西藏塔惹增地区下白垩统捷嘎组的厘定及其地质意义

笔者于西藏仲巴县塔惹增地区一带前人划分的一套早白垩世早期则弄群中发现了具有典型意义的、代表早白垩世晚期的Ampullina xainzaensis Yu,Ampullina cf. larteli Landerer,Tylostoma cf. brasilianus Maury,Pseudamaura cf. subfournaeti (Pcelincev),Gyrodes gaultiana Orbigny,Leviathania cf. gerassimovi(Pcelincev),Gymnentome cf. pizcuetana(Vilanova)等腹足类化石,以及较为丰富的中圆笠虫Mesorbitolina sp.和达克斯虫Daxia sp。表明在该区则弄群中至少有一部分以前没有被识别出的早白垩世晚期地层。通过岩石组合特征、基本层序、生物化石时代对比,将该套地层归属于捷嘎组。这一地层的确定为冈底斯带白垩系地层划分对比、地层格架建立提供了重要的依据,并丰富了该地层的古生物资料,且为中生代盆地的演化历史、古地理轮廓的确定提供了新的基础资料。     

微波消解―ICP―MS法测土壤和水系沉积物样品中的碘

介绍了用微波消解处理土壤和水系沉积物样品,用电感耦合等离子质谱仪(ICP-MS)快速高效测试碘的方法。方法的检出限为0. 012μg/g。所选的12个土壤和水系沉积物国家一级标准物质12次测定,除GBW07307a的RSD小于10%外,其余RSD值均小于5%,12次测试的平均值和标准值对数差绝对值均小于0. 05。方法加标回收率在98. 6%104. 6%之间。     

长江中下游宣城水东地区早白垩世酸性火山岩年代学、地球化学及岩石成因

位于长江中下游的宣城水东地区发育一套酸性火山岩,主要由流纹质角砾岩、流纹岩和珍珠岩组成。本文对该套火山岩进行了详细的锆石U-Pb年代学、主量元素、微量元素以及Nd-Hf同位素研究。LA-ICP MS锆石U-Pb定年结果显示3种岩性的火山岩年龄分别为133.2±0.8、133.4±0.8和131.5±0.9 Ma。主量元素组成上,这套酸性火山岩具高硅(72.51%~81.79%)、富钾(K_2O/Na_2O=2.04~14.93,平均6.72)、贫钙镁(Ca O=0.19%~1.57%,Mg O=0.06%~0.29%)的特征,属于弱过铝质(A/CNK=1.02~1.24)的高钾钙碱性-钾玄岩系列岩石。微量元素方面,轻重稀土元素分馏明显[(La/Yb)_N=5.43~9.17],具明显的负铕异常(Eu/Eu~*=0.44~0.60),富集大离子亲石元素(LILE)Rb、Th、K和Pb等,亏损Ba、Sr、Nb、P和Ti等元素,表现出壳源的特征。全岩Sr-Nd和锆石Hf同位素组成变化范围相对较小,(~(87)Sr/~(86)Sr)_i为0.707 3~0.708 8,εNd(t)值为-7.05~-5.56,εHf(t)为-8.6~-1.3。结合区域地质研究成果,认为宣城水东地区酸性火山岩可能是在约135 Ma古太平洋板块俯冲作用之后的伸展-拉伸环境下,由新元古代早期新生地壳重熔而成。     

祁连山新元古代——早古生代火山作用与铁-铜多金属成矿

祁连山造山带新元古代—早古生代是板块构造演化与成矿的最重要时段,铁、铜多金属矿产资源丰富,成矿作用与新元古代—早古生代火山作用密切相关。根据矿床产出构造位置,将祁连山铁、铜多金属矿床分为4类:大陆裂谷型铁(铜)矿床、岛弧-岛弧裂谷型铜多金属矿床、陆缘裂谷型铜多金属矿床、扩张脊型铜矿床。镜铁山铁(铜)型矿床是新元古代大陆裂谷火山作用过程中热水沉积作用的产物;东沟铜矿为晚寒武世大洋扩张脊火山作用的产物;白银矿田铜多属矿床是奥陶纪与岛弧-岛弧裂谷火山作用的产物;石居里铜矿是晚奥陶纪弧后扩张脊有关火山作用的产物;红沟铜矿则是晚奥陶世陆缘裂谷火山作用的产物。     

塔里木陆块西北缘萨热克砂岩型铜矿床构造-流体演化对成矿的制约

塔里木陆块西北缘萨热克砂岩型铜矿床构造演化、流体演化与成矿之间具有密切关系,处于一个统一系统中。矿床成岩期方解石中包裹体水的δD值为-65.3‰~-99.2‰,改造成矿期石英包裹体水的δD值为-77.7‰~-96.3‰,成岩成矿期成矿流体δ~(18)OH_2O变化范围为-3.22‰~1.84‰,改造成矿期成矿流体δ~(18)OH_2O变化范围为-4.26‰~5.14‰,指示萨热克铜矿成岩期、改造期成矿流体主要为中生代大气降水及其经水岩作用而成的盆地卤水。矿石中辉铜矿δ~(34)S值为-24.7‰~-15.4‰,指示硫主要源自硫酸盐细菌与有机质还原,部分源于有机硫。构造与成矿流体演化对砂岩铜矿成矿起关键制约作用。盆地发展早期强烈的抬升运动使盆地周缘基底与古生界剥蚀,为富铜矿源层的形成提供了丰富物源,至晚侏罗世盆地发展晚期,长期演化积聚的巨量含矿流体在库孜贡苏组砾岩胶结物及裂隙中富集,在萨热克巴依盆地内形成具有经济意义的砂岩型铜矿床。     

新疆三塘湖盆地上石炭统近源凝灰岩致密油藏形成条件

三塘湖盆地上石炭统烃源岩是火山喷发环境下形成的,烃源岩往往与厚度不等的凝灰岩交互出现,但凝灰岩致密储层的厚度和物性差异较大,源储关系较复杂,因而近源凝灰岩致密油藏的形成需要特定的条件。为了认识三塘湖盆地上石炭统近源凝灰岩致密油藏的形成条件,以典型致密油藏M36为例,综合运用岩心、薄片、测录井、地球化学测试等资料,对成藏要素进行解剖,建立上石炭统凝灰岩致密储层及烃源岩有效性的评价标准,并总结出近源致密油藏成藏模式。结果表明,储层孔隙度大于5%、对应渗透率大于0.07×10-3μm2的凝灰岩可以作为有效储层;烃源岩有机碳含量在4.0%以上,对应生烃潜量大于10%,且Ro大于0.8%的高炭泥岩、暗色泥岩为优质烃源岩;较好的储层、优质的烃源岩和互层型源储配置关系是近源凝灰岩致密油藏的形成条件。     

新疆哈密地区早泥盆世珊瑚动物群及其地质意义

新疆哈密地区下泥盆统发育,南部图拉尔根地区下泥盆统为大南湖组,北部三道白杨沟地区为卓木巴斯套组。在大南湖组中共发现四射珊瑚2属5种,床板珊瑚7属12种,并建立四射珊瑚组合Syringaxon moriense和床板珊瑚组合Pseudofavosites giganteus;在卓木巴斯套组共发现四射珊瑚5属7种,床板珊瑚2属2种,并建立四射珊瑚组合Orthopaterophyllum junggarense和床板珊瑚组合Pachyfavosites junggarensis。通过珊瑚在地层中的分布及组合的时代对比,确定前者的时代为早泥盆世埃姆斯期早期,后者的时代为埃姆斯期中晚期。通过与国内外典型的早泥盆世埃姆斯期珊瑚动物群的对比,认为哈密地区的珊瑚动物具有典型的早泥盆世温带动物群特征,在生物古地理区系上属于北方大区准噶尔-兴安省。     

滇西云县地区团梁子岩组变质岩锆石U-Pb年龄及其构造意义

滇西云县—景洪一带广泛出露的中元古界团梁子岩组是一套与扬子基底岩系密切相关的中低变质沉积岩夹火山岩系,其形成时代、沉积充填序列及大地构造属性一直存在争议。出露于云县漫湾地区的团梁子岩组发育厚数米的绿片岩(原岩玄武岩)及绢云石英千枚岩(原岩流纹岩)。采集绢云石英千枚岩样品进行LA-ICP-MS锆石U-Pb定年,分别获得1497±14Ma的岩浆结晶年龄和893±17.3Ma、425±15.7Ma、321±27Ma的变质年龄。认为团梁子岩组中以绿片岩、绢云石英千枚岩为主体的原始沉积岩系形成于中元古代中期,在新元古代全球性的格林威尔造山过程中被青白口纪花岗岩侵入并发生变质作用;在古特提斯洋俯冲过程中,经历古生代造弧作用;同时还获单颗粒2310±15Ma的碎屑锆石,推测滇西云县地区应存在古元古代的结晶基底,由此可知,团梁子岩组应是扬子陆块褶皱基底岩系的组成部分。     

Investigation of gas content of organic-rich shale:A case study from Lower Permian shale in southern North China Basin,central China

Measuring gas content is an essential step in estimating the commerciality of gas reserves. In this study,eight shale core samples from the Mouye-1 well were measured using a homemade patented gas desorption apparatus to determine their gas contents. Due to the air contamination that is introduced into the desorption canister, a mathematical method was devised to correct the gas quantity and quality.Compared to the chemical compositions of desorbed gas, the chemical compositions of residual gas are somewhat different. In residual gas, carbon dioxide and nitrogen record a slight increase, and propane is first observed. This phenomenon may be related to the exposure time during the transportation of shale samples from the drilling site to the laboratory, as well as the differences in the mass, size and adsorptivity of different gas molecules. In addition to a series of conventional methods, including the USBM direct method and the Amoco Curve Fit(ACF) method, which were used here for lost gas content estimation, a Modified Curve Fit(MCF) method, based on the 'bidisperse' diffusion model, was established to estimate lost gas content. By fitting the ACF and MCF models to gas desorption data, we determined that the MCF method could reasonably describe the gas desorption data over the entire time period, whereas the ACF method failed. The failure of the ACF method to describe the gas desorption process may be related to its restrictive assumption of a single pore size within shale samples. In comparison to the indirect method, this study demonstrates that none of the three methods studied in this investigation(USBM, ACF and MCF) could individually estimate the lost gas contents of all shale samples and that the proportion of free gas relative to total gas has a significant effect on the estimation accuracy of the selected method. When the ratio of free gas to total gas is lower than 45%, the USBM method is the best for estimating the lost gas content, whereas when the ratio ranges from 45% to 75% or is more than 75%, the ACF and MCF methods, are the best options respectively.     

Residual-state creep of clastic soil in a reactivated slow-moving landslide in the Three Gorges Reservoir Region,China

We study the creep properties of clastic soil in residual state. The intact samples are taken from a reactivated slow-moving landslide in the Three Gorges Reservoir Region, China. Firstly, the patterns of the landslide movement are analysed based on recent monitoring data, which indicate that the soil within the shear zone is undergoing two deformation processes: a creep phase, characterised by different creep rates, and a dormant phase. We then study the creep behaviour of the soil samples through a series of ring shear creep tests under various shear stress conditions. The creep response depends strongly on the ratio of the shear stress to the residual strength, and the normal effective stress, whereas the creep rate decreases due to strength regain. The long-term strength of the clastic soil is close to the residual strength. Therefore, the residual strength obtained from conventional shear test, which is less time consuming than creep test, can be used in long-term stability analyses of creeping landslides.