Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

The conformity of HI galaxies in ALFALFA-SDSS sample

The conformity effect,indicating the evolution of galaxies is related to its surrounding neighbor galaxies as far as a few Mpc,is an interesting phenomenon in the modeling of galaxy and evolution.Here we study the conformity effect of HI galaxies in a matched galaxy sample between SDSS DR7 and ALFALFA surveys.By checking the probability difference for the detected H i galaxies as a function of distance around a normal or an H i galaxy,we find that this effect is significant out to 5 Mpc.It also shows a dependence on the stellar mass of galaxies,with the strength the strongest in the stellar mass range of 10¹⁰*/M_⊙<10^10.5.However,when the sample is confined to central galaxies in groups with virial radii smaller than 1 Mpc,the 1-halo conformity signal is still evident,while the 2-halo conformity signal is reduced to a very weak amplitude.Our results confirm the previous study in the optical band that the 2-halo term is possibly caused by the bias effect in the sample selection.Furthermore,we confirm the existence of the 1-halo conformity discovered in the optical and radio band in previous investigations.Our results provide another viewpoint on the conformity effect and hope to shed light on the co-evolution of the galaxies and their neighbors in the current galaxy formation models.     

Discovery of Four New Clusters in the Cygnus Cloud

We report the discovery of four new open clusters(named QC 1,QC 2,QC 3 and QC 4)in the direction of Cygnus Cloud and select their members based on five astrometric parameters(l,b,ω,μα*,μδ)of Gaia DR2.We also derive their astrophysical parameters for each new cluster.Structure parameters are generated by fitting the radial density distribution with a King’s profile.Using solar metallicity,we performed isochrone-fitting on their purified color-magnitude diagrams(CMDs)to derive the age of the clusters.The known cluster NGC 7062 in an adjacent area is chosen to verify our identification process.The estimated distance,reddening and age of NGC 7062 are in good agreement with the literature.     

Filtering vibroseis data in the precorrelation domain

Vibroseis data recorded at short source–receiver offsets can be swamped by direct waves from the source. The signal-to-noise ratio, where primary reflections are the signal and correlation side lobes are the noise, decreases with time and late reflection events are overwhelmed. This leads to low seismic resolution on the vibroseis correlogram. A new precorrelation filtering approach is proposed to suppress correlation noise. It is the ‘squeeze-filter-unsqueeze’ (SFU) process, a combination of ‘squeeze’ and ‘unsqueeze’ (S and U) transformations, together with the application of either an optimum least-squares filter or a linear recursive notch filter. SFU processing provides excellent direct wave removal if the onset time of the direct wave is known precisely, but when the correlation recognition method used to search for the first arrival fails, the SFU filtering will also fail. If the tapers of the source sweeps are badly distorted, a harmonic distortion will be introduced into the SFU-filtered trace. SFU appears to be more suitable for low-noise vibroseis data, and more effective when we know the sweep tapers exactly. SFU requires uncorrelated data, and is thus cpu intensive, but since it is automatic, it is not labour intensive. With non-linear sweeps, there are two approaches to the S,U transformations in SFU. The first requires the non-linear analytical sweep formula, and the second is to search and pick the zero nodes on the recorded pilot trace and then carry out the S,U transformations directly without requiring the algorithm or formula by which the sweep was generated. The latter method is also valid for vibroseis data with a linear sweep. SFU may be applied to the removal of any undesired signal, as long as the exact onset time of the unwanted signal in the precorrelation domain is known or determinable.     

NUMERICAL STUDY ON DOMINATING FACTOR AND KEY AREA OF EL NINO CYCLE FORMATION*

A coupled model,which is employed to study the dominating factor and key area of El Nino cycle formation,consists of a dynamical ocean model and a statistical atmospheric model.The coupled model with seasonal forcing successfully reproduces the El Nino event cycle which exhibits quasi-regular oscillations with a preferred period of about 4 years.The results show that the heat content(HC) is transported between the eastern and the western tropical Pacific areas.The spatial distribution of HC anomalies for four phases of the whole cycle clearly shows a possible formation mechanism of El Nino.Experiments further suggest that sea surface temperature in the tropical Pacific and HC in the central tropical Pacific are the most important factors and the central tropical Pacific is the most important area for determining formation of El Nino cycle.     

中国优质环保型炼焦煤的评价及资源量等级

我国炼焦煤资源丰富，但优质炼焦煤一直处于短缺局面。根据全国已有煤质数据分析，从优质（主要考虑挥发分指标）、环保（主要考虑硫分和灰分指标）两个方面结合有害微量元素含量，将炼焦煤划分为四种类型，确定了优质环保型炼焦煤资源的评价步骤，对全国五个赋煤区优质环保型炼焦煤的资源量等级进行了统计分析。     

水布垭面板堆石坝的三维弹塑性数值分析研究

在建的清江水布垭面板堆石坝高达233 m,是目前同类坝型中最高的.采用MSC.Marc非线性有限元程序,发展了三维子模型法,对该坝进行了三维弹塑性有限元仿真分析,模拟了面板的分缝、坝体材料分区、填筑及蓄水过程,采用双屈服面弹塑性模型模拟堆石体的变形特征.根据数值分析的结果,对坝体和面板的应力变形分布规律进行了探讨.     

670矿床火山围岩铀赋存状态及配分研究

670矿床是中国东南部中生代火山岩带内典型的火山岩型铀钼矿床;矿床具有叠加成矿特点.本文利用诱发裂变径迹的方法研究了矿床火山围岩中铀的赋存状态及配分.结果表明火山围岩中的铀主要有三种赋存状态:(一)分布在火山基质及晶屑内均匀分散的质点铀,其裂变径迹是弥散状或弧立星射状分布;(二)吸附在蚀变矿物表面、矿物隙间及微裂隙内的聚合态铀,其裂变径迹为密集带状及团块状;(三)分布在副矿物中或呈铀矿物存在的铀,其裂变径迹为聚合星射状及团块状.矿物的蚀变过程,如绿泥石化、碳酸盐化等可改变火山围岩铀的赋存状态,造成铀在岩石中的活化和预富集,从而有利于矿化.因此火山围岩中铀的含量虽然较低,但对火山岩型铀矿的形成仍有重要意义.     

柴达木盆地西部地区咸化湖盆天然气地球化学特征及成因类型判识指标——以古近系—新近系为例

根据天然气地球化学基本理论,对柴达木盆地西部（柴西）地区天然气的地球化学特征进行分析。测试和收集该地区18个油气田及含油气构造的83个天然气样品,分析其组分和C同位素数据,结果显示,该区天然气以烃类气体为主,烃类含量介于79.24%~99.81%之间,天然气比重介于0.72~1.36之间,天然气干燥系数（C1/C2+）介于1.04~617.8之间,甲烷C同位素值介于-51.4‰~-24.2‰之间,乙烷C同位素值介于-34.2‰~-17.4‰之间。在此基础上,对该区不同构造带的天然气成因类型进行研究。研究结果表明,柴达木盆地西部地区天然气类型可划分为腐泥型气、腐殖型气、混合气3类,柴西北部天然气主要为腐泥型气和混合气,少量腐殖型气;柴西南部主要为腐泥型气,少量混合气。同时,建立了天然气成因类型的判识指标,对该区的天然气地球化学特征有了较为深入的认识,对今后的天然气勘探具有指导意义。     

Thermal depolymerization of kerogen and formation of immature oil

Two Chinese immature oil shales from the continental deposits of kerogen type I and II have been thermally treated combined with the technique of supercritical fluid extraction at 630–650 K and 15–25 MPa in a semi-continuous laboratory scale apparatus. Toluence is selected as the solvent. Up to 70–80% of the kerogen matrix can be converted to a thermal bitumen and extracted simultaneously. The chemical structural parameters from the NMR, IR, XRD, ESR and EA analyses of the kerogen and the thermal bitumen show striking resemblance in nature. It implies that the thermal bitumen is primarily a depolymerized product of the kerogen. Based on the GC/MS spectra of the aliphatic eluate of the thermal bitumen, the predominance of the odd/even ratio of the alkanes and the epimeric ratios, such as 20S(20S + 20R) of C-29 steranes and 22S/(22S + 22R) of C-32 terpanes, show that the maturity of the thermal bitumen from these oil shales is comparable to that of commercial immature oils from East China. The thermal bitumen is thought to be an intermediate product of the thermal degradation of kerogen.Since the thermal bitumen is mainly composed of asphaltenes and resins, it has a structure of gel. The gel-state bitumen may turn to sol-state readily due to its low aromaticity and polarity, or due to selective adsorption of asphaltenes by clay minerals. Then the migration potential of the bitumen is enhanced.Consequently, under favorable geological conditions, the thermal depolymerization of kerogen seems to be a probable mechanism to explain the formation of immature oils.