such as apply load, test speed, pin hardness and scratching distance on pin wear were investigated. As a conclusion of the study, good agreement between modeling and experimental results was obtained for a given condition. As in the experiment with various loads in both laboratory tests and modeling, with increasing applied load the Cerchar abrasivity index also increased in the experiment with Rockwell hardness HRC (An abbreviation for Rockwell Hardness measured on the C scale. The Rockwell test determines the hardness by measuring the depth of penetration of an indenter under a large load compared to the penetration made by a preload, that on the C scale use from a indenter with 120° cone and 150 kgf load) 42.     

Earthquake relocation in the Central Alborz region of Iran using a non-linear probabilistic method

In this study, we calculate accurate absolute locations for nearly 3,000 shallow earthquakes (≤20 km depth) that occurred from 1996 to 2010 in the Central Alborz region of northern Iran using a non-linear probabilistic relocation algorithm on a local scale. We aim to produce a consistent dataset with a realistic assessment of location errors using probabilistic hypocenter probability density functions. Our results indicate significant improvement in hypocenter locations and far less scattering than in the routine earthquake catalog. According to our results, 816 earthquakes have horizontal uncertainties in the 0.5–3.0 km range, and 981 earthquakes are relocated with focal-depth errors less than 3.0 km, even with a suboptimal network geometry. Earthquake relocated are tightly clustered in the eastern Tehran region and are mainly associated with active faults in the study area (the Mosha and Garmsar faults). Strong historical earthquakes have occurred along the Mosha and Garmsar faults, and the relocated earthquakes along these faults show clear north-dipping structures and align along east–west lineations, consistent with the predominant trend of faults within the study region. After event relocation, all seismicity lies in the upper 20 km of the crust, and no deep seismicity (>20 km depth) has been observed. In many circumstances, the seismicity at depth does not correlate with surface faulting, suggesting that the faulting at depth does not directly offset overlying sediments.     

Isolation and characterization of alkane degrading bacteria from petroleum reservoir waste water in Iran (Kerman and Tehran provenances)

Petroleum products spill and leakage have become two major environmental challenges in Iran. Sampling was performed in the petroleum reservoir waste water of Tehran and Kerman Provinces of Iran. Alkane degrading bacteria were isolated by enrichment in a Bushnel–Hass medium, with hexadecane as sole source of carbon and energy. The isolated strains were identified by amplification of 16S rDNA gene and sequencing. Specific primers were used for identification of alkane hydroxylase gene. Fifteen alkane degrading bacteria were isolated and 8 strains were selected as powerful degradative bacteria. These 8 strains relate to Rhodococcus jostii, Stenotrophomonas maltophilia, Achromobacter piechaudii, Tsukamurella tyrosinosolvens, Pseudomonas fluorescens, Rhodococcus erythropolis, Stenotrophomonas maltophilia, Pseudomonas aeruginosa genera. The optimum concentration of hexadecane that allowed high growth was 2.5%. Gas chromatography results show that all strains can degrade approximately half of hexadecane in one week of incubation. All of the strains have alkane hydroxylase gene which are important for biodegradation. As a result, this study indicates that there is a high diversity of degradative bacteria in petroleum reservoir waste water in Iran.     

A COMPARISON OF HYDROLOGY AND VEGETATION BETWEEN A CHANNELIZED STREAM AND A NONCHANNELIZED STREAM IN WESTERN TENNESSEE

The purpose of this study was to provide baseline data on floodplain forest structure, composition, and function that would be needed to predict and monitor the consequences of a proposed stream restoration project. This project would involve the “dechannelization” of Stokes Creek, a stream in western Tennessee that was channelized and leveed in the first half of the 1900s. To this end, we collected data on surface hydrology, soil redox potential (Eh), and the structure and composition of the floodplain vegetation of Stokes Creek. To place our findings into a regional context, we also collected comparable vegetation data from plots located along a nonchannelized stream reach of the Wolf River near Moscow, Tennessee. While hydrologic fluctuations of floodplain sites were synchronous with river dynamics for the Wolf River, the hydrology of floodplain sites at Stokes Creek was constrained by the influence of beaver dams, backflooding, and ponding of overland flow behind levees. Consequently, composition of the forest overstory, understory, and herbaceous strata was significantly different between the two sites. For example, Stokes Creek had a noticeable lack of cypress and tupelo sites, and a greater abundance of red maple. Analyses of size-class structure and woody debris quantity reinforced the existing differences between the more natural and human-impacted systems. While the current hydrology apparently has a negative affect on bottomland hardwoods, scattered regeneration stems and soil redox measurements indicate that a dechannelization effort that yielded lower water tables in the Stokes Creek floodplain potentially could increase bottomland hardwood establishment. [Key words: channelization, western Tennessee, bottomland hardwoods, hydrology.]     

Analysis of observed and projected interannual variability in the summer season onset,length, and end dates across the Iran

Theoretical and Applied Climatology - It is very important to study the role of global warming on the variability of summer characteristics in arid and semi-arid climates such as Iran, because of...