Geochemistry and geochronology of Late Jurassic and Early Cretaceous intrusions related to some Au (Sb) deposits in southern Anhui: a case study and review

Some Au deposits in southern Anhui Province have recently been found to be closely associated with Late Mesozoic intrusions. Typical examples include the Huashan Au (Sb) deposit and Au deposits at Zhaojialing, Wuxi, and Liaojia. In order to understand the mechanisms that led the formation of these Au deposits, we make detailed reviews on the geological characteristics of these Au deposits. Specifically, we present new LA-ICP-MS zircon U–Pb dating, along with elemental and Hf isotopic data from the Huashan Au (Sb) deposit. Our data suggests that the Huashan ore-related intrusions were emplaced during the Late Jurassic and Early Cretaceous periods (144–148 Ma). They are characterized by arc-magma features and high oxygen fugacity and are rich in inherited zircons. Zircon U–Pb ages and Lu–Hf isotopes from intrusions suggest that Proterozoic juvenile lithosphere is the main source of these intrusions. The regional geological history implies that lithosphere beneath southern Anhui was produced during a Proterozoic subduction and was fertilized with Au (Cu) in the process. Integrated with the results of previous studies, we inferred that Late Mesozoic intrusions formed by the remelting of the lithosphere could provide the metal endowment for the Au-rich deposits in southern Anhui.     

The effects of clay minerals and organic matter on nanoscale pores in Lower Paleozoic shale gas reservoirs,Guizhou, China

In organic-rich gas shales, clay minerals and organic matter (OM) have significant influences on the origin, preservation, and production of shale gas. Because of the substantial role of nanoscale pores in the generation, storage, and seepage of shale gas, we examined the effects of clay minerals and OM on nanoscale pore distribution characteristics in Lower Paleozoic shale gas reservoirs. Using the Niutitang and Longmaxi shales as examples, we determined the effects of clay minerals and OM on pores through sedimentation experiments. Field emission–scanning electron microscopy combined with low-pressure N₂ adsorption of the samples before and after sedimentation showed significant differences in pore location and pore size distribution between the Niutitang and Longmaxi shales. Nanoscale pores mostly existed in OM in the Longmaxi shale and in clay minerals or OM–clay composites in the Niutitang shale. The distribution differences were attributed largely to variability in thermal evolution and tectonic development and might account for the difference in gas-bearing capacity between the Niutitang and Longmaxi reservoirs. In the nanoscale range, mesopores accounted for 61–76% of total nanoscale pore volume. Considerably developed nanoscale pores in OM were distributed in a broad size range in the Longmaxi shale, which led to good pore connectivity and gas production. Numerous narrow pores (i.e., pores?<?20 nm) in OM–clay composites were found in the Niutitang shale, and might account for this shale’s poor pore connectivity and low gas production efficiency. Enhancing the connectivity of the mesopores (especially pores?<?20 nm and those developed in OM–clay composites) might be the key to improving development of the Niutitang shale. The findings provide new insight into the formation and evolutionary mechanism of nanoscale pores developed in OM and clay minerals.     

美国国家公园的地理信息系统(GIS)

通过介绍美国国家公园中GIS的管理与实施经验，结合我国在地质公园的GIS应用情况，达到促进我国国家地质公园及其它国家公园中的GIS应用的目的。     

Geology and Genesis of Peraluminous Granites in East Tianshan Upper Paleozoic Island Arc Belt

A peraluminous granite belt occurs along the connecting zone between the Turpan-Hami Precambrian block and the Upper Paleozoic island arc belt. Muscovite granite and twomica granite are the essential lithological components of that belt. All the potassium feldspars in these granites are microcline. Heavy minerals are dominated by magnetite. SiO₂ contents of these granites are greater than 73% with most of the A/NKC values greater than 1.1, normative corundum values greater than 1. Plots of CIPW norms in the (Al-K-Na)-Ca-(Fe²⁺+ Mg) diagram are mostly situated in the plagioclase-cordierite-muscovite region. The rocks are characterized by very low contents of minor elements and ΣREE with strong Eu depletion, δ¹⁸O values between 6.6‰ and 7.0‰, Rb-Sr isochron age of 260.2 ± 6.2 Ma and an initial⁸⁷Sr/⁸⁶ Sr ratio of 0.7052. These granites might have been produced by partial melting of moderately acidic volcanites and low-maturity sediments in the basement sequences and could be genetically connected with the southward A-type subduction of the Turpan-Hami block following the closure of the Middle Carboniferous back-arc basin.     

MTA固井技术在煤层气井中应用的实验研究

MTA固井技术在油气田中的运用已经取得了显著效果,能够提高二界面的抗剪切强度以及抵抗地层水对二界面的冲蚀。通过室内实验,对MTA固井技术在煤层气井中的运用进行探索。实验结果表明,MTA技术在煤层气井的固井模拟实验中,也能够有效的提高二界面的抗剪切强度,实现二界面的整体固化胶结,抵抗地层水对煤层气二界面的冲蚀,这些特点对于提高煤层气井的产能具有重要意义。作为一种施工简捷、效果显著的固井技术,MTA固井方法在煤层气井中的应用前景是极为广阔的。     

环境水样中铀、钍、镭和铅同位素及其比值的系统分析

本文研究了从5L水中用铁、铅、钡和铈作载体,系统分析~(234)U、~(238)U、~(228)Th、~(230)Th~(232)Th、~(224)Ra、~(226)Ra、~(228)Ra和~(210)Pb的含量或比值。铀、钍经Fe(OH)_3沉淀富集后用TBP萃淋树脂柱分离,用激光荧光和比色法测定,同位素比值用α谱仪测量,化学回收率在90％以上,测量下限分别为1μg/L和3μg/L。镭、铅经硫酸盐沉淀富集后,用EDTA在不同pH条件下分离,~(224)Ra和~(226)Ra用射气法测定,~(228)Ra和~(210)Pb分别用其β子体~(228)Ac和~(210)Bi在低本底β装置上测量,测量下限分别为2.5×10~(-2)、8×10~(-3)、4×10~(-3)和5×10~(-3)Bq/L。     

解梁与块单元衔接问题的新方法—单点约束法

本文通过单点约束方程,提出了解梁与块单元衔接问题的新方法。该方法比其它方法具有更大的灵活性和精确性,可推广到解其它不同维数的单元之间的衔接问题。     

Geochemical and Sr-Nd isotopic study of alkaline syenites in Liangtun-Kuangdonggou, Liaoning Province, China： Evidence for enriched mantle before 1.86 Ga and implications

The 1.86 Ga Liangtun-Kuangdonggou complex (LKC) is one of the oldest alkaline syenite bodies so far discovered in China. This syenite suite has elevated contents of total alkali (K2O Na2O), with an average of 10.50%, and a mean Rittmann Index (σ) of 6.48. The intrusions have slightly higher concentrations of K2O than those of Na2O on a weight percent basis, indicating the rocks belong to potassium-rich alkaline syenite series. Total rare-earth element concentrations (∑REE ) of the rocks are relatively high, ranging from 324×10 -6 to 1314×10 -6, with a mean value of 666×10 -6. The REE patterns are subparallel and rightward steep with (La/Yb)N >33, showing mild negative to positive Eu anomalies (δEu: 0.63-1.15). All samples exhibit strong LILE and LREE enrichments and TNT (Nb, Ta, Ti) and P depletions in multi-element spidergrams. On the εSr(t)-εNd(t) correlation diagram, most analytical data points plot within the enriched mantle field with low ( 87Sr/86Sr)i ratios (0.7045-0.7051) and negative εNd(t) values (-3.72--3.97), falling among those kimberlites from Fuxian County, Liaoning Provinve, from Mengyin County, Shandong Province and the Ⅱ-type kimberlites from South Africa. These characteristics imply that the LKC-rocks may have the same source as the above-mentioned kimberlites, i.e., they have close connections to the materials derived from enriched mantle reservoirs, further revealing that the upper mantle beneath the northeastern part of the North China Plate had been highly enriched before 1.86 Ga. Geodynamically, the LKC-rocks were formed in a within-plate environment with close genetic connections to rift-related alkaline magma activities possibly controlled by ancient mantle plumes.