The effect of slight to minor biodegradation on C<Subscript>6</Subscript> to C<Subscript>7</Subscript> light hydrocarbons in crude oils: a case study from Dawanqi Oilfield in the Tarim Basin,NW China

Light hydrocarbons (LHs) are one of the main petroleum fractions in crude oils, and carry much information regarding the genetic origin and alteration of crude oils. But secondary alterations—especially biodegradation—have a significant effect on the composition of LHs in crude oils. Because most of the LHs affected in oils underwent only slight biodegradation (rank 1 on the biodegradation scale), the variation of LHs can be used to describe more the refined features of biodegradation. Here, 23 crude oils from the Dawanqi Oilfield in the Tarim Basin, NW China, eleven of which have been biodegraded to different extents, were analyzed in order to investigate the effect of slight to minor biodegradation on C₆–C₇ LHs. The study results showed that biodegradation resulted in the prior depletion of straight-chained alkanes, followed by branched alkanes. In slight and minor biodegraded oils, such biodegradation scale could not sufficiently affect C₆–C₇ cycloalkanes. For branched C₆–C₇ alkanes, generally, monomethylalkanes are biodegraded earlier than dimethylalkanes and trimethylalkanes, which indicates that branched alkanes are more resistant to biodegradation, with the increase of substituted methyl groups on parent rings. The degree of alkylation is one of the primary controlling factors on the biodegradation of C₆–C₇ LHs. There is a particular case: although 2,2,3-trimethylbutane has a relative higher alkylation degree, 2,2-dimethylpentane is more resistant to biodegradation than 2,2,3-trimethylbutane. 2,2-Dimethylpentane is the most resistant to biodegradation in branched C₆–C₇ alkanes. Furthermore, the 2-methylpentane/3-methylpentane and 2-methylhexane/3-methylhexane ratios decreased steadily with increasing biodegradation, which implies that isomers of bilateral methyl groups are more prone to bacterial attack relative to mid-chain isomers. The position of the alkyls on the carbon skeleton is also one of the critical factors controlling the rate of biodegradation. With increasing biodegradation, Mango’s LH parameters K1 values decrease and K2 values increase, the values of n-heptane and isoheptane decrease, and the indices of methylcyclohexane and cyclohexane increase. LH parameters should be applied cautiously for the biodegraded oils. Because biodegraded samples belong to slight or minor biodegraded oils, the values of n-heptane and isoheptane from Dawanqi Oilfield can better reflect and determine the “Biodegraded” zone. When the heptane value is 0–21 and the isoheptane value is 0–2.6, the crude oil in Dawanqi Oilfield is defined as the “Biodegraded” zone.     

Review of Earth Critical Zone Research

Since the Earth Critical Zone put forward by National Research Council of America in 2001, it has got a lot of attention and some significant progresses have been made. This paper summarized those Earth Critical Zone projects and related research plans organized and implemented by the United States of America, Germany, Australia, France, China and the European Union, as well as main scientific problems and future development direction in the study of Earth Critical Zone. According to research status of China, the four main research contents should be strengthened including structure, formation and evolution mechanism of Earth Critical Zone, the coulpling interaction mechanism between migration and transformation of material and multi-processes, sevice function and evolution features of Earth Critical Zone and its support and effect on sustainable development, model simulation of process and system of Earth Critical Zone. In addition, our country should actively conduct cooperation and communication with the advanced countries, and enhance our involvement in international key research plans.     

Study on the Global Carbon Assimilation System Based on Multisource Remote Sensing Data

The Paris agreement signed in April, 2016 aims to balance global anthropogenic carbon emissions and terrestrial carbon sinks by the middle of the 21^st century. To fulfill this goal, it is necessary to calculate carbon fluxes of different regions reliably. The global carbon assimilation system is an effective technique for achieving this goal. The Ministry of Science and Technology of China supports the project entitled as study on the global carbon assimilation system based on multisource remote sensing data through the national key research and development programs for global change and adaptation during the thirteen-five period. This project will develop synergic inversion techniques for retrieving key parameters of biological and atmospheric cycles and for assimilating multisource remote sensing and ground based data. Then, the high resolution global carbon assimilation system coupled with an ecological model will be constructed. This system is able to assimilate jointly multisource observation data and to optimize key model parameters, photosynthesis and respiration carbon fluxes of global terrestrial ecosystems, and anthropogenic carbon emission fluxes of key regions. This system will be used to study quantitatively the spatial and temporal patterns of carbon fluxes of global terrestrial ecosystems and anthropogenic carbon emission fluxes of key regions and to identify the mechanisms driving the global terrestrial carbon sinks and sources. The outputs of this study will be helpful for the fulfillment of the key research and development programs for global change and adaptation and provide valuable data and technical support for the decision-making in China.     

Characteristic and Geological Significance of Microbially Induced Sedimentary Structures(MISS) in Terrestrial P-T Boundary in Xingyang,Western He’nan Province

Microbially Induced Sedimentary Structures (MISS) are primary sedimentary structures that arise syndepositionally from microbial community activity. Especially valuable are MISS for the analysis of early Archean (and extraterrestrial) deposits. However, most reports of MISS have focused on the Precambrian and Phanerozoic mass extinction marine sediments, and only a few and terrestrial MISS have been studied. The MISS presented in this paper, which mainly consists of mat growth feature, mat destruction feature and mat decay feature, are well preserved in terrestrial clastic rocks around the P-T boundary in Xiyang area, western Henan. Large U ridges, oriented sand quartz, mica grains and thin clayey laminae arranged parallel to bedding plane are the main features visible under the microscope. Several lines of evidence indicate that the Xingyang MISS are of biogenic origin. Abundant MISS in Xingyang may indicate the degradation of terrestrial ecosystems and proliferation of microbial mats immediately after the severe Permian-Triassic mass extinction. Study aiming at MISS helps to analyze their space distribution in the globe and to probe into links between microbial proliferation and environmental stresses following the end-Permian mass extinction in terrestrial ecosystems.     

Comparative Study of the Carbon Emission Situation and Goals between China and India

As the two large developing and populous countries, China and India face the dual challenges of economic development and climate change. Both of them are active in carbon emissions reduction, while India also bears the pressure of being “benchmarked” against China. With taking China and India as the sample of a comparative analysis, and the statistical value of a long sequence as the basic analysis data, based on the detailed analysis and comparison of carbon emissions history, the carbon emissions situation of the two countries from various dimensions including economic development, energy reserves and consumption, etc. were comparatively analyzed. The carbon intensity and energy structure after achieving the objectives were measured and compared by focusing on the carbon emissions reduction targets in China and India. The comparative results show that: China’s total carbon emissions are greater than India’s, but the growth rate of emissions, per capita emissions are significantly lower than India’s, while the carbon intensity decreases significantly faster than that of India. China has taken more efforts to make commitments to carbon reduction than India. With India’s energy structure adjustment, the situation will be gradually better than that in China.     

Detachment folding in a Lower Cambrian–Upper Permian karst reservoir: 3D model of the Yubei 3D area (eastern Markit Slope,Tarim Basin,Northwest China)

A three-dimensional (3D) structural modeling of the Lower Cambrian–Upper Permian Yubei 3D area was performed to understand its structural evolution. This model reproduces the present-day structure of the basin and comprises 11 horizons within Lower Cambrian to Upper Permian rocks. The analysis is based on 3D depth views and faults. The results image salt movements due to tectonics and/or burial. From these observations, this paper deduces that salt structures are correlated to the main faults and tectonic events. From the model analysis, we interpret the timing and geometry of Tarim Basin tectonics. The fault geometry can be resolved based on the strike of the fault, the morphology of hanging wall strata, and the stratigraphic distribution. Emphasis is placed on gypsum rock detachment, considering its movements during the Middle Caledonian event and decoupling effects during tectonic evolution. Moreover, we point to the structural control of the Paleozoic basement and the crustal architecture (Yubei 3D Zone) on the geometry of the Tarim Basin.     

Regional debris flow susceptibility analysis based on principal component analysis and self-organizing map: a case study in Southwest China

A method was developed to analyze the susceptibilities of 541 regional basins affected by debris flows at the Wudongde Dam site in southwest China. Determining susceptibility requires information on source material quantity and occurrence frequency. However, the large number of debris flows can hinder the individual field investigation in a each small basin. Factors that may trigger debris flows can be identified using remotely sensed interpretation information. Susceptibility analysis can then be conducted based on these factors. In this study, SPOT5 satellite imagery, digital elevation models (DEM), a lithology distribution map, and rainfall monitoring data were used to identify 12 debris flow trigger factors: basin relief ratio, slope gradient in the initiation zone, drainage density, downslope curvature of the main channel, vegetation coverage, main channel aspect, topographic wetness index, Melton’s ruggedness number, lithology, annual rainfall, form factor, and cross-slope curvature of the transportation zone. Principal component analysis was used to obtain the eight principal components of these factors that contribute to susceptibility results. Then, a self-organizing map method was adopted to analyze the principal components, which resulted in a debris flow susceptibility classification. Field validation of 26 debris flow basins was used to evaluate the errors of the susceptibility classification, as well as assess the causes of such errors. The study found that principle component analysis and self-organizing map methodologies are good predictors of basin susceptibility to debris flows.     

Underwater Navigation Based on Real-Time Simultaneous Sound Speed Profile Correction

Precise sound speed profile (SSP) information is critical when using sonar for underwater terrain navigation. Nevertheless, acquiring SSP information in real-time is difficult, especially in underwater navigation environment. To account for this problem, this paper presents an underwater navigation method that applies real-time SSP correction to the terrain measurements. The method uses a probe to measure the surface sound speed simultaneously. Meanwhile, redundancy of topographic measurement data is exploited to derive the equivalent SSP information. The acquired equivalent SSP is updated continuously with particle filter algorithm. The terrain measurements can be corrected in real-time with the equivalent SSP to improve the performance of underwater terrain navigation. By removing the impact of inaccurate SSP from the terrain measurements, the proposed method can achieve precise and robust underwater navigation result without using an underway-profiling instrument. Simulated results confirm the good performance of the proposed method.     

A Method for Automatically Selecting Aids to Navigation Based on their Spatial Influence Domains

To address the limitations of manually selecting aids to navigation (AtNs) on charts, a method for automatically selecting AtNs based on their spatial influence domains (SIDs) is proposed. First, the associations between the spatial attributes of an AtN are analyzed. Second, an SID of the AtN is defined, and a model of the SID is constructed based on the associations between the spatial attributes. Third, the importance of the location of the AtN is weighted based on the SID model. Fourth, an algorithm to automatically select AtNs based on the maximum coverage of the SIDS of preselected AtNs is developed. Finally, several AtNs are selected automatically using the algorithm. The experimental results demonstrate that (1) the proposed method can automatically select AtNs and the results comply with the requirements; (2) the automatic selection can eliminate the human-induced errors or the inconsistent results of manual selections from different operators; and (3) the efficiency of the proposed method is higher than that of current manual methods.