Dissolution kinetics of natural magnesite in lactic acid solutions

In this study, the dissolution of magnesite particles in aqueous lactic acid solutions was investigated in a batch reactor employing the parameters of stirring speed, particle size, temperature and acid concentration. The shrinking core model was evaluated to determine the effect of particle size, temperature and concentration. It was also found that the stirring speed did not change the dissolution. Consequently, it was determined that the dissolution rate is controlled by surface chemical reaction. The activation energy of the process was determined to be 50.3 kJ mol^− 1.     

Properties of the Aftershock Sequences of the 2003 Bingöl, M D = 6.4, (Turkey) Earthquake

Aftershock sequences of the magnitude M _{W =}6.4 Bingöl earthquake of 1 May, 2003 (Turkey) are studied to analyze the spatial and temporal variability of seismicity parameters of the b value of the frequency-magnitude distribution and the p value describing the temporal decay rate of aftershocks. The catalog taken from the KOERI contains 516 events and one month’s time interval. The b value is found as 1.49 ± 0.07 with Mc =3.2. Considering the error limits, b value is very close to the maximum b value stated in the literature. This larger value may be caused by the paucity of the larger aftershocks with magnitude M _D ≥ 5.0. Also, the aftershock area is divided into four parts in order to detect the differences in b value and the changes illustrate the heterogeneity of the aftershock region. The p value is calculated as 0.86 ± 0.11, relatively small. This small p value may be a result of the slow decay rate of the aftershock activity and the small number of aftershocks. For the fitting of a suitable model and estimation of correct values of decay parameters, the sequence is also modeled as a background seismicty rate model. Constant background activity does not appear to be important during the first month of the Bingöl aftershock sequences and this result is coherent with an average estimation of pre-existing seismicity. The results show that usage of simple modified Omori law is reasonable for the analysis. The spatial variability in b value is between 1.2 and 1.8 and p value varies from 0.6 to 1.2. Although the physical interpretation of the spatial variability of these seismicity parameters is not straightforward, the variation of b and p values can be related to the stress and slip distribution after the mainshock, respectively. The lower b values are observed in the high stress regions and to a certain extent, the largest b values are related to Holocene alluvium. The larger p values are found in some part of the aftershock area although no slip occurred after the main shock and it is interpreted that this situation may be caused by the alluvium structure of the region. These results indicate that the spatial distribution in b and p values are generally related to the rupture mechanism and material properties of an aftershock area.     

Regional Variation of the ω - Upper Bound Magnitude of GIII Distribution in and Around Turkey: Tectonic Implications for Earthquake Hazards

Complete data set of earthquakes in Turkey and the adjacent areas has been used in order to compute the ω values in 24 seismic regions of Turkey. The parameter is obtained through Gumbel’s third asymptotic distribution of extreme values and is well known as upper bound magnitude. This is an interpretation that no earthquake magnitude greater than ω can occur in a region. The results also estimate the most probable magnitude for a time period of 100 years. The estimates of ω exceed the value of 7.00 in 20 of the 24 seismic regions. An effort is also made to find a relation between the magnitude and the length of a fault in the complicated tectonics of Turkey and the surrounding area. Earthquake hazard revealed as tables and maps are also considered for Turkey and the surrounding area.     

Magnetotelluric images of the crust and mantle in the southwestern Taurides, Turkey

Inversion of the magnetotelluric data across the southwestern Taurides reveals two subzones of crust with varying thicknesses: conductive lower crust (<75 Ω m), overlain by resistive (>350 Ω m) upper crust, with four resistive cores (>2000 Ω m) separated by three relatively conductive vertical zones. The first and second vertical zones coincide with surface faults interpreted in Anatolia, such as Fethiye Burdur Fault Zone. The third one is the most conductive and lies in continuity with the Strabo Fault Zone in the Mediterranean Sea. A hypocentral cross section of earthquakes along the profile shows more dense seismic activity in the second resistive core where the conductive crust is not present beneath it. The depth of the crust/upper mantle boundary varies between 30 and 50 km and has an undulating character. The resistivity of the upper mantle reaches 500–1000 Ω m.     

Evaluating of the earthquake hazard parameters with Bayesian method for the different seismic source regions of the North Anatolian Fault Zone

The earthquake hazard parameters and earthquake occurrence probabilities are computed for the different regions of the North Anatolia Fault Zone (NAFZ) using Bayesian method. A homogenous earthquake catalog for M _S magnitude which is equal or larger than 4.0 is used for a time period between 1900 and 2015. Only two historical earthquakes (1766, M _S = 7. 3 and 1897, M _S = 7. 0) are included in Region 2 (Marmara Region) where a large earthquake is expected in the near future since no large earthquake has been observed for the instrumental period. In order to evaluate earthquake hazard parameters for next 5, 10, 20, 50, 100 years, M _max (maximum regional magnitude), β value, λ (seismic activity or density) are computed for the different regions of NAFZ. The computed M _max values are changed between 7.11 and 7.89. While the highest magnitude value is calculated in the Region 9 related to Tokat-Erzincan, the lowest value in the Region 10 including the eastern of Erzincan. The “quantiles” of “apparent” and “true” magnitudes of future time intervals of 5, 10, 20, 50, and 100 years are calculated for confidence limits of probability levels of 50, 70 and 90 % of the 10 different seismic source regions. The region between Tokat and Erzincan has earthquake hazard level according to the determined parameters. In this region the expected maximum earthquake size is 7.8 with 90 % occurrence probability in next 100 years. While the regional M _max value of Marmara Region is computed as 7.61, expected maximum earthquake size is 7.37 with 90 % occurrence probability in next 100 years.     

An evaluation of earthquake hazard parameters in the Iranian Plateau based on the Gumbel III distribution

The Gumbel’s third asymptotic distribution (GIII) of the extreme value method is employed to evaluate the earthquake hazard parameters in the Iranian Plateau. This research quantifies spatial mapping of earthquake hazard parameters like annual and 100-year mode beside their 90 % probability of not being exceeded (NBE) in the Iranian Plateau. Therefore, we used a homogeneous and complete earthquake catalogue during the period 1900–2013 with magnitude M _w ? ≥?4.0, and the Iranian Plateau is separated into equal area mesh of 1° late?×?1° long. The estimated result of annual mode with 90 % probability of NBE is expected to exceed the values of M _w 6.0 in the Eastern part of Makran, most parts of Central and East Iran, Kopeh Dagh, Alborz, Azerbaijan, and SE Zagros. The 100-year mode with 90 % probability of NBE is expected to overpass the value of M _w 7.0 in the Eastern part of Makran, Central and East Iran, Alborz, Kopeh Dagh, and Azerbaijan. The spatial distribution of 100-year mode with 90 % probability of NBE uncovers the high values of earthquake hazard parameters which are frequently connected with the main tectonic regimes of the studied area. It appears that there is a close communication among the seismicity and the tectonics of the region.     

Discrimination of earthquakes and quarry blasts in the eastern Black Sea region of Turkey

In recent years, a large number of quarry blasts have been detonated in the eastern Black Sea region. When these blasts are recorded by seismic stations, they contaminate the regional earthquake catalog. It is necessary to discriminate quarry blast records from the earthquake catalogs in order to determine the real seismicity of the region. Earthquakes and quarry blasts can be separated through different methods. These methods should be applied concurrently in order to safely distinguish these events. In this study, we discriminated quarry blasts from earthquakes in the eastern Black Sea region of Turkey. We used 186 seismic events recorded by the Karadeniz Technical University and Bogaziçi University Kandilli Observatory Earthquake Research Institute stations which are Trabzon, Espiye, Pazar, Borçka, Ayd?ntepe, and Gümü?hane between years of 2002 and 2010. For the discrimination of quarry blasts from earthquakes, we used both, statistical methods (calculation of the maximum ratio of S to P waves (S/P), complexity (C)) and spectral methods (spectrogram calculation). These methods included measuring the maximum amplitude S/P, C, spectral ratio, and time-frequency analysis. We especially relied on two-dimensional time-frequency analysis methods to discriminate quarry blasts from earthquakes in Turkey. As a result of this study, 68 % of the examined seismic events were determined to be quarry blasts and 32 % to be earthquakes. The earthquakes occurring on land are related to small faults and the blasts are concentrated in large quarries. Nearly 40 % of the earthquakes occurred in the Black Sea, most of them are related to the Black Sea thrust belt, where the largest earthquake was observed in the time period studied. The areas with the largest earthquake potential in the eastern Black Sea region are in the sea.     

Deliniation of Weathering in the Çatalca Granite Quarry with the Very Low Frequency (VLF) Electromagnetic Method

Faulting and weathering can endanger quarry operations by decreasing the total reserve, quarry’s useful life and production value. We investigated weathering and faulting problems in the Çatalca granite quarry at Istanbul in Turkey, using the Very Low Frequency (VLF) method. VLF method is an electromagnetic method which is very successful in locating vertical discontinuities such as faults and fracture zones. This method measures the apparent resistivity of the rocks in the region, besides the electromagnetic parameters such as tilt angle and ellipcity. Apparent resistivity is a very sensitive parameter to water presence inside the pores and fractures of the rocks. This feature enables the VLF method to map the boundaries between the fresh and cracked granite and altered zones in the quarry. In this work we mapped the faults and weathered zones within the granite in Çatalca quarry and found a high resistivity zone at the central part of the survey area which may be suitable for production. This study also shows the efficiency of the VLF method in understanding the structural and textural features of a quarry and estimating zones with high quality rocks for production planning.