A numerical study on the 2D behavior of the single and layered clayey basins

In this numerical study the effects of the stratification and change in material type on the dynamic behavior of the clayey basins are investigated. For this purpose two kinds of single and double layer basin models with the total depth of 100 m and width of 2 km have been selected. The single layer basins consist of soft, medium and stiff clayey materials, while double layer basins consist of a stiff sandy sub-layer overlaid by one of the soft, medium and stiff clayey soil layer. A range of bedrock inclinations at the valley sides from slighter \(10^{\circ }\) and \(20^{\circ }\) to steeper \(30^{\circ }\) and \(40^{\circ }\) are selected. A numerical study using finite difference based nonlinear code which utilizes appropriate static and dynamic boundary conditions, and includes hysteresis damping formulation based on user defined degradation curves is conducted using real earthquake motions of different strength and frequency content. The results of the 2D analyses show the differences in dynamic behavior of single and double layer basins from the aspect of amount and position of the maximum amplification and resonance period. It was seen that the shallower lateral parts of the basins are sensitive to lower periods while inner parts are sensitive to higher periods. Among other differences, the most important difference between the behavior of single and double layer basins was seen at the resonance period of the inner parts of the basins.     

Geodynamic evolution of the Sabzevar zone,northern central Iranian micro-continent

Mineralogy and Petrology - The Northern Central Iranian Micro-continent (CIM) represents Neotethys-related oceanic crust remnants, emplaced due to convergence between CIM and Eurasia plates during...     

Etiology of Salinity and Water Origin,the Main Dilemma of Badab Sourt,a Unique Travertine Spring

Badab Sourt travertine‐depositing springs in the north of Iran, naturally create a unique surreal landscape containing a range of stepped travertine terraces, similarly found only in a few other places on earth. This site comprises of three travertine saline springs with different values of salinity and discharge (SP₁, SP₂, and SP₃) and one non‐travertine fresh karstic spring (SP₄) within a distance of about 300 m. The etiology behind this salinity and the water origin are the main research's dilemma that were investigated using geological, hydrochemical, and stable isotopic techniques. Based on the topography and isotopic results, the carbonate formations in northern (Khoshyeilagh and Mobarak) and southern (Cretaceous limestone) parts of the springs potentially provide the initial hydraulic gradient for deep circulation of the water and CO₂. However, geological studies indicate that the hydraulic connectivity of the Cretaceous formation to the travertine springs is interrupted by impermeable geological formations. Based on the proposed conceptual hydrogeological model and mass balance calculations, the SP₄ spring is locally recharged from the nearby karstic area of Khoshyeilagh formation through shallow, short and steep groundwater flow circulation that is completely different from the travertine springs. The travertine spring (SP₁) is recharged from more distant areas having higher altitudes on Mobarak and Khoshyeilagh limestone and circulate more deeply before emerging on the surface. The SP₂ and SP₃ springs can derive from the mixing of the saline water (SP₁) and fresh water (SP₄). The dissolution of interlayers of halite in Shemshak formation is concluded as the main source of salinity. This is the first research article in detail to survey hydrogeology of the travertine springs in Iran.     

Visible light N-TiO<Subscript>2</Subscript>-induced photodegradation of Congo red: characterization,kinetics and mechanistic study

In this study, the photocatalytic degradation of Congo red has been investigated in N-doped TiO₂ (N-TiO₂) aqueous suspensions under visible light irradiation. Visible light-active N-TiO₂ was successfully prepared at three different weight contents (2.5, 5, and 7%) employing sol–gel method. It was able to harvest the visible irradiation with wavelength suitable for activation. X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectrometer, diffused reflectance UV–Vis spectroscopy, nitrogen adsorption Brunauer–Emmert–Teller, Raman spectroscopy, photoluminescence and X-ray photoelectron spectrometer were used to characterize the doped catalyst. The samples had a relatively large specific Brunauer–Emmert–Teller surface areas of about 42 m² g^?1 with average X-ray diffraction crystalline size of 52 nm and showed visible light photocatalytic activity at about 408 nm. The impacts of several operating parameters on the Congo red photodegradation process were examined. Langmuir–Hinshelwood model exhibited pseudo-first-order degradation kinetics. N-TiO₂-assisted plausible photodegradation mechanism has been suggested based on the qualitatively detected intermediate compounds.     

Trend analysis of rainfall pattern over the Central India during 1901–2010

In the present study, trends of rainfall of the Central India were evaluated in monthly, seasonal, and annual time scales using the Revised Mann-Kendall (RMK) test, Sen’s slope estimator, and innovative trend method (ITM). For this purpose, the monthly rainfall data for 20 stations in Madhya Pradesh (MP) and Chhattisgarh (CG) states in Central India during 1901–2010 was used. The Sen’s slope estimator was utilized for calculating the slope of rainfall trend line. Based on the obtained results of RMK test, there is no significant trend in the stations for the January and October months. The results also showed that for MP, two out of 15 considered stations indicate significant annual trend, while the CG has four out of five stations with significant trend. The results of applying ITM test indicated that most of the stations have decreasing trends in annual (16 stations), summer (16 stations), and monsoon (11 stations) seasons, while the winter (12 stations) and post monsoon (11 stations) seasons generally show increasing trend. Unlike the RMK, the ITM shows significant increasing trend in rainfall of November and December months. The finding of current study can be used for irrigation and water resource management purpose over the Central India.     

Analysis of karst spring recession curves,west of Iran

The recession hydrographs of karst springs provide important information about aquifer characteristics such as storage properties and drainage potential, karstification degree, and other hydrological features. The Faresban, Famaasb, Gonbad-e-Kabood, and Gian springs are the important karst springs which drain main karst aquifers in west of Iran. In this study, we evaluate hydrological characteristics of these four karst springs using different analytic equations. Almost, all the recession curves were well fitted by a function that consists of three main exponential terms. The initial portion of the recession curve represents the fast drainage of large fractures and conduits, ending with the slowly decreasing curve, where the drainage of rock matrix and small fissures or baseflow is dominant. The Gian spring has the largest storage volume but the lowest drained water (7%). Using Mangin’s equation, it is apparent that the baseflow supplies over 85% of the total drained water to the Gian spring, while a small quantity of total outflow is made up of quickflow periods. Of the water available to the Famaasb, Faresban, and Gonbad-e-Kabood springs, 85, 80, and 70% are drained during period of baseflow, respectively, whereas the quickflow periods have minor importance in some springs. Based on the Coutagne’s equation results, it can be concluded that the catchment of the Famaasb and Gonbad-e-Kabood springs have a karstified saturation zone with drainage channels that provide a rapid discharge with little storage capacity. At Gian catchment area, the initial discharge is not as rapid as karstification but is fairly homogeneous throughout the aquifer.     

The effects of agricultural practice and land-use on the distribution and origin of some potentially toxic metals in the soils of Golestan province, Iran

Soil samples were collected from the agricultural lands of Golestan province, north of Iran and analyzed for 24 elements including eight toxic metals of As, Cd, Co, Cr, Cu, Pb, Se and Zn. Electrical conductivity, pH, organic matter, soil texture, calcium carbonate content as well as soil cation exchange capacity were also determined. The possible sources of metals are identified with multivariate analysis such as correlation analysis, principal component analysis (PCA), and cluster analysis. In addition, enrichment factors were used to quantitatively evaluate the influences of agricultural practice on metal loads to the surface soils. The PCA and cluster analysis studies revealed that natural geochemical background are the main source of most elements including Al, Co, Cr, Cs, Cu, Fe, K, Li, Ni, Pb, V and Zn in the arable soils of the province (more than 90 %), however, those soils which have been developed on the mafic and metamorphic rocks were considerably contributed on metal concentration (43 %). Calcium and Sr were constituents of calcareous rocks and Na and S were mainly controlled by saline soils in the north of the province. Loess deposits was also accounting for high levels of selenium concentration. Phosphorous was mostly related to application of P-fertilizers and organophosphate pesticides. The comparison of metal load and enrichment factor for dry and irrigated farmlands showed that Cd, Co, Pb, Se and Zn had higher concentrations in the irrigated lands where considerable amounts of agrochemicals had been applied. However, it also found that proximity of arable lands to urban and industrial areas resulted in higher Pb and Cd values in the irrigated agricultural sources relative to dry ones.     

Application of Leeb Hardness Test in Prediction of Dynamic Elastic Constants of Sedimentary and Igneous Rocks

Geotechnical and Geological Engineering - The Leeb hardness test is a non-destructive and portable technique that can be used both in the laboratory and in-field applications. The main purpose of...