Metabolites from mangrove endophytic fungus Dothiorella sp.

Mangroves are special woody plant communities in the intertidal zone of tropical and subtropical coasts. They prove to be a natural microorganisms and new metabolites storage. In the study of mangrove endophytic fungi metabolites, four new compounds, Compounds 1, 2, 3 and 4, as well as a known octaketide, cytosporone B (5), are isolated from an endophytic fungus, Dothiorella sp., HTF3. They all show cytotoxic activities. The elucidation of these structures is mainly based on 1D/2D NMR and ESI-MS spectral analyses.     

南海东北部末次冰期以来的沉积环境演变

利用南海东北部上陆坡处所取的D孔柱样进行硅藻分析,结合粒度与碎屑矿物分析结果,探讨该海域末次冰期以来沉积环境演变过程.结果表明：粒度与硅藻分析结果较为吻合,共同显示D孔柱样可分为上下两层.上表层（0～2 cm）的砂质沉积层为冰后期海进过程改造的晚更新世残留沉积层,即变余沉积;下层（2～130 cm）主要是末次冰期形成的浅海沉积.整个柱样可反映出海洋同位素MIS 4期海退至MIS 3期海进与MIS 2期海退至冰后期海进的沉积变化韵律.     

冬季东中国海环流中的中尺度涡旋数值模拟

采用高精度的POM模式 ,考虑了海底地形、外来流、长江径流、海面风应力、海面热通量等多方面因素的影响 ,模拟了冬季东中国海环流结构。模拟结果显示 :在黄海东部很可能存在两个涡 ,中心分别在124°37′E ,37°N ,124°E ,35°30′N ;东海北部存在一个大型的气旋式涡旋 ,其中心位置在125.1°E ,30.5°N附近 ,该涡旋是由东北向的台湾暖流、西北向的黄海暖流及南下的沿岸流组成的封闭结构 ;日本九州以西黑潮入侵分支形成一涡旋 ,黑潮分支是形成此涡旋的直接动力因素 ,另外地形和冬季盛行的偏北风也对该涡旋的形成有一定正面影响。     

Advances in the Study of Geochemistry and Paleo-oceanography of the Co-rich Crust

The current advances in the study of geochemistry and paleo-oceanography of the Co-rich crust are reviewed in this paper. We summarize the study of geochemistry of the Co-rich crust, discuss the diffusion of elements in the Co-rich crust and the exchange with ambient seawater. Besides, we discuss the effect of phosphatization and substrate rocks on the composition of the Co-rich crust. We also introduce the application of stable isotopes (including the stable isotopes of Pb, Nd, and Hf), radioactive isotopes (including the radioactive isotopes of Be, U and Th), and elements (including the major elements, minor elements and rare earth elements) to the study of paleo-oceanography of the Co-rich crust.     

从国际司法判例和国际海洋法看中日海洋区域的划界

《联合国海洋法公约》规定，海洋划界争端应在有关国际法的基础上，以和平的方式加以解决，中、日两国的海洋介应该按照国际法的规定，找到适合两国情况的比较公平的原则和方法。     

南海和冲绳海槽沉积物的生物标记化合物

本文对南海深海和冲绳海槽二个柱状样进行了正构烷烃、甾烷和萜烷生物标记化合物分布特征的研究。由于它们所处的沉积环境和生源母质上的差异,反映在正构烷烃的CPI值、C_(17)和C_(18)的含量、轻重烃比值、化合物构型的转化、有机质的成熟度和17α(H)-22,29,30-三降藿烷与18α(H)-22,29,30-三降新藿烷的比值等地球化学参数上的差别。冲绳海槽沉积物的多源性决定了其有机组分的特殊性,如生物来源的C_(17)和C_(18)量占有优势,有机碳含量(1.0—1.3％)高于南海样(0.3—1.0％),重排甾烷量少,生物构型的ββ藿烷已转变成地质构型的αβ藿烷和βα型莫烷化合物。     

星载SAR浅海水下地形和水深测量模拟仿真──水下地形高度、坡度和方向与可测水深分析

根据星载合成孔径雷达(SAR)浅海水下地形和水深成像机理,建立了浅海水下地形和水深雷达后向散射截面仿真模型.利用该模型模拟并分析了不同地形条件下,浅海水下地形的雷达后向散射截面.分析结果表明,水下地形高度越高,SAR可测量的水深越深;水下地形坡度越大,越易被SAR所观测.水下地形的星载SAR测量还与水下地形的方向有关,与卫星飞行方向平行的水下地形最易被SAR观测,与卫星飞行方向垂直的水下地形最不易被SAR观测.     

RESEARCH ON THE DETERMINATION OF Pb, Cd, Cu AND Zn IN SEAWATER BY STRIPPING VOLTAMMETRY

In this paper, a comparison viral made between the two results of determining Pb, Cd, Cu and Zn in seawater by direct current (tripping voltammetry (DCS) with rotating glass carbon electrode and by differential pulse stripping voltammetry (DPS) with hanging mercury drop electrode (HMDE). By DCS, the range of linear calibration curves obtained was 4×10-3 M-2×10-7M for Cu, Zn and Cd, and 4× 10-9M-2×10-3M for Pb. By using DPS, the range of linear calibration curve was as follows: Cu 0.65-1.9 ppb; Pb 1.0-10 ppb; Zn 0.65-2.0 ppb; Cd 0.02-0.14 ppb. It was found that DCS could be used for determining Pb, Cu, Zn in coastal waters, but it is necessary to add gallium ion to it to eliminate the interference of Cu-Zn inter-metallic compound for determining Zn. The DPS is better for determinig Cd.     

Water mass formation variability in the intermediate layer of the east sea

Long-term variability in the intermediate layer of the eastern Japan Basin has been investigated to understand the variability of water mass formation in the East Sea. The simultaneous decrease of temperature at shallower depths and oxygen increasing at deeper depths in the intermediate layer took place in the late 1960’s and the mid-1980’s. Records of winter sea surface temperatures and air temperatures showed that there were cold winters that persisted for several years during those periods. Therefore, it was assumed that a large amount of newly-formed water was supplied to the intermediate layer during those cold winters. Close analysis suggests that the formation of the Upper Portion of Proper Water occurred in the late 1960’s and the Central Water in the mid-1980’s.