Biosorption of methylene blue from aqueous solutions by Typha angustata phytomass

The objective of this study was to investigate the biosorption of an azo dye (Methylene blue) by a wetland phytomass (Typha angustata) under post-phytoremediation scenario. Thus, the phytomass was used without any chemical modification. The batch adsorption experiments were conducted to evaluate the effects of contact time and temperatures (25–45 °C) on the adsorption of methylene blue (MB) from aqueous solution by cattail phytomass (CP). More than 80 % of MB dye was removed from the aqueous solution within first 10 min of the experiment. Langmuir isotherm was modeled to describe the monolayer adsorption of MB dye (R ² = 0.995) with the maximum adsorption capacity of 8.1 mg/g at 25 °C. Pseudo-second-order kinetic model adequately described the kinetics of absorption process (R ² = 0.999). The adsorption of MB on the cattail phytomass was a spontaneous and endothermic process that was governed by chemisorption. Hence, CP could be applied as a potential low cost biosorbent to treat dyeing wastewater.     

Micromechanics approach to poroelastic behavior of a jointed rock

The formulation of macroscopic poroelastic behavior of a jointed rock is investigated within the framework of a micro–macro approach. The joints are modeled as interfaces, and their behavior is modeled by means of generalized poroelastic state equations. Starting from Hill's lemma extended for a jointed medium and extending the concept of strain concentration to relate the joint displacement jump to macroscopic strain, the overall poroelastic constitutive equations for the jointed rock are formulated. The analysis emphasizes the main differences and similarities of the resulting behavior with respect to that characterizing ordinary porous media. It is shown that, unlike ordinary porous media, conditions on the poroelastic parameters of joints are required for the macroscopic drained stiffness to entirely define the poroelastic behavior. This is achieved, for instance, if the joint network is characterized by a unique Biot coefficient. Extension of the analysis to non‐linear poroelasticity is also outlined. Finally, the theoretical formulation is applied to two particular cases of jointed rock for which explicit expressions of the overall poroelastic parameters are derived. Copyright © 2011 John Wiley & Sons, Ltd.     

Crustal structure of the Ordovician Macquarie Arc,Eastern Lachlan Orogen,based on seismic‐reflection profiling

In the Eastern Lachlan Orogen, the mineralised Molong and Junee‐Narromine Volcanic Belts are two structural belts that once formed part of the Ordovician Macquarie Arc, but are now separated by younger Silurian‐Devonian strata as well as by Ordovician quartz‐rich turbidites. Interpretation of deep seismic reflection and refraction data across and along these belts provides answers to some of the key questions in understanding the evolution of the Eastern Lachlan Orogen—the relationship between coeval Ordovician volcanics and quartz‐rich turbidites, and the relationship between separate belts of Ordovician volcanics and the intervening strata. In particular, the data provide evidence for major thrust juxtaposition of the arc rocks and Ordovician quartz‐rich turbidites, with Wagga Belt rocks thrust eastward over the arc rocks of the Junee‐Narromine Volcanic Belt, and the Adaminaby Group thrust north over arc rocks in the southern part of the Molong Volcanic Belt. The seismic data also provide evidence for regional contraction, especially for crustal‐scale deformation in the western part of the Junee‐Narromine Volcanic Belt. The data further suggest that this belt and the Ordovician quartz‐rich turbidites to the east (Kirribilli Formation) were together thrust over ?Cambrian‐Ordovician rocks of the Jindalee Group and associated rocks along west‐dipping inferred faults that belong to a set that characterises the middle crust of the Eastern Lachlan Orogen. The Macquarie Arc was subsequently rifted apart in the Silurian‐Devonian, with Ordovician volcanics preserved under the younger troughs and shelves (e.g. Hill End Trough). The Molong Volcanic Belt, in particular, was reworked by major down‐to‐the‐east normal faults that were thrust‐reactivated with younger‐on‐older geometries in the late Early ‐ Middle Devonian and again in the Carboniferous.     

The Maltese Islands: climate, vegetation and landscape

The Maltese Islands, situated in the central Mediterranean, occupy an area of only some 316 km². The climate is typically Mediterranean: the average annual rainfall is c. 530 mm of which some 85% falls during the period October to March; the mean monthly temperature range is 12--26 °C, and the islands are very windy and sunny. Although small, the Maltese Islands have a considerable diversity of landscapes and ecosystems which are representative of the range and variety of those of the Mediterranean region. The islands are composed mainly of limestones, the soils are young and are very similar to the parent rocks, and there are no mountains, streams or lakes, but only minor springs; the main geomorphological features are karstic limestone plateaux, hillsides covered with clay taluses, gently rolling limestone plains, valleys which drain runoff during the wet season, steep sea-cliffs on the south-western coasts, and gently sloping rocky shores to the Northeast. The main vegetational assemblages are maquis, garigue and steppe; minor ones include patches of woodland, coastal wetlands, sand dunes, freshwater, and rupestral communities; the latter are the most scientifically important in view of the large number of endemic species they support. Human impact is significant. Some 38% of the land area is cultivated, c. 15% is built up, and the rest is countryside. The present landscape is a result of the interaction of geology and climate, coupled with the intense human exploitation of the environment over many thousands of years, which has altered the original condition of the vegetation cover, principally through the diversion of vast tracts of land to cultivation, the construction of terraces, water catchment devices, irrigation channels and drainage ditches, the grazing of animals on uncultivated land, and the development of land for buildings and industry. The scantiness of the soil, combined with the erratic rainfall and the periodic disturbance of the vegetation cover, has resulted in extensive erosion. As a consequence it is now difficult for the original vegetation to reassert itself, affecting the landscape drastically and permanently. Much of the original native flora has been lost or marginalised and the present day non-urban landscape is now dominated by vegetation consisting mainly of ruderal and introduced species. As the population increases, and human pressure on the environment mounts, such trends are likely to continue and it is only very recently that some important initiatives have been taken to manage the environment and halt the deterioration of the landscape.     

Water quality impacts from mining in the Black Hills,South Dakota,USA

The focus of this research was to determine if abandoned mines constitute a major environmental hazard in the Black Hills. Many abandoned gold mines in the Black Hills contribute acid and heavy metals to streams. In some areas of sulfide mineralization local impacts are severe, but in most areas the impacts are small because most ore deposits consist of small quartz veins with few sulfides. Pegmatite mines appear to have negligible effects on water due to the insoluble nature of pegmatite minerals. Uranium mines in the southern Black Hills contribute some radioactivity to surface water, but the impact is limited because of the dry climate and lack of runoff in that area.     

A surface complexation model for cadmium and lead adsorption onto diatom surface

This work is devoted to the physico-chemical study of cadmium and lead interaction with diatom–water interfaces for two marine planktonic (Thalassiosira weissflogii = TW, Skeletonema costatum = SC) and two freshwater periphytic species (Achnanthidium minutissimum = AMIN, Navicula minima = NMIN) by combining adsorption measurements with surface complexation modeling. Reversible adsorption experiments were performed at 20 °C after 3 h of exposure as a function of pH, metal concentration in solution, and ionic strength. While the shape of pH-dependent adsorption edge is similar among all four diatom species, the constant-pH adsorption isotherm and maximal binding capacities differ. These observations allowed us to construct a surface complexation model for cadmium and lead binding by diatom surfaces that postulates the constant capacitance of the electric double layer and considers Cd and Pb complexation with mainly carboxylic and, partially, silanol groups. Parameters of this model are in agreement with previous acid–base titration results and allow quantitative reproduction of all adsorption experiments.     

Lithofacies succession of maar crater deposits in the Eifel area (Germany)

ABSTRACT Maar craters often contain exceptionally preserved fossils and maar sediments may reflect detailed environmental changes. Volcanosedimentary processes in a Middle Eocene maar crater lake are illustrated by the deposits of Eckfeld Maar in the Tertiary Hocheifel Volcanic Field (Rhenish Massif, Germany). The maar origin of the basin is evident from a circular negative gravity anomaly which indicates a low-density funnel-shaped basin filling. From the facies analysis of an Eocene (Eckfeld) and a Pleistocene (Döttingen) maar we develop a lithozone classification for the interpretation of maar sediments: syn-/post-eruptive breccias are followed by a fining-upwards sequence of lacustrine mud with coarse layers and final swamp deposits. From the facies analysis and regional geological data we reconstruct the pre- to post-eruptive history of a maar crater prior to post-Eocene uplift. These observations can be used for the interpretation of Tertiary and Quaternary maar craters that are ideal fossil and sediment traps.     

Distribution and sources of pre-anthropogenic lead isotopes in deep ocean water from FeMn crusts

The lead isotope composition of ocean water is not well constrained due to contamination by anthropogenic lead. Here the global distribution of lead isotopes in deep ocean water is presented as derived from dated (ca. 100 ka) surface layers of hydrogenetic Fe-Mn crusts. The results indicate that the radiogenic lead in North Atlantic deep water is probably supplied from the continents by river particulates, and that lead in Pacific deep water is similar to that characteristic of island and continental volcanic arcs. Despite a short residence time in deep water (80–100 a), the isotopes of lead appear to be exceedingly well mixed in the Pacific basin. There is no evidence for the import of North Atlantic deep water-derived lead into the Pacific ocean, nor into the North Indian Ocean. This implies that the short residence time of lead in deep water prohibits advection over such long distances. Consequently, any climate-induced changes in deep-water flow are not expected to result in major changes in the seawater Pb-isotope record of the Pacific Ocean.     

Graben generation of major sedimentary basins

Regional isostatic adjustment to the load that fills the trough of a large graben will produce a surface depression that extends far beyond the boundaries of the load. Sediment infilling of this depression can lead to the development of a major sedimentary basin as the regional adjustment mechanism approaches isostatic equilibrium.     

Metal content and environmental risk assessment around high-altitude mine sites

Gold mining activities in Apolobamba area, northwest of La Paz, Bolivia have created serious environmental concern and great risk to human health. The current methods used to extract gold are too primitive resulting in metal contamination of soil and water. The objectives of this study were to: (1) determine the degree of metal pollution, and (2) assess the risk to human health and environment in the Apolobamba area. Soil, water, sediment samples, and mine spills were collected and analyzed. Metals including Pb, Cu, Zn, Cd, and Hg concentrations were higher in surface soils than in subsurface soils indicating active atmospheric deposition of metals. Sediment samples had elevated levels of metals probably from mine spills discharged into the Sunchulli River. Surface soils in the Sunchulli community show the highest levels of Pb and Hg in all soil samples and may pose a risk to the health of the human population and environment.